公开(公告)号：US20180265612A1

公开(公告)日：2018-09-20

申请号：US15542149

申请日：2016-01-18

Applicant: TOHO TITANIUM CO., LTD.

Inventor： Hiroyuki Kono ,  Toshiya Uozumi ,  Shingo Yamada ,  Toshihiko Sugano

IPC: C08F110/06

CPC classification number: C08F110/06 ,  C08F4/658 ,  C08F10/00 ,  C08F2410/01 ,  C08F4/651 ,  C08F4/6565 ,  C08F2500/12 ,  C08F2500/18

Abstract: A solid catalyst component for olefin polymerization is produced by bringing a vinylsilane compound (d) into contact with a catalyst component, the catalyst component being a powdery solid component obtained by bringing a magnesium compound (a), a titanium halide compound (b), and an electron donor compound (c) into contact with each other, the electron donor compound (c) being one or more compounds that do not include a phthalic ester structure, and include one or more groups selected from an ester group, a carbonate group, and an ether group, the vinylsilane compound (d) being brought into contact with the catalyst component in a 0.1 to 15-fold molar quantity with respect to the molar quantity (on a titanium atom basis) of the titanium halide compound (b) included in the catalyst component.

公开(公告)号：US09587050B2

公开(公告)日：2017-03-07

申请号：US14427143

申请日：2014-02-13

Applicant: TOHO TITANIUM CO., LTD.

Inventor： Motoki Hosaka ,  Noriaki Nakamura ,  Shingo Yamada ,  Toshihiko Sugano

IPC: C08F110/06 ,  C08F210/06 ,  C08F299/02 ,  C08F10/00

CPC classification number: C08F110/06 ,  C08F10/00 ,  C08F210/06 ,  C08F297/083 ,  C08F299/02 ,  C08F4/651 ,  C08F210/16 ,  C08F2500/12 ,  C08F2500/15 ,  C08F10/06 ,  C08F2/001 ,  C08F4/6492

Abstract: A method for producing a solid catalyst component for olefin polymerization produces a novel solid catalyst component for olefin polymerization that achieves excellent olefin polymerization activity and activity with respect to hydrogen during polymerization, and can produce an olefin polymer that exhibits a high MFR, high stereoregularity, and excellent rigidity. The method includes a first step that brings a magnesium compound, a tetravalent titanium halide compound, and one or more first internal electron donor compounds excluding an aromatic dicarboxylic acid diester into contact with each other to effect a reaction, followed by washing; a second step that brings a tetravalent titanium halide compound and one or more second internal electron donor compounds into contact with a product obtained by the first step to effect a reaction, followed by washing; and a third step that brings one or more third internal electron donor compounds into contact with a product obtained by the second step to effect a reaction.

Abstract translation: 一种用于烯烃聚合的固体催化剂组分的制备方法产生用于烯烃聚合的新型固体催化剂组分，其在聚合过程中实现优异的烯烃聚合活性和相对于氢的活性，并且可以制备出显示出高MFR，高立构规整性的烯烃聚合物， 刚性好。 该方法包括使镁化合物，四价卤化钛化合物和除芳香族二羧酸二酯以外的一种以上的第一内部电子给体化合物接触进行反应，然后进行洗涤的第一工序; 第二步骤，使四价卤化钛化合物和一种或多种第二内电子给体化合物与通过第一步获得的产物接触以进行反应，随后进行洗涤; 以及第三步骤，其使一个或多个第三内部电子给体化合物与通过第二步获得的产物接触以进行反应。

公开(公告)号：US20150240002A1

公开(公告)日：2015-08-27

申请号：US14427143

申请日：2014-02-13

Applicant: TOHO TITANIUM CO., LTD.

Inventor： Motoki Hosaka ,  Noriaki Nakamura ,  Shingo Yamada ,  Toshihiko Sugano

IPC: C08F110/06 ,  C08F210/06 ,  C08F299/02

CPC classification number: C08F110/06 ,  C08F10/00 ,  C08F210/06 ,  C08F297/083 ,  C08F299/02 ,  C08F4/651 ,  C08F210/16 ,  C08F2500/12 ,  C08F2500/15 ,  C08F10/06 ,  C08F2/001 ,  C08F4/6492

Abstract: A method for producing a solid catalyst component for olefin polymerization produces a novel solid catalyst component for olefin polymerization that achieves excellent olefin polymerization activity and activity with respect to hydrogen during polymerization, and can produce an olefin polymer that exhibits a high MFR, high stereoregularity, and excellent rigidity. The method includes a first step that brings a magnesium compound, a tetravalent titanium halide compound, and one or more first internal electron donor compounds excluding an aromatic dicarboxylic acid diester into contact with each other to effect a reaction, followed by washing; a second step that brings a tetravalent titanium halide compound and one or more second internal electron donor compounds into contact with a product obtained by the first step to effect a reaction, followed by washing; and a third step that brings one or more third internal electron donor compounds into contact with a product obtained by the second step to effect a reaction.

Abstract translation: 一种用于烯烃聚合的固体催化剂组分的制备方法产生用于烯烃聚合的新型固体催化剂组分，其在聚合过程中实现优异的烯烃聚合活性和相对于氢的活性，并且可以制备出显示出高MFR，高立构规整性的烯烃聚合物， 刚性好。 该方法包括使镁化合物，四价卤化钛化合物和除芳香族二羧酸二酯以外的一种以上的第一内电子给体化合物接触进行反应，然后进行洗涤的第一工序; 第二步骤，使四价卤化钛化合物和一种或多种第二内电子给体化合物与通过第一步获得的产物接触以进行反应，随后进行洗涤; 以及第三步骤，其使一个或多个第三内部电子给体化合物与通过第二步获得的产物接触以进行反应。

公开(公告)号：US10472436B2

公开(公告)日：2019-11-12

申请号：US15542149

申请日：2016-01-18

Applicant: TOHO TITANIUM CO., LTD.

Inventor： Hiroyuki Kono ,  Toshiya Uozumi ,  Shingo Yamada ,  Toshihiko Sugano

IPC: C08F110/06 ,  C08F4/658 ,  C08F10/00

Abstract: A solid catalyst component for olefin polymerization exhibits excellent catalytic activity during polymerization, and can produce a polymer that exhibits excellent stereoregularity, bulk density, and the like even when a polymerization catalyst is produced in an inert atmosphere using an electron donor compound other than a phthalic ester and an organosilicon compound. The solid catalyst component for olefin polymerization is produced by bringing a vinylsilane compound (d) into contact with a catalyst component, the catalyst component being a powdery solid component obtained by bringing a magnesium compound (a), a titanium halide compound (b), and an electron donor compound (c) into contact with each other, the electron donor compound (c) being one or more compounds that do not include a phthalic ester structure, and include one or more groups selected from an ester group, a carbonate group, and an ether group, the vinylsilane compound (d) being brought into contact with the catalyst component in a 0.1 to 15-fold molar quantity with respect to the molar quantity (on a titanium atom basis) of the titanium halide compound (b) included in the catalyst component.

公开(公告)号：US10392453B2

公开(公告)日：2019-08-27

申请号：US15542723

申请日：2016-01-18

Applicant: TOHO TITANIUM CO., LTD.

Inventor： Hiroyuki Kono ,  Toshiya Uozumi ,  Shingo Yamada ,  Toshihiko Sugano

IPC: C08F110/06 ,  C08F4/654 ,  C08F10/00

Abstract: A method for producing an olefin polymerization catalyst includes bringing a solid catalyst component for olefin polymerization, a vinylsilane compound, an organosilicon compound, and an organoaluminum compound into contact with each other in an inert organic solvent under an inert gas atmosphere in the absence of a specific vinyl compound, wherein a washing treatment is not performed after the vinylsilane compound has been added to the reaction system, the solid catalyst component includes a magnesium compound, a titanium halide compound, and an electron donor compound that does not include a phthalic acid ester structure, and includes a diol skeleton, and the organosilicon compound does not include a vinyl group, and includes at least one group selected from an alkoxy group and an amino group.

公开(公告)号：US11008408B2

公开(公告)日：2021-05-18

申请号：US16088158

申请日：2017-03-23

Applicant: TOHO TITANIUM CO., LTD.

Inventor： Hiroyuki Kono ,  Shingo Yamada ,  Toshiya Uozumi

IPC: C07C29/70 ,  C07C31/30 ,  C08F4/52 ,  C08F10/06 ,  C07F3/02 ,  C08F4/642

Abstract: There is provided a novel alkoxymagnesium which, when used as a constituent of a solid catalyst component for olefin polymerization to polymerize an olefin, may reduce the formation rate of a fine powder and may form a polymer having an excellent particle size distribution under high polymerization activity. The alkoxymagnesium is characterized by comprising secondary particles each of which is an aggregate of primary particles having an average particle diameter of less than 1 μm and by having a ratio represented by the average particle diameter of the primary particles/the average particle diameter of the secondary particles of 0.1 or less, a total pore volume of 0.5 to 1 cm3/g, a specific surface area of less than 50 m2/g, and a particle size distribution index (SPAN) 1 or less.

公开(公告)号：US20170369608A1

公开(公告)日：2017-12-28

申请号：US15542723

申请日：2016-01-18

Applicant: TOHO TITANIUM CO., LTD.

Inventor： Hiroyuki Kono ,  Toshiya Uozumi ,  Shingo Yamada ,  Toshihiko Sugano

IPC: C08F110/06

CPC classification number: C08F110/06 ,  C08F4/654 ,  C08F10/00

Abstract: A method for producing an olefin polymerization catalyst includes bringing a solid catalyst component for olefin polymerization, a vinylsilane compound, an organosilicon compound, and an organoaluminum compound into contact with each other in an inert organic solvent under an inert gas atmosphere in the absence of a specific vinyl compound, wherein a washing treatment is not performed after the vinylsilane compound has been added to the reaction system, the solid catalyst component includes a magnesium compound, a titanium halide compound, and an electron donor compound that does not include a phthalic acid ester structure, and includes a diol skeleton, and the organosilicon compound does not include a vinyl group, and includes at least one group selected from an alkoxy group and an amino group.

公开(公告)号：US09593188B2

公开(公告)日：2017-03-14

申请号：US14427169

申请日：2014-02-13

Applicant: TOHO TITANIUM CO., LTD.

Inventor： Motoki Hosaka ,  Noriaki Nakamura ,  Shingo Yamada ,  Toshihiko Sugano

IPC: C08F210/16 ,  C08F110/06 ,  C08F10/00

CPC classification number: C08F210/16 ,  C08F10/00 ,  C08F110/06 ,  C08F210/06 ,  C08F297/083 ,  C08F4/651 ,  C08F10/06 ,  C08F4/6492 ,  C08F2500/12 ,  C08F2500/15 ,  C08F2/001

Abstract: A method produces a novel solid catalyst component for olefin polymerization that achieves excellent olefin polymerization activity and activity with respect to hydrogen during polymerization, and can produce an olefin polymer that exhibits a high MFR, high stereoregularity, and excellent rigidity. The method includes a first step that brings a magnesium compound, a tetravalent titanium halide compound, and one or more first internal electron donor compounds into contact with each other to effect a reaction, followed by washing; a second step that brings one or more second internal electron donor compounds into contact with a product obtained by the first step to effect a reaction; and a third step that brings a tetravalent titanium halide compound and one or more third internal electron donor compounds into contact with a product obtained by the second step to effect a reaction.

Abstract translation: 一种方法生产用于烯烃聚合的新型固体催化剂组分，其在聚合过程中可获得优异的烯烃聚合活性和相对于氢的活性，并且可以制备出显示出高MFR，高立构规整性和优异刚性的烯烃聚合物。 该方法包括使镁化合物，四价卤化钛化合物和一种或多种第一内电子给体化合物彼此接触以进行反应，随后进行洗涤的第一步骤; 第二步，使一个或多个第二内电子给体化合物与通过第一步获得的产物接触以进行反应; 以及第三步骤，使四价卤化钛化合物和一种或多种第三内电子给体化合物与通过第二步获得的产物接触以进行反应。

公开(公告)号：US20150240011A1

公开(公告)日：2015-08-27

申请号：US14427169

申请日：2014-02-13

Applicant: TOHO TITANIUM CO., LTD.

Inventor： Motoki Hosaka ,  Noriaki Nakamura ,  Shingo Yamada ,  Toshihiko Sugano

IPC: C08F210/16 ,  C08F110/06

CPC classification number: C08F210/16 ,  C08F10/00 ,  C08F110/06 ,  C08F210/06 ,  C08F297/083 ,  C08F4/651 ,  C08F10/06 ,  C08F4/6492 ,  C08F2500/12 ,  C08F2500/15 ,  C08F2/001

Abstract: A method produces a novel solid catalyst component for olefin polymerization that achieves excellent olefin polymerization activity and activity with respect to hydrogen during polymerization, and can produce an olefin polymer that exhibits a high MFR, high stereoregularity, and excellent rigidity. The method includes a first step that brings a magnesium compound, a tetravalent titanium halide compound, and one or more first internal electron donor compounds into contact with each other to effect a reaction, followed by washing; a second step that brings one or more second internal electron donor compounds into contact with a product obtained by the first step to effect a reaction; and a third step that brings a tetravalent titanium halide compound and one or more third internal electron donor compounds into contact with a product obtained by the second step to effect a reaction.

Abstract translation: 一种方法生产用于烯烃聚合的新型固体催化剂组分，其在聚合过程中可获得优异的烯烃聚合活性和相对于氢的活性，并且可以制备出显示出高MFR，高立构规整性和优异刚性的烯烃聚合物。 该方法包括使镁化合物，四价卤化钛化合物和一种或多种第一内电子给体化合物彼此接触以进行反应，随后进行洗涤的第一步骤; 第二步，使一个或多个第二内电子给体化合物与通过第一步获得的产物接触以进行反应; 以及第三步骤，使四价卤化钛化合物和一种或多种第三内电子给体化合物与通过第二步获得的产物接触以进行反应。