Thermographic recording materials containing a mesionic 1,2,4-triazolium-3-thiolate compound
    92.
    发明申请
    Thermographic recording materials containing a mesionic 1,2,4-triazolium-3-thiolate compound 失效
    含有中分子1,2,4-三唑鎓-3-硫醇盐化合物的热成像记录材料

    公开(公告)号:US20050142506A1

    公开(公告)日:2005-06-30

    申请号:US11007487

    申请日:2004-12-08

    IPC分类号: G03C1/00 G03C1/498

    摘要: A substantially light-insensitive black and white monosheet thermographic recording material comprising a support and a thermosensitive element, the thermosensitive element containing a substantially light-insensitive organic silver salt, an organic reducing agent therefor in thermal working relationship therewith, a binder and at least one mesionic 1,2,4-triazolium-3-thiolate compound.

    摘要翻译: 一种基本上不透光的黑色和白色单片热成像记录材料,包括支撑体和热敏元件,该热敏元件含有基本上不光敏的有机银盐,与其热加工关系的有机还原剂,粘合剂和至少一种 中间体1,2,4-三唑鎓-3-硫醇化合物。

    Stabilizers for use in substantially light-insensitive thermographic recording materials
    93.
    发明授权
    Stabilizers for use in substantially light-insensitive thermographic recording materials 失效
    用于基本上不透光的温度记录材料的稳定剂

    公开(公告)号:US06902880B2

    公开(公告)日:2005-06-07

    申请号:US10705292

    申请日:2003-11-10

    摘要: A substantially light-insensitive black and white monosheet thermographic recording material comprising a support and a thermosensitive element, the thermosensitive element containing a substantially light-insensitive organic silver salt, an organic reducing agent therefor in thermal working relationship therewith, a binder and at least one stabilizer selected from the group consisting of 1-(5-mercapto-1-tetrazolyl)-acetyl compounds represented by formula (I): wherein R1 is —NR2R3, —OR4 or an optionally substituted aryl or heteroaryl group; R2 is hydrogen or an optionally substituted alkyl, aryl or heteroaryl group; R3 is an optionally substituted aryl or heteroaryl group; and R4 is an optionally substituted aryl group; and compounds with two or more groups represented by formula (II): where Q comprises the necessary atoms to form a 5- or 6-membered unsaturated heterocyclic ring, A is hydrogen, a counterion to compensate the negative charge of the thiolate group or two or more A groups provide a linking group between the two or more groups represented by formula (II).

    摘要翻译: 一种基本上不透光的黑色和白色单片热成像记录材料,包括支撑体和热敏元件,该热敏元件含有基本上不光敏的有机银盐,与其热加工关系的有机还原剂,粘合剂和至少一种 选自由式(I)表示的1-(5-巯基-1-四唑基) - 乙酰基化合物的稳定剂:其中R 1是-NR 2 R 2 或者任选取代的芳基或杂芳基; R 2是氢或任选取代的烷基,芳基或杂芳基; R 3是任选取代的芳基或杂芳基; R 4是任选取代的芳基; 和具有两个或更多个由式(II)表示的基团的化合物:其中Q包括形成5-或6-元不饱和杂环的必要原子,A是氢,用于补偿硫醇基或二价的负电荷的抗衡离子 或更多个A基团在由式(II)表示的两个或更多个基团之间提供连接基团。

    Thermographic recording material with improved print archivability without loss in printability
    94.
    发明授权
    Thermographic recording material with improved print archivability without loss in printability 有权
    具有改进的打印可归档性而不损失可打印性的热成像记录材料

    公开(公告)号:US06759367B2

    公开(公告)日:2004-07-06

    申请号:US10107378

    申请日:2002-03-27

    IPC分类号: B41M530

    CPC分类号: G03C1/4989 G03C1/49827

    摘要: A monosheet black and white substantially light-insensitive thermographic recording material comprising a thermosensitive element and a support, the thermosensitive element containing a substantially light-insensitive organic silver salt, a 3,4-dihydroxybenzene compound in thermal working relationship therewith and a binder, wherein the 3,4-dihydroxybenzene compound is an aryloxo-3,4-dihydroxybenzene compound in which the aryl-group is substituted with at least one substituent having a &sgr;m-value greater than 0; or a heteroaryloxo-3,4-dihydroxybenzene compound in which the heteroaryl group has a unified aromaticity index IA greater than 53 and is optionally substituted with at least one group selected from the group consisting of aryl, hydroxy, carboxy, sulfo, sulfoalkyl, sulfoaryl, sulfonylalkyl, sulfonylaryl, annulated aryl, annulated heteroaryl, carboxyalkyl, carboxyaryl, oxoalkyl, oxoaryl, halogen, nitro, cyano and mercapto-alkyl groups; and a thermographic recording process therefor.

    摘要翻译: 包含热敏元件和载体的单片黑色和白色基本上不光敏感的热敏成像记录材料,所述热敏元件含有基本上不光敏的有机银盐,与其热处理的3,4-二羟基苯化合物和粘合剂,其中 3,4-二羟基苯化合物是芳氧基-3,4-二羟基苯化合物,其中芳基被至少一个Sigmam值大于0的取代基取代; 或杂芳基氧-3,4-二羟基苯化合物,其中杂芳基具有大于53的统一芳香族指数IA,并且任选被至少一个选自芳基,羟基,羧基,磺基,磺基烷基,磺基芳基 磺酰基烷基,磺酰基芳基,环状芳基,环状杂芳基,羧基烷基,羧基芳基,氧代烷基,氧代芳基,卤素,硝基,氰基和巯基 - 烷基; 及其热成像记录方法。

    Thermographic recording material with improved image tone
    95.
    发明授权
    Thermographic recording material with improved image tone 失效
    具有改善图像色调的热成像记录材料

    公开(公告)号:US06686313B2

    公开(公告)日:2004-02-03

    申请号:US09996272

    申请日:2001-11-28

    IPC分类号: B41M530

    CPC分类号: G03C1/4989

    摘要: A monosheet black and white substantially light-insensitive thermographic recording material comprising a thermosensitive element and a support, the thermosensitive element containing a substantially light-insensitive organic silver salt and an organic reducing agent therefor in thermal working relationship therewith and a binder, wherein the thermographic recording material comprises a reaction product of an amino-group containing polymer and a compound according to formula (I): wherein each of R1, R2, R3 and R4 is independently hydrogen or an optionally substituted alkyl, aryl, heteroaryl, alkoxy or aryloxy group; L is a divalent linking group selected from the group consisting of oxygen and optionally substituted alkyl, aryl, heteroaryl, alkenyl and alkynyl groups; and m is either 0 or 1; and n is either 0 or 1; and a preparation process therefor.

    摘要翻译: 包含热敏元件和载体的单片黑色和白色基本上不光敏感的热敏成像记录材料,热敏元件含有基本上不光敏的有机银盐和与其进行热加工关系的有机还原剂和粘合剂,其中热敏成像 记录材料包含含氨基聚合物和根据式(I)的化合物的反应产物:其中R 1,R 2,R 3和R 4各自独立地为氢或 任选取代的烷基,芳基,杂芳基,烷氧基或芳氧基; L是选自氧和任选取代的烷基,芳基,杂芳基,烯基和炔基的二价连接基团; m为0或1; 且n为0或1; 及其制备工艺。

    Photothermographic recording material
    97.
    发明授权
    Photothermographic recording material 失效
    光热记录材料

    公开(公告)号:US06607872B1

    公开(公告)日:2003-08-19

    申请号:US09202256

    申请日:1999-06-14

    IPC分类号: G03C1498

    摘要: A photothermographic recording material comprising a photo-addressable thermally developable element coatable from aqueous media comprising a substantially light-insensitive organic silver salt, photosensitive silver halide in catalytic association with the substantially light-insensitive organic silver salt and a reducing agent in thermal working relationship with the substantially light-insensitive organic silver salt and a binder, characterized in that the binder comprises a water-soluble polymer, a water-dispersible polymer or a mixture of a water-soluble polymer and a water-dispersible polymer and particles of the photosensitive silver halide are non-aggregating in the photo-addressable thermally developable element and are uniformly distributed over and between particles of the substantially light-insensitive organic silver salt, at least 80% by number of the particles having a diameter, determined by transmission electron microscopy, of ≦40 nm; and a recording process therefor.

    摘要翻译: 一种光热记录材料,其包含可光寻址的可热显影元件,其由含有基本上不光敏的有机银盐的水性介质涂覆,光敏卤化银与基本上不受光敏感的有机银盐催化缔合,和与热处理关系的还原剂 基本上不光敏的有机银盐和粘合剂,其特征在于粘合剂包括水溶性聚合物,水分散性聚合物或水溶性聚合物和水分散性聚合物的混合物以及感光性银颗粒 卤化物在光寻址热可显影元件中是非聚集的,并且均匀地分布在基本上不受光的有机银盐的颗粒之间和之间,至少80%的具有通过透射电子显微镜测定的直径的颗粒, 的<= 40nm; 及其记录过程。

    Thermographic recording material with improved image tone
    98.
    发明授权
    Thermographic recording material with improved image tone 失效
    具有改善图像色调的热成像记录材料

    公开(公告)号:US06586363B2

    公开(公告)日:2003-07-01

    申请号:US09995281

    申请日:2001-11-27

    IPC分类号: B41M530

    摘要: A substantially light-insensitive black and white thermographic recording material comprising a thermosensitive element and a support, the thermosensitive element containing at least one substantially light-insensitive organic silver salt, an organic reducing agent therefor in thermal working relationship therewith, an image tone stabilizer and a binder, wherein the image tone stabilizer is a compound according to formula (I): wherein R1 is hydrogen, an alkali metal ion, an ammonium ion, a phosphonium ion, a sulphonium ion, an alkaline earth ion or an optionally substituted alkyl, cycloalkyl, heterocyclic, alkaryl, aralkyl, heteroaryl or aryl group; R2 is an optionally substituted alkyl, cycloalkyl, heterocyclic, alkaryl, aralkyl, heteroaryl or aryl group; or R1 and R2 together represent the atoms necessary to form a ring structure; and X is hydrogen, an alkali metal ion, an ammonium ion, a phosphonium ion, a sulphonium ion or an alkaline earth ion; and a recording process therefor.

    摘要翻译: 包含热敏元件和支持体的基本上不透光的黑白热成像记录材料,所述热敏元件含有至少一种基本上不光敏的有机银盐,与其热加工关系的有机还原剂,图像色调稳定剂和 粘合剂,其中所述图像稳定剂是根据式(I)的化合物:其中R1是氢,碱金属离子,铵离子,鏻离子,锍离子,碱土金属离子或任选取代的烷基, 环烷基,杂环,烷芳基,芳烷基,杂芳基或芳基; R2是任选取代的烷基,环烷基,杂环,烷芳基,芳烷基,杂芳基或芳基; 或者R1和R2一起表示形成环结构所必需的原子; X为氢,碱金属离子,铵离子,鏻离子,锍离子或碱土金属离子; 及其记录过程。

    Photothermographic materials with increa sed photosensitivity

    公开(公告)号:US06576415B2

    公开(公告)日:2003-06-10

    申请号:US09928755

    申请日:2001-08-13

    IPC分类号: G03C1498

    CPC分类号: G03C1/49845

    摘要: A process for producing an aqueous dispersion comprising: preparing a dispersion of photosensitive silver halide and a binder or a surfactant in an aqueous medium; and subsequently either (a) adding a first silver salt to the silver halide dispersion and then adding a second silver salt; or (b) adding the second silver salt to the silver halide dispersion and then adding the first silver salt, wherein the aqueous dispersion is substantially free of a water-soluble metal or ammonium salt of an aliphatic carboxylic acid with greater than 12 carbon atoms, the first silver salt is a substantially light-insensitive and substantially water-insoluble silver salt of an organic carboxylic acid, and the second silver salt has a water-solubility greater than 0.1 g in 1 L of water at 20° C.; an aqueous dispersion obtainable therewith; a photothermographic recording material prepared with the aqueous dispersion; and a process for preparing the photothermographic recording material. In addition the use of the second silver salt for increasing the sensitivity of a photothermographic recording material is provided.

    Photosensitive silver halide element comprising chemically sensitized emulsion grains and method to prepare them
    100.
    发明授权
    Photosensitive silver halide element comprising chemically sensitized emulsion grains and method to prepare them 失效
    包含化学敏化乳剂颗粒的感光卤化银元件及其制备方法

    公开(公告)号:US06316176B1

    公开(公告)日:2001-11-13

    申请号:US09621962

    申请日:2000-07-21

    IPC分类号: G03C109

    摘要: A method has been described of chemically sensitizing a silver halide emulsion having silver halide grains and a binder, comprising the steps of adding thereto, besides a chemically sensitizing agent providing sulphur, an organo-tellurium sensitizing compound providing tellurium in a molar ratio amount versus sulphur of less than 0.30. A light-sensitive silver halide photographic element has also been described which has been made highly sensitive by chemically sensitizing a silver halide emulsion which has been made highly sensitive by the method described hereinbefore.

    摘要翻译: 已经描述了对具有卤化银颗粒和粘合剂的卤化银乳剂进行化学敏化的方法,包括以下步骤:除了提供硫的化学增感剂之外,向其中加入有机碲致敏化合物,其提供摩尔比与硫的碲 小于0.30。 还描述了一种感光卤化银照相元件,其已经通过使通过上述方法高度敏感的卤化银乳剂化学增感而被高度敏感。