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公开(公告)号：US06464848B1
公开(公告)日：2002-10-15
申请号：US09388449
申请日：1999-09-02
申请人： Toru Matsumoto
发明人： Toru Matsumoto
IPC分类号： G01N27333
CPC分类号： G01N27/301
摘要： On an insulating substrate 1 is formed an electrode 2, on which is then formed a protection layer 3 consisting of a methacrylate-resin polyfluoroalcohol ester layer.
摘要翻译： 在绝缘基板1上形成电极2，然后形成由甲基丙烯酸酯 - 树脂多氟醇酯层构成的保护层3。
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公开(公告)号：US06391174B1
公开(公告)日：2002-05-21
申请号：US09444867
申请日：1999-11-22
IPC分类号： G01N27333
CPC分类号： G01N27/404 , G01N27/40
摘要： An ion exchange membrane for use in sensors which measure dissolved gases. Disclosed is a method for using ion exchangers in gas permeable membranes to maintain optimal conditions in the electrolyte contained within the sensor. This can greatly extend the lifetime and improve the stability relative to sensors of similar size and electrolyte volume that have been constructed using prior art.
摘要翻译： 用于测量溶解气体的传感器的离子交换膜。 公开了一种在透气膜中使用离子交换剂以保持包含在传感器内的电解质中的最佳条件的方法。 这可以大大延长寿命并提高相对于使用现有技术构造的类似尺寸和电解质体积的传感器的稳定性。
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公开(公告)号：US06248595B1
公开(公告)日：2001-06-19
申请号：US09298719
申请日：1999-04-23
申请人： Jaw Fang Lee , Sergey K. Maneshin , Marcus E. Kolb , Xin Yang
发明人： Jaw Fang Lee , Sergey K. Maneshin , Marcus E. Kolb , Xin Yang
IPC分类号： G01N27333
CPC分类号： G01N33/0037 , Y02A50/245 , Y10T436/12 , Y10T436/17 , Y10T436/173076 , Y10T436/173845 , Y10T436/174614 , Y10T436/175383 , Y10T436/178459 , Y10T436/179228 , Y10T436/25875
摘要： The invention relates to apparatus and a method for measuring NOx in biochemical processes, and to apparatus and methods for real time measuring the nitrification and/or denitrification rate of a liquid with or without suspended solids.
摘要翻译： 本发明涉及用于测量生物化学过程中的NOx的装置和方法，以及用于实时测量具有或不具有悬浮固体的液体的硝化和/或脱氮速率的装置和方法。
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公开(公告)号：US06197172B1
公开(公告)日：2001-03-06
申请号：US09162478
申请日：1998-09-28
申请人： David H. Dicks , Handani Winarta , John Hiti , Nicole Pouliot , Jeffrey C. Chien , Chung Chang Young
发明人： David H. Dicks , Handani Winarta , John Hiti , Nicole Pouliot , Jeffrey C. Chien , Chung Chang Young
IPC分类号： G01N27333
CPC分类号： G01N27/40
摘要： An electrochemical sensor with a gelled membrane for prolonging the useful life of an ion-selective electrode. The gelled membrane is a hydrophilic membrane having a specially-formulated gel layer coated on one side. The gel-coated side of the gelled membrane is in intimate contact with the ion-selective membrane and separates the ion-selective membrane from the test samples and the calibration and cleaning fluids. The gelled membrane is a semi-permeable barrier which allows passage of the species to be measured while inhibiting the passage of surfactant and proteinaceous material into the polymeric ion-selective membrane.
摘要翻译： 具有凝胶膜的电化学传感器，用于延长离子选择性电极的使用寿命。 凝胶膜是具有一面涂布特殊配制的凝胶层的亲水膜。 凝胶膜的凝胶涂层与离子选择膜紧密接触，并将离子选择性膜与测试样品和校准和清洁液分离。 凝胶膜是半透性屏障，其允许待测量的物质通过，同时抑制表面活性剂和蛋白质物质进入聚合物离子选择性膜。
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公开(公告)号：US06740225B2
公开(公告)日：2004-05-25
申请号：US09799969
申请日：2001-03-06
申请人： Bonnie Gurry , Meijun Shao , Laurie Dudik , Chung-Chiun Liu
发明人： Bonnie Gurry , Meijun Shao , Laurie Dudik , Chung-Chiun Liu
IPC分类号： G01N27333
CPC分类号： G01N27/4045 , G01N33/182
摘要： A thick film electrochemical microsensor device for measuring or regulating chlorine and bromine in water, comprising a substrate to which is applied an optimum arrangement of at least two electrodes. The device is especially useful for measuring or regulating chlorine and bromine levels in swimming pool or spa water. A method of measuring or regulating ions of at least one of chlorine and bromine in water is also described, which comprises contacting the water with the microsensor of the present invention; measuring the current output of the microsensor; determining the level of at least one of chlorine and bromine indicated by the current output; and generating a signal.
摘要翻译： 一种用于测量或调节水中氯和溴的厚膜电化学微传感器装置，包括施加至少两个电极的最佳布置的基底。 该设备对于测量或调节游泳池或水疗中的氯和溴水平尤其有用。 还描述了测量或调节水中氯和溴中的至少一种的离子的方法，其包括使水与本发明的微传感器接触; 测量微传感器的电流输出; 确定由当前输出指示的氯和溴中的至少一个的水平; 并产生信号。
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公开(公告)号：US06638404B2
公开(公告)日：2003-10-28
申请号：US09911290
申请日：2001-07-23
申请人： Masaaki Terashima , Osamu Seshimoto
发明人： Masaaki Terashima , Osamu Seshimoto
IPC分类号： G01N27333
CPC分类号： G01N27/333 , G01N27/307
摘要： In the manufacture of an ion selective electrode composed of a non-electroconductive support, a pair of electrodes each of which has a silver metal layer and a silver halide layer, an electrolytic material layer, an ion selective membrane, and a non-electroconductive sheet having a pair of openings for receiving a sample solution and a reference solution, respectively, and having thereon a bridge member for electrically connecting the sample solution received in one opening and the reference solution received in another opening, the ion selective membrane is advantageously divided into two separate portions, one of which is placed in a position above one electrode and another of which is placed in a position above another electrode.
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公开(公告)号：US06599409B1
公开(公告)日：2003-07-29
申请号：US09590781
申请日：2000-06-08
IPC分类号： G01N27333
CPC分类号： G01N27/401 , G01N27/30
摘要： A flowing junction reference electrode exhibiting heretofore unattainable potentiometric characteristics is described, comprising a microfluidic liquid junction member that is situated between a reference electrolyte solution and a sample solution. This microfluidic liquid junction member has an array of nanochannels spanning the member and physically connecting the reference electrolyte solution and a sample solution, but while the electrolyte solution flows through the array of nanochannels and into the sample solution at a linear velocity, the sample solution does not substantially enter the array of nanochannels via the mechanisms of diffusion, migration, convection or other known mechanisms. The number of nanochannels in the array is preferably between approximately 108 and approximately 100. Also preferably, the nanochannels are substantially straight and are substantially parallel to one another; such an array of nanochannels is herein described as anisotropic. The nanochannels are also preferably coated. The widths of any nanochannels in the array of nanochannels are preferably uniform, in that the width of any nanochannel is substantially equal to the width of any other nanochannels in the array. The nanochannels preferably have widths of greater than approximately 1 nanometer and less than approximately 500 nanometers, and most preferably of 70 nanometers. The electrode may be constructed out of any suitable material, and is preferably is constructed of a polymer, most preferably a polymer selected from the group consisting of polycarbonate and polyimide, and may also preferably be constructed of silicon, glass, or ceramic.
摘要翻译： 描述了迄今无法实现的电位特性的流动接合参考电极，其包括位于参考电解质溶液和样品溶液之间的微流体液体接合部件。 该微流体液接合部件具有横跨该部件的纳米通道的阵列并物理连接参考电解质溶液和样品溶液，但是当电解质溶液以线速度流过纳米通道阵列并进入样品溶液时，样品溶液 通过扩散，迁移，对流或其他已知机制的机制基本上不进入纳米通道阵列。 阵列中的纳米通道的数量优选在约108和约100之间。还优选地，纳米通道基本上是直的并且基本上彼此平行; 这种纳米通道阵列在此被描述为各向异性。 纳米通道也优选地被涂覆。 纳米通道阵列中的任何纳米通道的宽度优选是均匀的，因为任何纳米通道的宽度基本上等于阵列中任何其它纳米通道的宽度。 纳米通道优选具有大于约1纳米且小于约500纳米，最优选70纳米的宽度。 电极可以由任何合适的材料制成，并且优选由聚合物构成，最优选由聚碳酸酯和聚酰亚胺组成的组中选择的聚合物构成，并且还优选由硅，玻璃或陶瓷构成。
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公开(公告)号：US06579434B1
公开(公告)日：2003-06-17
申请号：US08714914
申请日：1996-09-17
IPC分类号： G01N27333
CPC分类号： G01N27/333
摘要： A free fluoride ion sensitive electrode with longer service life can be obtained by eliminating the use of any cement or similar adhesive to hold the fluoride sensing crystal of the electrode in place within the rest of the structure of the electrode, using instead a pressure sealed combination of the fluoride sensing crystal and upper and lower elastomeric gaskets. This arrangement also permits replacing the crystal and sealing gaskets if needed, without replacing any of the other components of the electrode.
摘要翻译： 可以通过消除使用任何水泥或类似粘合剂将电极的氟化物感应晶体保持在电极结构的其余部分内的适当位置，而不是使用压力密封组合来获得具有更长使用寿命的氟化物离子敏感电极 的氟化物感应晶体和上下弹性垫片。 如果需要，这种布置还可以替换晶体和密封垫圈，而不需要替换电极的其它部件。
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9.发明授权公开(公告)号：US06398931B1
公开(公告)日：2002-06-04
申请号：US09495084
申请日：2000-01-31
IPC分类号： G01N27333
CPC分类号： G01N27/4035 , G01N27/333
摘要： An improved combination ion-selective electrode apparatus is provided that comprises an electrode body, a reference electrode, and an ion-sensing electrode. The reference electrode comprises a ion-permeable junction. A removable membrane cap contains a ion-selective membrane. The membrane cap can be removed from the ion-selective electrode apparatus without endangering the integrity of the reference electrode and is distinct from the ion-permeable junction. The membrane cap contains a removable ion-sensitive membrane that can be replaced if the ion-sensitive membrane fails to thereby place the combination ion-selective electrode apparatus back into service. Moreover, a single combination ion-selective electrode apparatus can be used to measure a variety of analyte ions by simple replacement of the membrane cartridge.
摘要翻译： 提供了一种改进的组合离子选择性电极装置，其包括电极体，参比电极和离子感测电极。 参考电极包括离子可渗透结。 可移除的膜帽包含离子选择性膜。 膜帽可以从离子选择性电极装置中去除而不危及参考电极的完整性，并且不同于离子可渗透结。 膜帽包含可移除的离子敏感膜，如果离子敏感膜不能使组合离子选择性电极装置恢复使用，则可以更换。 此外，通过简单地更换膜盒，可以使用单组合离子选择性电极装置来测量各种分析物离子。
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公开(公告)号：US06328866B1
公开(公告)日：2001-12-11
申请号：US09220789
申请日：1998-12-28
IPC分类号： G01N27333
CPC分类号： G01N27/307 , G01N27/3335
摘要： An ion sensor and an ion sensor plate provided with an ion sensitive membrane which is characterized in that the ion sensitive membrane contains a material constituting the dissociation equilibrium of Ag/X, and an excessive quantity of an ion sensitive material or an anion scavenger. A coated film of surfactant is provided at the inner face of the passageway communicating with the test liquid-measuring electrode so as to add the surfactant to the test liquid. The plasticizer is added at a ratio of 65 to 80% by weight. The atomic ratio of silver and halogen in the silver halide layer is set to at least 1.2. The particle diameter of the modified silver halide layer is set to at most 1 &mgr;m.
摘要翻译： 一种具有离子敏感膜的离子传感器和离子传感器板，其特征在于，离子敏感膜含有构成Ag / X的解离平衡的材料和过量的离子敏感材料或阴离子清除剂。 在与测试液体测量电极连通的通道的内表面处提供表面活性剂的涂膜，以将表面活性剂加入到测试液中。 以65〜80重量％的比例添加增塑剂。 卤化银层中的银和卤素的原子比设定为至少1.2。 改性卤化银层的粒径设定为1μm以下。
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