公开(公告)号：US3884988A

公开(公告)日：1975-05-20

申请号：US33262773

申请日：1973-02-15

Applicant: SNAM PROGETTI

Inventor： GIROTTI PIERLEONE ,  TESEI RENATO ,  FLORIS TELEMACO

IPC: C08F110/14 ,  C07C2/08 ,  C07C2/30 ,  C07C6/02 ,  C07C9/14 ,  C08F4/14 ,  C08F10/14 ,  C10M107/10 ,  C10M169/00 ,  C07C3/10

CPC classification number: C10M3/00 ,  C08F10/14 ,  C10M2205/00

Abstract: Synthetic, high quality lubricating oils are produced through the polymerization of a single alpha-olefin or a mixture of alpha-olefins from ''''wax-cracking'''' having the formula R - CH CH2 wherein R is an alkyl radical containing from 2 to 16 C atoms, by the use, in a dry nitrogen atmosphere, of a catalyst system constituted by a compound of a transition metal selected from groups IV to VIII of the periodic system (e.g., TiCl4) and by two coordinate anionic cocatalysts, one of which is an aluminum compound of inorganic nature devoid of any metal-carbon bond and consisting of a polyiminic linear polymer (e.g., a polyimine alane represented by the formula:

WHEREIN R is alkyl, aryl or cycloalkyl and n is a whole number from 4 to 25) and the other of which is an aluminum compound of the conventional Ziegler type with a metal-carbon link (e.g., an aluminum alkyl sesquichloride or an aluminum dialkyl monochloride.

Abstract translation: 合成的高品质润滑油是通过单个α-烯烃或由具有式R-CH = CH 2的“蜡裂解”）的α-烯烃的混合物的聚合制备的，其中R是含有2至16个碳原子的烷基 原子通过在干燥的氮气气氛中使用由周期性系统的IV至VIII族的过渡金属的化合物（例如TiCl 4）构成的催化剂体系以及由两个配位阴离子助催化剂组成的催化剂体系，其中之一是 不含任何金属 - 碳键并由多元线性聚合物（例如，由下式表示的聚亚烷基亚烷基，其中R是烷基，芳基或环烷基并且n是整数4至25）的无机性的铝化合物， 另一种是具有金属 - 碳键的常规齐格勒型铝化合物（例如，烷基倍半氯化铝或一氯化铝二烷基铝。