Herbicidal sulphonylamino(thio)carbonyl compounds
    92.
    发明授权
    Herbicidal sulphonylamino(thio)carbonyl compounds 失效
    除草磺酰氨基(硫代)羰基化合物

    公开(公告)号:US06525211B1

    公开(公告)日:2003-02-25

    申请号:US09838812

    申请日:2001-04-20

    IPC分类号: C07C30941

    摘要: The invention relates to novel sulphonylamino(thio)carbonyl compounds of the formula (I), in which A represents a single bond, oxygen, sulphur or the group N—R, in which R represents hydrogen, alkyl, alkenyl, alkinyl or cycloalkyl, Q represents oxygen or sulphur, R1 represents hydrogen or formyl or represents in each case optionally substituted alkyl, alkenyl, alkinyl, alkylcarbonyl, alkoxycarbonyl, alkylsulphonyl, cycloalkyl, cycloalkylcarbonyl or cycloalkylsulphonyl, R2 represents cyano or halogen or represents in each case optionally substituted alky, alkenyl, alkinyl, alkoxy, alkenyloxy or alkinyloxy, and R3 represents in each case optionally substituted heterocyclyl having 5 ring members of which at least one is oxygen, sulphur or nitrogen and from one to three further ring members can be nitrogen, and salts of compounds of the formula (I), the previously known compounds 4,5-dimethoxy-2-(2,5-dimethoxy-phenylsulphonylaminocarbonyl)-2,4-dihydro-3H-1,2,4-triazol-3-one, 4,5-diethoxy-2-(2,5-dimethoxy-phenylsulphonylaminocarbonyl)-2,4-dihydro-3H-1,2,4-triazol-3-one and N-(2,5-dimethoxy-phenylsulphonyl)-1,5-dimethyl-1H-pyrazole-3-carboxamide being excluded by disclaimer; and also to processes and novel intermediates for the preparation of the novel substances and to their use as herbicides.

    摘要翻译: 本发明涉及式(I)的新型磺酰基氨基(硫代)羰基化合物,其中A表示单键,氧,硫或基团NR,其中R表示氢,烷基,烯基,炔基或环烷基,Q表示氧 或硫,R1表示氢或甲酰基,或表示在各种情况下任选取代的烷基,烯基,炔基,烷基羰基,烷氧基羰基,烷基磺酰基,环烷基,环烷基羰基或环烷基磺酰基,R2表示氰基或卤素,或表示在各情况下任选取代的烷基,烯基,炔基 ,烷氧基,烯氧基或烷氧基,R 3在各自的情况下表示具有5个环成员的任选取代的杂环基,其中至少一个是氧,硫或氮,并且一至三个其它的环成员可以是氮, I),先前已知的化合物4,5-二甲氧基-2-(2,5-二甲氧基 - 苯基磺酰基氨基羰基)-2,4-二氢-3H-1,2,4-三唑-3-酮,4,5-二乙氧基 -2-(2,5-二 甲氧基 - 苯基磺酰基氨基羰基)-2,4-二氢-3H-1,2,4-三唑-3-酮和N-(2,5-二甲氧基 - 苯基磺酰基)-1,5-二甲基-1H-吡唑-3-甲酰胺 被排除在免责声明之外;还涉及用于制备新物质和用作除草剂的方法和新型中间体。

    Herbicidal sulphonylamino(thio)carbonyl compounds
    94.
    发明授权
    Herbicidal sulphonylamino(thio)carbonyl compounds 有权
    除草磺酰氨基(硫)羰基化合物

    公开(公告)号:US06251831B1

    公开(公告)日:2001-06-26

    申请号:US09223246

    申请日:1998-12-30

    IPC分类号: A01N43653

    摘要: The invention relates to novel sulphonylamino(thio)carbonyl compounds of the formula (I), in which A represents a single bond, oxygen, sulphur or the group N—R, in which R represents hydrogen, alkyl, alkenyl, alkinyl or cycloalkyl, Q represents oxygen or sulphur, R1 represents hydrogen or formyl or represents in each case optionally substituted alkyl, alkenyl, alkinyl, alkylcarbonyl, alkoxycarbonyl, alkylsulphonyl, cycloalkyl, cycloalkylcarbonyl or cycloalkylsulphonyl, R2 represents cyano or halogen or represents in each case optionally substituted alkyl, alkenyl, alkinyl, alkoxy, alkenyloxy or alkinyloxy, and R3 represents in each case optionally substituted heterocyclyl having 5 ring members of which at least one is oxygen, sulphur or nitrogen and from one to three further ring members can be nitrogen, and salts of compounds of the formula (I), the previously known compounds 4,5-dimethoxy-2-(2,5-dimethoxy-phenylsulphonylaminocarbonyl)-2,4-dihydro-3H-1,2,4-triazol-3-one, 4,5-diethoxy-2-(2,5-dimethoxy-phenylsulphonylaminocarbonyl)-2,4-dihydro-3H-1,2,4-triazol-3-one and N-(2,5-dimethoxy-phenylsulphonyl)-1,5-dimethyl-1H-pyrazole-3-carboxamide being excluded by disclaimer; and also to processes and novel intermediates for the preparation of the novel substances and to their use as herbicides.

    摘要翻译: 本发明涉及式(I)的新型磺酰基氨基(硫代)羰基化合物,其中A表示单键,氧,硫或基团NR,其中R表示氢,烷基,烯基,炔基或环烷基,Q表示氧 或硫,R 1表示氢或甲酰基或在每种情况下表示任选取代的烷基,烯基,炔基,烷基羰基,烷氧基羰基,烷基磺酰基,环烷基,环烷基羰基或环烷基磺酰基,R 2表示氰基或卤素,或表示在各种情况下任选取代的烷基,烯基, ,烷氧基,烯氧基或烷氧基,R 3在各自的情况下表示具有5个环成员的任选取代的杂环基,其中至少一个是氧,硫或氮,并且一至三个其它的环成员可以是氮, I),先前已知的化合物4,5-二甲氧基-2-(2,5-二甲氧基 - 苯基磺酰基氨基羰基)-2,4-二氢-3H-1,2,4-三唑-3-酮,4,5-二乙氧基 -2-(2,5-d 苯并磺酰基氨基羰基)-2,4-二氢-3H-1,2,4-三唑-3-酮和N-(2,5-二甲氧基 - 苯基磺酰基)-1,5-二甲基-1H-吡唑-3-甲酰胺 由免责声明排除;以及用于制备新物质和用作除草剂的方法和新型中间体。

    Process for the preparation of alkoxytriazolinones
    96.
    发明授权
    Process for the preparation of alkoxytriazolinones 失效
    制备烷氧基三唑啉酮的方法

    公开(公告)号:US5606070A

    公开(公告)日:1997-02-25

    申请号:US528585

    申请日:1995-09-15

    IPC分类号: C07D249/12

    CPC分类号: C07D249/12

    摘要: Alkoxytriazolinones of the general formula (I), ##STR1## in which R.sup.1 and R.sup.2 independently of one another represent in each case optionally substituted alkyl, alkenyl, alkinyl, cycloalkyl, cycloalkylalkyl, aryl or arylalkyl,(which can be used as intermediates for the preparation of herbicidal active compounds) are obtained in very good yields and in high purity by reacting iminothiocarbonic diester (II) with carbazinic esters (III) ##STR2## in which R.sup.3 and R.sup.4 in each case represent, for example, alkyl or aryl, at -20.degree. C. to +50.degree. C. (1st step) and subjecting the semicarbazide derivatives (IV) formed in this process with elimination of R.sup.3 -SH ##STR3## to a cyclizing condensation reaction and if appropriate in the presence of a base at 20.degree. C. to 100.degree. C. with elimination of R.sup.4 --OH, if appropriate after intermediate isolation (2nd step).

    摘要翻译: 通式(I)的烷氧基​​三唑啉酮,其中R 1和R 2彼此独立地表示在各种情况下为任选取代的烷基,烯基,炔基,环烷基,环烷基烷基,芳基或芳烷基(其可以用作 用于制备除草活性化合物的中间体)以非常好的产率和高纯度通过亚氨基碳二酸酯(II)与咔嗪酸酯(III)反应获得,其中R 3和R 4在每种情况下代表例如烷基或 芳基,在-20℃至+ 50℃(第一步),并将在该过程中形成的氨基脲衍生物(IV)与R3-SH的消除进行环化缩合反应,并且如果在适当的情况下存在 的碱在20℃至100℃,如果适当,在中间分离(第二步)后消除R4-OH。

    Thienysulfonylamino (thio) carbonyl compounds
    100.
    发明授权
    Thienysulfonylamino (thio) carbonyl compounds 有权
    噻吩磺酰氨基(硫)羰基化合物

    公开(公告)号:US06383988B1

    公开(公告)日:2002-05-07

    申请号:US09319021

    申请日:1999-06-01

    IPC分类号: A01N43653

    摘要: The invention relates to novel thienylsulphonylamino(thio)carbonyl compounds of the formula (I), in which Q represents oxygen or sulphur, R1 represents cyano, halogen or in each case optionally cyano-, halogen- or C1-C4-alkoxy-substituted alkyl, alkenyl, alkinyl, alkoxy, alkenyloxy or alkinyloxy having in each case up to 6 carbon atoms, R2 represents cyano, halogen or in each case optionally cyano-, halogen- or C1-C4-alkoxy-substituted alkyl, alkenyl, alkinyl, alkoxy, alkenyloxy or alkinyloxy having in each case up to 6 carbon atoms, and R3 represents in each case optionally substituted heterocyclyl having 5 ring members, at least one of which represents oxygen, sulphur or nitrogen and one to three others may represent nitrogen, and salts of compounds of the formula (I), to processes and novel intermediates for preparing the novel compounds and to their use as herbicides.

    摘要翻译: 本发明涉及式(I)的新型噻吩基磺酰基氨基(硫代)羰基化合物,其中Q表示氧或硫,R 1表示氰基,卤素或在各种情况下任选为氰基,卤素或C 1 -C 4烷氧基取代的烷基, 烯基,炔基,烷氧基,烯氧基或烷氧基,每种情况下最多6个碳原子,R 2代表氰基,卤素或在各种情况下任选为氰基,卤素或C 1 -C 4烷氧基取代的烷基,烯基,炔基,烷氧基, 在每种情况下具有至多6个碳原子的烯氧基或链烯氧基,R 3在每种情况下表示任选取代的具有5个环成员的杂环基,其中至少一个表示氧,硫或氮,并且一至三个表示氮,化合物的盐 式(I)的方法,用于制备新化合物和用作除草剂的新型中间体。