摘要:
A method for the removal of nitrogen compounds from FCC feed or from catalytically cracked distillates including FCC cycle oils by using formaldehyde to selectively couple organic heterocyclic nitrogen species in the FCC feed or FCC distillate to form higher boiling coupling products out of the boiling range of FCC distillate. Removal of the nitrogenous compounds improves the operation of subsequent hydrodesulfurization steps needed for the distillate fraction to conform to low sulfur standards. The formaldehyde is preferably used in the form of paraformaldehyde. The reaction between the nitrogenous compounds in the cycle oil fraction with the formaldehyde is conveniently carried out in the cycle oil pumparound circuit of the FCC main column.
摘要:
A method for the removal of nitrogen compounds from FCC feed or from catalytically cracked distillates including FCC cycle oils by using formaldehyde to selectively couple organic heterocyclic nitrogen species in the FCC feed or FCC distillate to form higher boiling coupling products out of the boiling range of FCC distillate. Removal of the nitrogenous compounds improves the operation of subsequent hydrodesulfurization steps needed for the distillate fraction to conform to low sulfur standards. The formaldehyde is preferably used in the form of paraformaldehyde. The reaction between the nitrogenous compounds in the cycle oil fraction with the formaldehyde is conveniently carried out in the cycle oil pumparound circuit of the FCC main column.
摘要:
The invention described herein is directed to (a) slurry hydroprocessing (SHP) of a feed under SHP conditions; (b) deasphalting, under deasphalting conditions the product obtained from said step (a) and recovering a solvent deasphalted oil and solvent deasphalted rock; (c) calcining said solvent deasphalted rock at a temperature of ≦about 1200° F. to produce an ash catalyst precursor; (d) recycling said ash catalyst precursor to said step (a).
摘要:
Heavy oil feeds are hydroprocessed in the presence of a solvent under conditions that provide a variety of benefits. The solvent can be an added solvent or a portion of the liquid effluent from hydroprocessing. The processes allow for lower pressure processing of heavy oil feeds for extended processing times or extended catalyst lifetimes be reducing or mitigating the amount of coke formation on the hydroprocessing catalyst.
摘要:
Heavy oil feeds are hydroprocessed in the presence of a solvent under conditions that provide a variety of benefits. The solvent can be an added solvent or a portion of the liquid effluent from hydroprocessing. The processes allow for lower pressure processing of heavy oil feeds for extended processing times or extended catalyst lifetimes be reducing or mitigating the amount of coke formation on the hydroprocessing catalyst.