公开(公告)号：US5021546A

公开(公告)日：1991-06-04

申请号：US536049

申请日：1990-06-11

Applicant: David R. Fagerburg ,  Mark Rule ,  Joseph J. Watkins ,  Paul B. Lawrence

Inventor： David R. Fagerburg ,  Mark Rule ,  Joseph J. Watkins ,  Paul B. Lawrence

IPC: C08G75/02 ,  C08G75/14

CPC classification number: C08G75/0227 ,  C08G75/0263 ,  C08G75/14

Abstract: A process for producing elemental iodine and a copoly(arylene sulfide) corresponding to the structure ##STR1## wherein y is in the range of 0.001 to 0.15, x is in the range of 0.02 to 0.65 and n is at least 100, consisting essentially of (1) reacting at a temperature above about 175.degree. C., a mixture of diiodobenzene and diiodobiphenyl and elemental sulfur to produce the copoly(arylene sulfide), and (2) recovering the elemental iodine.

Abstract translation: 对应于结构 + TR 的元素碘和共聚（亚芳基硫醚）的方法，其中y在0.001至0.15的范围内，x在0.02至0.65的范围内，n至少为 100，基本上由（1）在高于约175℃的温度下反应，二碘苯和二碘联苯和元素硫的混合物产生共聚（亚芳基硫醚），和（2）回收元素碘。

公开(公告)号：US4845273A

公开(公告)日：1989-07-04

申请号：US188113

申请日：1988-04-25

Applicant: Guy R. Steinmetz ,  Mark Rule

Inventor： Guy R. Steinmetz ,  Mark Rule

IPC: C07C51/10

CPC classification number: C07C51/10

Abstract: Disclosed is a process for the production of aromatic carboxylic acids by the carbonylation of aromatic iodides in the presence of a rhodium catalyst and a Bronsted base in a hydrocarbon carboxylic acid reaction medium.

Abstract translation: 公开了在烃羧酸反应介质中在铑催化剂和布朗斯台德碱存在下通过芳族碘化物的羰基化生产芳族羧酸的方法。

公开(公告)号：US4649216A

公开(公告)日：1987-03-10

申请号：US889458

申请日：1986-07-25

Applicant: Mark Rule ,  Thomas H. Larkins, Jr. ,  Donald W. Lane ,  Guy R. Steinmetz

Inventor： Mark Rule ,  Thomas H. Larkins, Jr. ,  Donald W. Lane ,  Guy R. Steinmetz

IPC: C07C51/10 ,  C07C67/36

CPC classification number: C07C51/10

Abstract: This invention relates to a novel carbonylation process for the production of aromatic carboxylic acids. More particularly, this invention relates to a process for the carbonylation of aromatic iodides with carbon monoxide in the presence of a nickel catalyst in a hydrocarbon carboxylic acid reaction medium to prepare aromatic carboxylic acids.

Abstract translation: 本发明涉及用于生产芳族羧酸的新的羰基化方法。 更具体地，本发明涉及在烃羧酸反应介质中在镍催化剂存在下用一氧化碳羰基化芳族碘化物以制备芳族羧酸的方法。