摘要:
Novel hyper-branched, dense, high-refractive-index polymers, and compositions utilizing those polymers are provided, along with methods of forming high refractive index films with those compositions. The refractive index of the material is at least about 1.8 at 400 nm. Further, it can be made into optically transparent thin films of only a couple hundred angstroms thickness to thick films of several micrometers thick, as well as into “bulk” solids. The use of a thermal acid or a photo acid generator facilitates crosslinking after the coating process.
摘要:
The present invention provides optical parts having good impact resistance, good adhesiveness between the substrate and a thin film layer coating formed thereon, good scratch resistance and good antireflection capabilities. The thin film layer coating composition comprises (1) a dithian ring containing sulfur compound and/or a benzene ring containing sulfur compound, and (2) a polyfunctional thiol compound.
摘要:
Poly(biphenylene sulfide/poly(phenylene sulfide) copolymers are produced by contacting a p-dihalobenzene and a bis-p-halobiphenyl under polymerization condiditons. Additionally a poly(biphenylene sulfide)/poly(phenylene sulfide) copolymer/fiber reinforced composite is provided.
摘要:
A process for preparation of a copoly(arylene sulfide) corresponding to the structure ##STR1## wherein A is a divalent substituted or unsubstituted aromatic radical, T is a monovalent aromatic radical, x is in the range of 0.5 to 0.001 and n is an integer from 1 to 100.
摘要:
Disclosed herein is a melt-stable poly(arylene thioether-ketone) composition, which comprises:(A) 100 parts by weight of a melt-stable poly(arylene thioether-ketone) having predominant recurring units of the formula ##STR1## and having a melting point, Tm of 310.degree.-380.degree. C., a residual melt crystallization enthalpy, .DELTA.Hmc (420.degree. C./10 min) of at least 10 J/g, a melt crystallization temperature, Tmc (420.degree. C./10 min) of at least 210.degree. C. and a reduced viscosity of 0.2-2 dl/g;(B) 0-400 parts by weight of at least one of thermoplastic resins; and(C) at least one of fibrous fillers and/or at least one of inorganic fillers in a proportion of 0-400 parts by weight per 100 parts by weight of the sum of said components (A) and (B).At least either one of the components (B) or (C) is contained in a proportion of at least 0.1 part by weight per 100 parts by weight of the component (A).
摘要:
Poly(arylene sulfide) compositions heat curable to products exhibiting improved high temperature properties are provided comprising a minor amount of alkyl-substituted cyclic repeating units and a major amount of cyclic repeating units free of alkyl substituents. The copolymers can be blended with arylene sulfide homopolymers to provide compositions exhibiting improved curing characteristics, as well as being combined with various fillers to provide coating compositions and laminates formed therefrom.
摘要:
To provide: a method of manufacturing granular polyarylene sulfide (PAS) with improved particle strength while improving the yield of the granular PAS by introducing and recovering PAS with a moderate molecular weight in granular PAS; and granular PAS.A method of manufacturing granular PAS according to the present invention includes: a polymerizing step of subjecting a dihalo aromatic compound and at least one type of sulfur source selected from the group consisting of alkali metal sulfides and alkali metal hydrosulfides to polymerization reaction in an organic amide solvent; and a cooling step of cooling the reaction product mixture after the polymerizing step. Addition of a phase separation agent to the reaction product mixture is started at a point in time from the start of the polymerizing step to before the start of forming granular PAS in the cooling step, and when the temperature of the reaction product mixture is 245° C. or higher, 50 mass % or greater of the phase separation agent is added to the reaction product mixture. The polymerizing step includes a predetermined PAS prepolymer generating step, and a predetermined converting step to a high molecular weight PAS.