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    Stable conducting polymer and processes for the preparation thereof
    2.
    发明授权
    Stable conducting polymer and processes for the preparation thereof 失效
    稳定的导电聚合物及其制备方法

    公开(公告)号：US5510532A

    公开(公告)日：1996-04-23

    申请号：US162620

    申请日：1993-12-07

    申请人： Suh B. Rhee ,  Myong-Hoon Lee ,  Chang-Jin Lee ,  Bong S. Moon

    发明人： Suh B. Rhee ,  Myong-Hoon Lee ,  Chang-Jin Lee ,  Bong S. Moon

    IPC分类号： C07C211/45 ,  C07C211/52 ,  C07C303/32 ,  C07C309/04 ,  C07C309/14 ,  C08G73/00 ,  C08K5/42 ,  C07C211/00

    CPC分类号： C08K5/42

    摘要： Conductive polymers having repeating units of formula (II) ##STR1## formed by chemical or electrochemical oxidation of aniline derivatives of formula (I) ##STR2## wherein R.sub.1 denotes --(CH.sub.2).sub.n --; n is an integer between 2 and 12; R.sub.2, R.sub.3, R.sub.4 and R.sub.5 denote hydrogens or one or two of them can be a halogen atom, methyl, methoxy or nitro groups; and X denotes hydrogen an alkali metal ion, an ammonium ion, an alkyl ammonium ion or an anilinium ion. The conductive polymers have excellent stability toward electrochemical redox cyclization and good processibility.

    摘要翻译： 具有式（II）的重复单元的导电聚合物通过化学或电化学氧化式（I）的苯胺衍生物形成（II）其中R1表示 - （CH2）n-; n是2和12之间的整数; R2，R3，R4和R5表示氢，或者它们中的一个或两个可以是卤素原子，甲基，甲氧基或硝基; X表示氢，碱金属离子，铵离子，烷基铵离子或苯胺鎓离子。 导电聚合物具有优异的电化学氧化还原环化稳定性和良好的加工性能。

    Conductive polymeric composite with high electrical activation density and method for preparing the same
    4.
    发明授权
    Conductive polymeric composite with high electrical activation density and method for preparing the same 失效
    具有高电活化密度的导电聚合物复合材料及其制备方法

    公开(公告)号：US5416170A

    公开(公告)日：1995-05-16

    申请号：US66346

    申请日：1993-05-24

    申请人： Suh B. Rhee ,  Myong H. Lee ,  Chang J. Lee ,  Yong K. Kang

    发明人： Suh B. Rhee ,  Myong H. Lee ,  Chang J. Lee ,  Yong K. Kang

    IPC分类号： C07C13/00 ,  C08F2/04 ,  C08G61/12 ,  C08G73/06 ,  C08K5/00 ,  C08L39/04 ,  C08L41/00 ,  C08L43/00 ,  C08L65/00 ,  H01B1/12 ,  H01M4/60 ,  C08K5/08

    CPC分类号： H01M4/60 ,  C08G61/124 ,  C08G73/0611 ,  C08K5/0091 ,  C08L43/00 ,  C08L65/00 ,  H01B1/128

    摘要： A conductive polymeric composite with an improved electrical activation density obtained by compounding a ferrocene derivative used as a dopant with a polypyrrole of a conductive polymer and a method for preparing the same. The conductive composite can be produced by use of a chemical method or an electrochemical method. In the case of using the chemical method, pyrrole or its derivative is dissolved in a solution containing a ferrocene derivative, together with one or mixture of ferric trichloride, ammonium persulfate and copper chloride-aluminum chloride. In the case of using the electrochemical method, a solution, in which pyrrole or its derivative is dissolved together with ferrocene derivative, is used, as an electrolytic solution, alone or together with a solution in which an electrolyte of inorganic salt such as ammonium salt, lithium perchloric acid and tetraalkylammonium perchloric acid is dissolved. The composite is a superior conductive composite exhibiting an electrochemical activity by virtue of reversible oxidation-reduction reaction of conductive polymer itself and having a high density of electrochemically active material by virtue of an addition of an electrochemical activity obtained by the oxidation-reduction reaction of ferrocene added as an electrolyte.

    摘要翻译： 通过将用作掺杂剂的二茂铁衍生物与导电聚合物的聚吡咯混合获得的具有改善的电活化密度的导电聚合物复合物及其制备方法。 导电性复合体可以通过使用化学方法或电化学方法来制造。 在使用化学方法的情况下，将吡咯或其衍生物与三氯化铁，过硫酸铵和氯化铜 - 氯化铝的一种或混合物一起溶解在含有二茂铁衍生物的溶液中。 在使用电化学方法的情况下，使用其中吡咯或其衍生物与二茂铁衍生物一起溶解的溶液作为电解液，单独或与其中的无机盐如铵盐的电解质一起 ，高氯酸锂和高氯酸四烷基铵溶解。 复合材料是通过导电聚合物本身的可逆氧化 - 还原反应显示出电化学活性的优异的导电复合材料，并且通过加入通过二茂铁的氧化还原反应获得的电化学活性，并具有高密度的电化学活性材料 作为电解质添加。