公开(公告)号：US3883573A

公开(公告)日：1975-05-13

申请号：US37028773

申请日：1973-06-15

Applicant: STANDARD OIL CO

Inventor： MILBERGER ERNEST C ,  DOLHYJ SERGE R ,  WHITE JAMES F

IPC: B01J8/06 ,  B01J23/88 ,  B01J27/192 ,  B01J27/195 ,  C07C121/02

CPC classification number: C07C253/26 ,  B01J8/06 ,  B01J27/192 ,  B01J27/195 ,  B01J2208/00212 ,  B01J2208/00256 ,  B01J2208/00876 ,  Y02P20/52 ,  C07C255/08

Abstract: Very desirable temperature control in the ammoxidation of propylene or isobutylene in a fixed-bed, tubular reactor is obtained by using an oxidation catalyst having two physical forms. The first catalyst which initially contacts the reactants is an essentially inert support having a strongly adhering coat of a catalytic material, and the second catalyst that contacts the reactants after contact with the first catalyst consists essentially of the catalytic material.

Abstract translation: 通过使用具有两种物理形式的氧化催化剂，可以获得固定床，管式反应器中丙烯或异丁烯的氨氧化反应非常理想的温度控制。 最初与反应物接触的第一催化剂是具有催化材料的强粘附层的基本上惰性的载体，并且在与第一催化剂接触之后与反应物接触的第二催化剂基本上由催化材料组成。

公开(公告)号：US3875220A

公开(公告)日：1975-04-01

申请号：US40530973

申请日：1973-10-11

Applicant: STANDARD OIL CO OHIO

Inventor： WHITE JAMES F ,  REGE JAMES R

IPC: B01J23/28 ,  B01J23/30 ,  B01J23/31 ,  B01J23/88 ,  B01J23/887 ,  B01J23/888 ,  B01J27/199 ,  C07C51/25 ,  C07C57/055 ,  C07C57/04 ,  C07C51/30

CPC classification number: B01J23/8878 ,  B01J23/002 ,  B01J23/28 ,  B01J23/30 ,  B01J23/31 ,  B01J23/8877 ,  B01J23/8885 ,  B01J27/199 ,  B01J2523/00 ,  C07C51/252 ,  C07C57/04 ,  B01J2523/51 ,  B01J2523/55 ,  B01J2523/68 ,  B01J2523/69 ,  B01J2523/842 ,  B01J2523/67 ,  B01J2523/14 ,  B01J2523/847 ,  B01J2523/24 ,  B01J2523/397 ,  B01J2523/845 ,  B01J2523/28 ,  B01J2523/54 ,  B01J2523/822 ,  B01J2523/3712 ,  B01J2523/53 ,  B01J2523/18 ,  B01J2523/17 ,  B01J2523/43

Abstract: Catalysts containing phosphorus, vanadium and molybdenum have been found to be especially effective for the oxidation of methacrolein with molecular oxygen to obtain methacrylic acid. The catalysts may be optionally promoted with Bi, As, B, Ce, Cr, Ag, Fe, W, Pb, Mn, Tl, Te, Ni, Nb, B, Sn and/or Cu.

Abstract translation: 已经发现含有磷，钒和钼的催化剂对于用分子氧氧化甲基丙烯醛特别有效，以获得甲基丙烯酸。 可以任选地用Bi，As，B，Ce，Cr，Ag，Fe，W，Pb，Mn，Tl，Te，Ni，Nb，B，Sn和/或Cu来促进催化剂。