Abstract:
A process is disclosed for improving the oxidative resistance of amorphous carbon or graphite articles. The process comprises applying a solution of water; an oxide or hydroxide of a group 2 metal; a member of the group consisting of nitric acid; sodium nitrite and sodium carbonate; and boric acid or sodium tetraborate.
Abstract:
New complexes of saline type, which are represented by the formula: (Me Lm L''n Aa) Xx WHEREIN, Me represents Rh, Ir, Ru, Pd or Pt; L, L'' represent primary or secondary olefin, linear, branched or cyclic, having from 2 to 12 carbon atoms, and may be substituted by functional unsaturated compounds such as unsaturated nitriles; A is a neutral ligand such as a nitrile, phosphine, phosphite, arsine or stibine; X is an anion such as BF4 , PF6 , ClO4 or NO3 ; m + n equals 1, 2 or 3; a is 0, 1, 2 or 3; and x is 1 or 2, are useful as catalysts in olefin reactions such as the hydrogenation of olefins at 50*-80* C., in the oligomerization or dimerization or codimerization of olefins and in the hydration of olefins by reaction with water in alcohol solvents.
Abstract:
D R A W I N G 1. PROCESS RECOVEING ISOPRENE OF POLYMERIZATION GRADE FROM A MIXTURE OF C4 AND C5 HYDROCARBON INCUDING ISOPRENE, COMPRISED OF THE FOLLOWING STEPS; (A) RATIFICATION WHEREIN C4 HYDROCARBONS, LOW BOILING ACETYLENIC COMPOUNDS, 70% TO 90% OF ISOPENTANE ARE WITHDRAWN AS OVERHEAD, AND DIMERIZATION AND POLYMERIZATION PRODUCTS 30% TO 60% OF THE HIGH BOILING HYDROCARBON PRESENT IN THE FEED ARE WITHDRAWN AS BOTTOM PRODUCT, AND THE STREAM CONTAINING ISOPRENE IS WITHDRAWN IN VAPOR PHASE FROM A PLATE OF THE EXHAUST SECTION OF A RECTIFIER; (B) A FIRST EXTRACTIVE DISTILLATION, UTILIZING REFLUX AND SOLVENT, SELECTED FROM THE GROUP CONSISTING OF NFORMYLMORPHOLINE, MORPHOLINE AND MIXTURES OF SAID COMPOUNDS WITH EACH OTHER AND WITH WATER, OBTAINED BY SUBJECTING TO FLASH EVAPORATION THE BOTTOM STREAM OF A SECOND EXTRACTIVE DISTILLATION STEP, WHEREIN MONOCYCLOPENTADIENE, HIGH BOILING ACETYLENIC COMPOUNDS AND 40% TO 70% OF PENTADIENES PRESENTS IN SAID STREAM ARE WITHDRAWN AS BOTTOM PRODUCT AND A STREAM CONTAINING RAW ISOPRENE IS WITHDRAWN AS OVERHEAD WITH OLEFINES, CYCLOPENTENE, AND C5 SATURATED HYDROCARBONS; (C) STRIPPING THE BOTTOM STREAM OF THE FIRST EXTRACTIVE DISTILLATION STEP BY SEPARATING THE SOLVENT FROM MOMOCYCLOPENTADIENE AND OTHER HYDROCARBONS, WHEREIN THE SOLVENT IS RECOVERED AS BOTTOM PRODUCT AND MONOCYCLOPENTADIENE AND OTHER HYDROCARBONS SOLUBLE IN THE SOLVENT ARE DISCHARGED AS OVERHEAD; (D) RECTIFICATION OF THE OVERHEAD HYDROCARBON STREAM FROM THE STRIPPING STEP (C) WHEREIN MONOCYCLOPENTADIENE, THE HIGH BOILING ACETYLENIC COMPOUNDS AND 40% TO 70% BASED ON THE FEEDSTOCK OF THE DIENE COMPOUNDS ARE WITHDRAWN AS BOTTOM PRODUCT AND ISOPRENE CONTAINED IN THE STREAM COMING FROM STRIPPING STEP (C) IS DISCHARGED AS OVERHEAD PRODUCT AND SENT TO THE RECTIFICATION COLUMN OF STEP (A); (E) SECOND EXTRACTIVE DISTILLATION OF THE RAW ISOPRENE STREAM OBTAIN FROM THE FRIST EXTRACTIVE DISTILLATION STEP (B) WHEREIN SAID STREAM IS FED IN VAPOR PHASE AND THE C5 SATURATED AND OLEFINIC COMPOUNDS ARE WITHDRAWN AS OVERHEAD, THE SOLVENT NECESSARY THEREFOR BEING WITHDRAWN FROM THE BOTTOM OF THE STRIPPING COLUMN OF STEP (C); (F) FLASH EVAPORATION OF THE STREAMS DISCHARGED AS BOTTOM PRODUCT IN THE EXTRACTIVE DISTILLATION STEP (E), THE LIQUID PHASE BEING RECYCLED TO THE TOP OF THE FIRST EXTRACTIVE COLUMN FOR SUPPLYING SAID COLUMN BOTH WITH THE EXTRACTIVE SOLVENT AND THE HYDROCARBON STREAM NECESSARY FOR THE REFLUX, THE VAPOR PHASE CONSTITUTED BY ISOPRENE ESSENTIALLY IMPURE FOR CYCLOPENTENE AND CYCLOPENTANE BEING SENT TO A FURTHER RECTIFICATION STEP; (G) RECTIFICATION ELMINATING AS BOTTOM PRODUCT THE STILL PRESENT HEAVY COMPOUNDS, CYCLOPENTENE, CYCLOPENTANE AND THE REMAINING PENTADIENES WITHDRAWING AS OVERHEAD A STREAM OF ISOPRENE CONTAINING TACES OF LOW BOILING COMPOUNDS, WHICH STREAM IS RECYCLED TO THE RECTIFICATION COLUMN OF STEP (A) WITHDRAWING IN LIQUID PHASE FROM A PLATE OF THE UPPER SECTION OF THE RECTIFICATION COLUMN POLYMERIZATION GRADE ISOPRENE.
Abstract:
1. PROCESS FOR THE PREPARATION OF ACRYLONITRILE WHILD COMPRISES CONTACTING, AT A TEMPERATURE OF FROM 300*C. TO 500*C., A GASEOUS MIXTURE OF PROPYLENE, AMMONIA AND OXYGEN IN THE PRESENCE OF A CATALYST CONSISTING ESSENTIALLY OF A MIXTURE OF URANIUM OXIDE AND TELLURIUM OXIDE WHEREIN THE TE/U ATOMIC RATIO IS IN THE RANGE FROM 2 TO 5.
WEHEREIN X IS AN ATOM OF HAOLGEN, Z IS NITROGEN, CARBON OR PHOSPHOROUS; R'' IS HYDROGEN RADICAL WITH FROM 1 TO 10 CARBON ATOMS, OR HYDROGEN, OR IS EQUAL TO X; Y IS A MEMBER OF THE GROUP CONSISTING OF
1. PROCESS FOR THE PRODUCTION OF BUTYL RUBBER THROUGH THE COPOLYMERIZATION OF ISOBUTYLENE AND ISOPRENE WHEREIN THE IMPROVEMENT COMPRISES CONDUCTING THE COPOLYMERIZATION REACTION IN THE PRESENCE OF A CATALYTIC SYSTEM CONSISTING ESSENTIALLY OF: (A) A METALORGANIC COMPOUND OF ALUMINUM HAVING THE FORMULA AIR3 OR AIR2X WHERE X IS A HALOGEN ATOM AND R IS A HYDROCARBON RADICAL WITH FROM 1 TO 10 CARBON ATOMS, OR HYDROGEN; AND (B) A COMPOUND CONTAINING A MOBILE HALOGEN GROUP OR AT LEAST ONE IN WHICH THE HALOGEN GROUP IS EASILY EXCHANGEABLE DUE TO THE PRESENCE OF AN ELECTROPHILIC GROUP REPRESENED BY THE FORMULA Y'' IS EQUAL TO Y, OR TO R''; Y OR Y'' MAY BE A BIVALENT RADICAL LINKED THROUGH A DOUBLE BON DIRECTLY TO Z; Y AND Y'' MAY BE CONNECTED TO EACH OTHER CLOSING THEMSELVES CYCLICALLY ON Z; R'''' IS AN ALKYLIC OR ARYLIC RADICAL, SIMPLE OR SUBSTITUTED; N AND H ARE 0 OR 1.
Abstract:
1. PROCESS FOR THE PRODUCTION OF BUTYL RUBBER THROUGH THE COPOLYMERIZATION OF ISOLBUTYLENE AND ISOPRENE WHEREIN THE IMPROVEMENT COMPRISES CONDUCTING THE COPOLYMERIZATION IN THE PRESENCE OF A CATALYTIC SYSTEM CONSISTING ESSENTIALLY OF: (A) A METALORGANIC COMPOUND OF ALUMINUM REPRESENTED BY THE FORMULA AIR3 OR AIR2X WHEREIN X IS A HALOGEN ATOM; R IS A HYDROCARBON RADICAL WITH FROM 1 TO 10 CARBON ATOMS OR HYDROGEN; AND (B) A HALOID OF AN ORGANIC ACID OR THIOACID REPRESENTED BY THE GENERAL FORMULA
R''-C(=Y)-X''
IN WHICH X'' IS A HALOGEN ATOM; R'' IS AN ALKYLIC RESIDUE, CYCLOALKYLIC, ALKYLARYLIC, ALKYLCYCLOALKYLIC, OR IS EQUAL TO X'' OR IS REPRESENTED BY THE FORMULA
Abstract:
1. A PROCESS FOR THE PREPARATION OF OXIDATION CATALYST BASED ON OXIDES OF ANTIMONY AND OF A SECOND METAL SELECTED FROM THE GROUP CONSISTING IRON, URANIUM, TIN, CERIUM, MANGANESE AND THORIUM SAID PROCESS COMPRISING (I) PROVIDING A POWDERED CATALYTIC MASS BY HEATING COMPOUNDS OF THE SAID METALS WHICH ARE THERMALLY DECOMPOSABLE TO THE METAL OXIDES, (II) DRYING THE FINELY POWDERED CATALYTIC MASS, (II) ADDING A COMPOUND, VOLATILE AT TEMPERATURE LOWER THAN THE CATALYST ACTIVATION TEMPERATURE, AND SELECTED FROM THE GROUP CONSISTING OF AMMONIUM CARBONATE, AMMONIUM BICARBONATE UREA, HEMAMETHYLENETETRAMINE AND OXALIC ACID, (IV) MOLDING THE CATALYST PREPARATION TO SHAPE, (V) HEATING THE SHAPED CATALYST UNTIL SAID VOLATILE COMPOUND IS COMPLETELY ELIMINATED AND (VI) THEN CALCINING TO OBTAIN THE OXIDES OF THE SAID METALS.
Abstract:
A PROCESS IS DISCLOSED FOR PRODUCING A NEW SERIES OF ADDITION HOMO-AND CO-POLYMERS FROM MONOMERS SUCH AS EPISULPHIDES, WITH ALKALI METAL HALIDE CATALYSTS (E.G. LII) IN A POLAR SOLVENT BALANCED BETWEEN DONOR STRENGTH AND DIELECTRIC CONSTANT (E.G. HEXAMETHYLPHOSPHORAMIDE) WITH A CATALYST MONOMER MOLE RATIO RANGING FROM 0.001% TO 20% AND AT A TEMPERATURE IN THE RANGE FROM -20 TO 20*C.
Abstract:
THIS INVENTION PROVIDED A SOLUTION AND NOVEL PROCEDURE FOR IMPARTING OXIDATION RESISTANCE TO AMORPHOUS CARBON OR GRAPHITE MANUFACTURED ARTICLES BY MEANS OF THE COATING SOLUTION WHICH CONSISTS OF WATER, PHOSPHORIC ACID, ONE OR MORE COMPOUNDS SELECTED FROM THE GROUPS OF SALTS, OXIDES AND HYDROXIDES OF A METAL OF THE 2ND GROUP OF THE PERIODIC SYSTEM; ONE OR BOTH COMPONENTS OF THE GROUP FORMED BY BORIC AND SOLDIUM TETRABORATE DECAHYDRATE AND ONE OR MORE COMPOUNDS SELECTED FROM THE GROUP CONSISTING OF NITRIC ACID, SODIUM NITRITE AND SODIUM CARBONATE.
Abstract:
THIS INVENTION RELATES TO A PROCESS FOR THE PRODUCTION OF A REDUCING GAS FOR USE IN A BLAST FURNACE SAID PROCESS COMPRISING SEPARATELY PREHEATING A HYDROGEN FUEL AND SEPARATELY PREHEATING THE SUPPORTOR OF COMBUSTION TO BE USED IN THE PARTIAL COMBUSTION FURNACE WHERE THE REDUCING GAS IS PRODUCED TO A TEMPERATURE IN THE RANGE OF 800*-1500* C; FEEDING THE PREHEATED SUPPORTER OF COMBUSTION TO THE PARTIAL COMBUSTION FURNACE TOGETHER WITH THE FUEL WHICH HAS BEEN PREHEATED TO AT LEAST 600* C, COOLING IF NECESSARY THE OBTAINED GASES TO A TEMPRATURE SUITABLE FOR INTRODUCTION INTO THE BLAST FURNACE AND; FEEDING THE GASES TO THE BLAST FURNACE.