公开(公告)号：US20120104373A1

公开(公告)日：2012-05-03

申请号：US13283936

申请日：2011-10-28

Applicant: Hideko Inoue ,  Satoko Shitagaki ,  Satoshi Seo

Inventor： Hideko Inoue ,  Satoko Shitagaki ,  Satoshi Seo

IPC: H01L51/54 ,  C07F15/00

CPC classification number: C07F15/0033 ,  C07F15/0086 ,  C09K11/06 ,  C09K2211/1044 ,  C09K2211/1088 ,  C09K2211/185 ,  H01L51/0085 ,  H05B33/14

Abstract: An object is to provide a novel organometallic complex capable of phosphorescence and having high heat resistance. Alternatively, an object is to provide a light-emitting device with high added value. The objects are achieved by providing an organometallic complex which has a structure represented by a general formula (G1) or (G2) below and is formed in such a way that a corresponding one of pyrazine derivatives represented by general formulae (G0) and (G0′) below is ortho-metalated by a Group 9 or Group 10 metal ion, or by providing a light-emitting element and a light-emitting device including the organometallic complex.

Abstract translation: 目的是提供一种能够发光并具有高耐热性的新型有机金属络合物。 或者，目的在于提供具有高附加值的发光装置。 通过提供具有由下述通式（G1）或（G2）表示的结构的有机金属络合物来实现，其目的是使通式（G0）和（G0）表示的相应的吡嗪衍生物 '）通过第9族或第10族金属离子进行邻金属化，或者通过提供包含有机金属络合物的发光元件和发光器件。

公开(公告)号：US20120098417A1

公开(公告)日：2012-04-26

申请号：US13277603

申请日：2011-10-20

Applicant: Hideko Inoue ,  Tomoya Yamaguchi ,  Satoko Shitagaki ,  Takahiro Ushikubo ,  Satoshi Seo ,  Yui Yamada ,  Hiromi Nowatari

Inventor： Hideko Inoue ,  Tomoya Yamaguchi ,  Satoko Shitagaki ,  Takahiro Ushikubo ,  Satoshi Seo ,  Yui Yamada ,  Hiromi Nowatari

IPC: H05B33/14 ,  C07F15/00

CPC classification number: H01L51/0085 ,  C07F15/0033 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/1011 ,  C09K2211/1044 ,  C09K2211/185 ,  H01L27/18 ,  H01L27/3244 ,  H01L27/3283 ,  H01L51/009 ,  H01L51/5012 ,  H01L51/5016 ,  H01L51/5044 ,  H01L51/5278 ,  H01L2251/5361 ,  H05B33/14

Abstract: Provided is a novel substance that can emit phosphorescence. Alternatively, provided is a novel substance with high emission efficiency. An organometallic complex in which a 4-arylpyrimidine derivative is a ligand and iridium is a central metal is provided. Specifically, an organometallic complex having a structure represented by a general formula (G1) is provided. In the general formula (G1), R1 represents a substituted or unsubstituted alkyl group having 1 to 4 carbon atoms or a substituted or unsubstituted aryl group having 6 to 10 carbon atoms, R2 represents any of hydrogen, a substituted or unsubstituted alkyl group having 1 to 4 carbon atoms, and a substituted or unsubstituted phenyl group, R3 represents hydrogen or a substituted or unsubstituted alkyl group having 1 to 4 carbon atoms, and Ar1 represents a substituted or unsubstituted arylene group having 6 to 10 carbon atoms.

Abstract translation: 提供可以发射磷光的新物质。 或者，提供了具有高排放效率的新型物质。 提供其中4-芳基嘧啶衍生物为配体和铱为中心金属的有机金属配合物。 具体地说，提供具有由通式（G1）表示的结构的有机金属络合物。 在通式（G1）中，R 1表示取代或未取代的碳原子数1〜4的烷基或取代或未取代的碳数为6〜10的芳基，R 2表示氢，取代或未取代的烷基， 至4个碳原子，以及取代或未取代的苯基，R 3表示氢或取代或未取代的碳原子数1〜4的烷基，Ar 1表示取代或未取代的碳数为6〜10的亚芳基。

公开(公告)号：US08128727B2

公开(公告)日：2012-03-06

申请号：US11939003

申请日：2007-11-13

Applicant: Ryoji Nomura ,  Satoshi Seo ,  Hideko Inoue ,  Kaoru Kato

Inventor： Ryoji Nomura ,  Satoshi Seo ,  Hideko Inoue ,  Kaoru Kato

IPC: C22B5/20 ,  H01J9/50

CPC classification number: C22B7/006 ,  C22B3/10 ,  C22B11/042 ,  C22B61/00 ,  H01L51/56 ,  Y02P10/214 ,  Y02P10/234

Abstract: It is an object of the present invention to collect a scarce metal such as iridium from a light-emitting element which is no longer used. A method for collecting a metal is provided in which an organic metal compound which can emit visible light from a triplet excited state at room temperature is heated, or an EL layer of a light-emitting layer containing an organic metal compound which can emit visible light from a triplet excited state at room temperature is dissolved in a solvent to form a solution, and the solution is heated, irradiated with microwaves or treated with acid water. According to the above method, resources of metals such as iridium or platinum, which are scarce metals, can be utilized efficiently.

Abstract translation: 本发明的目的是从不再使用的发光元件中收集诸如铱的稀缺金属。 提供了一种用于收集金属的方法，其中可以在室温下从三重激发态发出可见光的有机金属化合物被加热，或者含有可发射可见光的有机金属化合物的发光层的EL层 从室温下的三重激发态溶解在溶剂中形成溶液，将溶液加热，用微波照射或用酸水处理。 根据上述方法，可以有效地利用作为稀有金属的诸如铱或铂的金属的资源。

公开(公告)号：US08084145B2

公开(公告)日：2011-12-27

申请号：US11092816

申请日：2005-03-29

Applicant: Hideko Inoue ,  Satoko Shitagaki ,  Satoshi Seo

Inventor： Hideko Inoue ,  Satoko Shitagaki ,  Satoshi Seo

IPC: H01L51/54 ,  C09K11/06

CPC classification number: C09K11/06 ,  C07F15/0033 ,  C09K2211/1007 ,  C09K2211/1044 ,  C09K2211/185 ,  H01L51/0085 ,  H01L51/5016 ,  H05B33/14 ,  Y10S428/917

Abstract: An organometallic complex comprising a moiety represented by the following general formula (1). The organometallic complex is applied to a light-emitting element, and a light-emitting device reduced in power consumption is manufactured by using the light-emitting element. (where R1 to R4 are individually any one of hydrogen, a halogen atom, an acyl group, an alkyl group, an alkoxyl group, an aryl group, a cyano group, and a heterocyclic group, Ar is one of an aryl group having an electron-withdrawing group and a heterocyclic group having electron-withdrawing group, and M is one of an element of Group 9 and an element of Group 10)

Abstract translation: 一种包含由以下通式（1）表示的部分的有机金属络合物。 有机金属配合物被应用于发光元件，通过使用发光元件来制造功耗降低的发光装置。 （式中，R 1〜R 4分别为氢，卤原子，酰基，烷基，烷氧基，芳基，氰基，杂环基中的任一个，Ar为具有 吸电子基团和具有吸电子基团的杂环基，M是第9族元素和第10族元素之一）

公开(公告)号：US20110245495A1

公开(公告)日：2011-10-06

申请号：US13079936

申请日：2011-04-05

Applicant: Hideko Inoue ,  Tomoka Nakagawa ,  Satoshi Seo

Inventor： Hideko Inoue ,  Tomoka Nakagawa ,  Satoshi Seo

IPC: C07F15/00

CPC classification number: C07F15/0033 ,  C07F15/0086 ,  C09K11/06 ,  C09K2211/1044 ,  C09K2211/185 ,  H01L51/0085 ,  H01L51/0087 ,  H01L51/5016

Abstract: An object is to provide a novel organometallic complex capable of emitting phosphorescence by using, as a ligand, an organic compound with which a variety of derivatives can be easily synthesized. Another object is to provide an organometallic complex having high heat resistance. Other objects are to provide a light-emitting element having high emission efficiency and to provide a light-emitting device, an electronic device, and a lighting device having reduced power consumption. Provided are an organometallic complex including a structure represented by the following General Formula (G1), and a light-emitting element, a light-emitting device, an electronic device, and a lighting device formed using the organometallic complex including the structure represented by the following General Formula (G1).

Abstract translation: 目的是提供一种能够通过使用可以容易地合成各种衍生物的有机化合物作为配体来提供能够发射磷光的新型有机金属配合物。 另一个目的是提供一种具有高耐热性的有机金属络合物。 其他目的是提供一种具有高发射效率的发光元件，并提供具有降低的功耗的发光装置，电子装置和照明装置。 提供了包含由以下通式（G1）表示的结构的有机金属络合物，以及发光元件，发光器件，电子器件和使用包含由 遵循通式（G1）。

公开(公告)号：US07960038B2

公开(公告)日：2011-06-14

申请号：US11431648

申请日：2006-05-09

Applicant: Nobuharu Ohsawa ,  Hideko Inoue ,  Satoshi Seo ,  Satoko Shitagaki

Inventor： Nobuharu Ohsawa ,  Hideko Inoue ,  Satoshi Seo ,  Satoko Shitagaki

IPC: H01L51/54 ,  H05B33/12

CPC classification number: H01L51/0085 ,  C09K11/025 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/1022 ,  C09K2211/1029 ,  C09K2211/1044 ,  C09K2211/185 ,  H01L51/0072 ,  H01L51/009 ,  H01L51/5016 ,  H01L51/5052 ,  H05B33/14 ,  Y10S428/917

Abstract: The light emitting element includes a first electrode and a second electrode, between which a light emitting layer, a hole transporting layer provide in contact with the light emitting layer, an electron transporting layer provided in contact with the light emitting layer, and a mixed layer provided between the electron transporting layer and the second electrode. The mixed layer includes an electron transporting substance and a substance showing an electron donating property with respect to the electron transporting substance. The light emitting layer includes an organometallic complex represented in General Formula (1) and a host. R1 and R2 each represent an electron-withdrawing substituent group. R3 and R4 each represent any of hydrogen or an alkyl group having 1 to 4 carbon atoms. L represents any of a monoanionic ligand having a beta-diketone structure, a monoanionic bidentate chelating ligand having a carboxyl group, or a monoanionic bidentate chelating ligand having a phenolic hydroxyl group.

Abstract translation: 发光元件包括第一电极和第二电极，在该第一电极和第二电极之间，发光层，与发光层接触的空穴传输层，与发光层接触设置的电子传输层，以及混合层 设置在电子传输层和第二电极之间。 该混合层包括电子传输物质和相对于电子传输物质显示给电子性的物质。 发光层包括通式（1）表示的有机金属络合物和主体。 R1和R2各自表示吸电子取代基。 R 3和R 4各自表示氢或碳原子数为1〜4的烷基中的任一个。 L表示具有β-二酮结构的单阴离子配体，具有羧基的单阴离子二齿螯合配体或具有酚羟基的单阴离子二齿螯合配体中的任一种。

公开(公告)号：US20100181905A1

公开(公告)日：2010-07-22

申请号：US12688075

申请日：2010-01-15

Applicant: Hideko Inoue ,  Satoshi Seo ,  Nobuharu Ohsawa

Inventor： Hideko Inoue ,  Satoshi Seo ,  Nobuharu Ohsawa

IPC: H01J1/63 ,  C07F15/00

CPC classification number: C07F15/0033 ,  C09K11/06 ,  C09K2211/1044 ,  C09K2211/185 ,  H05B33/14

Abstract: To provide a novel organometallic complex capable of emitting phosphorescence by using an organic compound with which a variety of derivatives can be easily synthesized as a ligand. In addition, to provide an organometallic complex which exhibits red emission. To provide an organometallic complex formed by ortho-metalation of an m-alkoxyphenyl pyrazine derivative represented by General Formula (G0) below with respect to an ion of a metal belonging to Group 9 or Group 10. In addition, to provide an organometallic complex which exhibits red emission formed by ortho-metalation of an m-alkoxyphenyl pyrazine derivative represented by General Formula (G0) below with respect to an ion of a metal belonging to Group 9 or Group 10.

Abstract translation: 通过使用可以容易地合成各种衍生物作为配体的有机化合物来提供能够发射磷光的新的有机金属配合物。 另外，提供显示红色发射的有机金属络合物。 提供通过下述通式（G0）表示的间 - 烷氧基苯基吡嗪衍生物相对于属于第9族或第10族的金属的离子进行邻位金属化而形成的有机金属络合物。此外，为了提供一种有机金属络合物， 表示通过下述通式（G0）表示的间 - 烷氧基苯基吡嗪衍生物相对于属于第9族或第10族的金属的离子进行邻位金属化而形成的红色发射。

公开(公告)号：US20100117068A1

公开(公告)日：2010-05-13

申请号：US12691003

申请日：2010-01-21

Applicant: Hideko Inoue ,  Satoshi Seo

Inventor： Hideko Inoue ,  Satoshi Seo

IPC: H01L51/52 ,  H01L51/54

CPC classification number: H01L51/009 ,  C07F15/0033 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/1014 ,  C09K2211/1044 ,  C09K2211/185 ,  H01L27/3209 ,  H01L51/008 ,  H01L51/0085 ,  H01L51/5016 ,  H01L51/5036

Abstract: It is an object of the present invention to provide a substance which can emit red phosphorescence which is closer to the chromaticity coordinates of red according to the NTSC standard. The present invention provides an organometallic complex represented by the general formula (1), wherein each of R1 to R3 represents any one of hydrogen, a halogen group, an acyl group, an alkyl group, an alkoxyl group, an aryl group, a cyano group, and a heterocyclic group, and at least one of R1 to R3 represents an electron-withdrawing group; and M represents a Group 9 element or a Group 10 element, and when M is the Group 9 element, n=2, whereas when M is the Group 10 element, n=1. Such an organometallic complex can emit red phosphorescence with good spectral luminous efficiency which is closer to the chromaticity coordinates of red according to the NTSC standard.

Abstract translation: 本发明的目的是提供一种可以发射红色磷光的物质，其更接近于根据NTSC标准的红色的色度坐标。 本发明提供由通式（1）表示的有机金属配合物，其中，R 1〜R 3各自表示氢，卤素基，酰基，烷基，烷氧基，芳基，氰基 基和杂环基，并且R 1至R 3中的至少一个表示吸电子基团; 并且M表示第9族元素或第10族元素，并且当M为第9族元素时，n = 2，而当M为第10族元素时，n = 1。 这样的有机金属络合物可以发射红色磷光，具有良好的光谱发光效率，其更接近于根据NTSC标准的红色的色度坐标。

公开(公告)号：US20080261477A1

公开(公告)日：2008-10-23

申请号：US11939003

申请日：2007-11-13

Applicant: Ryoji Nomura ,  Satoshi Seo ,  Hideko Inoue ,  Kaoru Kato

Inventor： Ryoji Nomura ,  Satoshi Seo ,  Hideko Inoue ,  Kaoru Kato

IPC: H01J9/50

CPC classification number: C22B7/006 ,  C22B3/10 ,  C22B11/042 ,  C22B61/00 ,  H01L51/56 ,  Y02P10/214 ,  Y02P10/234

Abstract: It is an object of the present invention to collect a scarce metal such as iridium from a light-emitting element which is no longer used. A method for collecting a metal is provided in which an organic metal compound which can emit visible light from a triplet excited state at room temperature is heated, or an EL layer of a light-emitting layer containing an organic metal compound which can emit visible light from a triplet excited state at room temperature is dissolved in a solvent to form a solution, and the solution is heated, irradiated with microwaves or treated with acid water. According to the above method, resources of metals such as iridium or platinum, which are scarce metals, can be utilized efficiently.

Abstract translation: 本发明的目的是从不再使用的发光元件中收集诸如铱的稀缺金属。 提供了一种用于收集金属的方法，其中可以在室温下从三重激发态发出可见光的有机金属化合物被加热，或者含有可发射可见光的有机金属化合物的发光层的EL层 从室温下的三重激发态溶解在溶剂中形成溶液，将溶液加热，用微波照射或用酸水处理。 根据上述方法，可以有效地利用作为稀有金属的诸如铱或铂的金属的资源。

公开(公告)号：US20080149923A1

公开(公告)日：2008-06-26

申请号：US11986949

申请日：2007-11-27

Applicant: Nobuharu Ohsawa ,  Hideko Inoue ,  Satoshi Seo

Inventor： Nobuharu Ohsawa ,  Hideko Inoue ,  Satoshi Seo

IPC: H01L51/54

CPC classification number: H05B33/14 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/1011 ,  C09K2211/1029 ,  C09K2211/1044 ,  C09K2211/185 ,  H01L51/006 ,  H01L51/0072 ,  H01L51/0081 ,  H01L51/0085 ,  H01L51/5016 ,  H01L2251/5384 ,  H01L2251/552

Abstract: Light-emitting elements having high emission efficiency and long lifetime can be provided. By forming light-emitting devices including the light-emitting elements, the light-emitting devices having low power consumption and long lifetime can be provided. A light-emitting device comprises a light-emitting element including a light-emitting layer between a first electrode and a second electrode. The light-emitting layer includes a first organic compound having a hole-transporting property, a second organic compound having an electron transporting property, and an organometallic complex. A central metal of the organometallic complex is an element belonging to one of Group 9 and Group 10, and a ligand of the organometallic complex is a ligand having a pyrazine skeleton.

Abstract translation: 可以提供发光效率高，使用寿命长的发光元件。 通过形成包括发光元件的发光器件，可以提供具有低功耗和长寿命的发光器件。 发光装置包括在第一电极和第二电极之间包括发光层的发光元件。 发光层包括具有空穴传输性的第一有机化合物，具有电子传输性的第二有机化合物和有机金属络合物。 有机金属络合物的中心金属是属于第9族和第10族之一的元素，有机金属络合物的配体是具有吡嗪骨架的配体。