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111.发明授权
公开(公告)号：US4640964A
公开(公告)日：1987-02-03
申请号：US741514
申请日：1985-06-05
申请人： Marvin M. Johnson , Max P. McDaniel
发明人： Marvin M. Johnson , Max P. McDaniel
CPC分类号： C08F10/00
摘要： A catalyst support based on aluminum polyphosphate or polyphosphoric acid-impregnated alumina is provided by two alternative techniques. In the first embodiment, an aluminum polyphosphate composition is heated in a dry atmosphere and thereafter impregnated with a zerovalent chromium component under anhydrous conditions. The resulting catalyst is active for olefin polymerization. In the second embodiment, alumina is impregnated with a polyphosphoric acid composition. This resulting polyphosphoric acid impregnated alumina can be used as a support for zerovalent chromium or can be impregnated with a chromium component and oxidized to give an active hexavalent chromium species. The resulting catalysts are advantageous because of their unusual sensitivity to hydrogen thus allowing great leeway in molecular weight control.
摘要翻译： 通过两种替代技术提供了基于聚磷酸铝或多磷酸浸渍的氧化铝的催化剂载体。 在第一实施方案中，将聚磷酸铝组合物在干燥气氛中加热，然后在无水条件下用零价铬组分浸渍。 所得催化剂对于烯烃聚合是有活性的。 在第二实施方案中，用多磷酸组合物浸渍氧化铝。 所得多磷酸浸渍的氧化铝可用作零价铬的载体，或可用铬成分浸渍并氧化，得到活性六价铬物质。 所得到的催化剂是有利的，因为它们对氢气具有不寻常的敏感性，从而允许在分子量控制方面具有很大的余地。
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公开(公告)号：US4596862A
公开(公告)日：1986-06-24
申请号：US685528
申请日：1984-12-24
CPC分类号： C08F10/00 , C08F210/16
摘要： Ethylene polymer is particularly suitable for the production of tough film is produced under slurry conditions using a fluorided aluminophosphate support and a reaction temperature within the range of 93.degree. to 107.degree. C. in the presence of hydrogen and a small amount of trialkyl boron cocatalyst wherein said aluminophosphate has a phosphorous to aluminum ratio within the very narrow range of 0.15 to 0.4 and wherein said aluminophosphate carrying chromium catalyst is being activated at a temperature within the range of 482.degree. to 704.degree. C. The resulting film is not only substantially superior to film made from the best of the readily available commercial resins but is also better than film made from polymers using a similar catalyst system without the specific combination of parameters of this invention.
摘要翻译： 乙烯聚合物特别适用于在氢气和少量三烷基硼助催化剂存在下，在浆液条件下使用氟化磷酸铝载体和反应温度在93至107℃的范围内制备韧性膜，其中 所述磷酸铝在0.15〜0.4的非常窄的范围内具有磷与铝的比例，并且其中所述载有铬的磷酸铝催化剂在482℃至704℃的温度下活化。所得膜不仅基本上优于 由最容易获得的市售树脂制成的薄膜，但是也优于使用类似催化剂体系的聚合物制成的薄膜，而没有本发明的参数的具体组合。
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113.发明授权Olefin polymerization using activated chromium catalyst treated with tertiary alcohol 失效使用用叔醇处理的活化铬催化剂进行烯烃聚合
公开(公告)号：US4559394A
公开(公告)日：1985-12-17
申请号：US635080
申请日：1984-07-27
申请人： Max P. McDaniel
发明人： Max P. McDaniel
摘要： A catalyst is produced by contacting an already activated silica-titania supported chromium composition with a tertiary alcohol and thereafter reactivating under relatively mild conditions. Such contacting is conveniently carried out by forming a slurry of the catalyst in an inert diluent containing a small amount of the alcohol. The resulting catalyst is useful in olefin polymerization. In such polymerization operations, the catalyst offers the advantage of allowing polymerization at a lower reactor temperature to achieve a given melt flow.
摘要翻译： 通过使已经活化的二氧化钛 - 二氧化钛负载的铬组合物与叔醇接触，然后在相对温和的条件下再活化来制备催化剂。 这种接触方便地通过在含有少量醇的惰性稀释剂中形成催化剂浆料来进行。 所得催化剂可用于烯烃聚合。 在这种聚合操作中，催化剂提供了在较低的反应器温度下进行聚合以获得给定的熔体流动的优点。
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公开(公告)号：US4504638A
公开(公告)日：1985-03-12
申请号：US549511
申请日：1983-11-07
申请人： Max P. McDaniel , Marvin M. Johnson
发明人： Max P. McDaniel , Marvin M. Johnson
IPC分类号： C08F10/00 , C08F4/44 , C08F4/24 , C08F4/62 , C08F110/02
CPC分类号： C08F10/00
摘要： In accordance with one embodiment of this invention, a chromium catalyst supported on an aluminum phosphate-containing base is used in conjunction with a boron component either as a part of the base or as a cocatalyst. The resulting catalyst is unique both in its favorable sensitivity to molecular weight control agents such as hydrogen and in its ability to produce a fundamentally different olefin polymer. In accordance with another embodiment of this invention, the chromium is supported on a phosphate base produced using a melt of the aluminum salt.
摘要翻译： 根据本发明的一个实施方案，负载在含磷酸铝的碱上的铬催化剂与作为碱的一部分的硼组分或作为助催化剂一起使用。 所得催化剂在其对分子量控制剂如氢气的良好的敏感性以及其产生基本上不同的烯烃聚合物的能力方面是独特的。 根据本发明的另一个实施方案，将铬负载在使用铝盐熔体制备的磷酸盐基底上。
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公开(公告)号：US4503201A
公开(公告)日：1985-03-05
申请号：US573161
申请日：1984-01-23
申请人： Max P. McDaniel , Phil M. Stricklen
发明人： Max P. McDaniel , Phil M. Stricklen
IPC分类号： C08F10/02 , C08F4/24 , C08F4/06 , C08F110/02
CPC分类号： C08F10/02 , Y10S526/907
摘要： A silica composition is calcined at a temperature high enough to remove some but not all of the hydroxyl content. Generally temperatures of at least 400.degree. C. are required and temperatures above 1000.degree. C. are undesirable, the most preferred temperature being about 600.degree.-800.degree. C. The thus calcined silica is then treated with chromyl chloride at an elevated temperature and finally given a treatment in a carbon monoxide ambient. While the final composition contains chlorine which is normally considered a catalyst poison, the material is surprisingly active as an olefin polymerization catalyst.
摘要翻译： 将二氧化硅组合物在足够高的温度下煅烧以除去一些但不是全部的羟基含量。 通常需要至少400℃的温度，高于1000℃的温度是不期望的，最优选的温度为约600℃-800℃。然后将经煅烧的二氧化硅在高温下用氯化铬处理，最后 给予一氧化碳环境中的处理。 虽然最终组合物含有通常被认为是催化剂毒物的氯，但该材料作为烯烃聚合催化剂具有令人惊奇的活性。
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公开(公告)号：US4489172A
公开(公告)日：1984-12-18
申请号：US500752
申请日：1983-06-03
申请人： Max P. McDaniel
发明人： Max P. McDaniel
摘要： A catalyst is produced by contacting an already activated silica-titania supported chromium composition with a tertiary alcohol and thereafter reactivating under relatively mild conditions. Such contacting is conveniently carried out by forming a slurry of the catalyst in an inert diluent containing a small amount of the alcohol.
摘要翻译： 通过使已经活化的二氧化钛 - 二氧化钛负载的铬组合物与叔醇接触，然后在相对温和的条件下再活化来制备催化剂。 这种接触方便地通过在含有少量醇的惰性稀释剂中形成催化剂浆料来进行。
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公开(公告)号：US4444964A
公开(公告)日：1984-04-24
申请号：US423596
申请日：1982-09-27
申请人： Max P. McDaniel , Marvin M. Johnson
发明人： Max P. McDaniel , Marvin M. Johnson
CPC分类号： C08F10/00
摘要： In accordance with one embodiment of this invention, a chromium catalyst supported on an aluminum phosphate-containing base is used in conjunction with a boron component either as a part of the base or as a cocatalyst. The resulting catalyst is unique both in its favorable sensitivity to molecular weight control agents such as hydrogen and in its ability to produce a fundamentally different olefin polymer. In accordance with another embodiment of this invention, the chromium is supported on a phosphate base produced using a melt of the aluminum salt.
摘要翻译： 根据本发明的一个实施方案，负载在含磷酸铝的碱上的铬催化剂与作为碱的一部分的硼组分或作为助催化剂一起使用。 所得催化剂在其对分子量控制剂如氢气的良好的敏感性以及其产生基本上不同的烯烃聚合物的能力方面是独特的。 根据本发明的另一个实施方案，将铬负载在使用铝盐熔体制备的磷酸盐基底上。
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118.发明授权Polymerization process using surface heat treated silica-containing catalyst base 失效使用表面热处理二氧化硅的催化剂基团的聚合方法
公开(公告)号：US4434280A
公开(公告)日：1984-02-28
申请号：US427255
申请日：1982-09-29
申请人： Max P. McDaniel , M. Bruce Welch
发明人： Max P. McDaniel , M. Bruce Welch
CPC分类号： B01J23/26 , B01J21/063 , C08F10/02
摘要： A silica base for a chromium olefin polymerization catalyst is subjected to a high temperature treatment as for instance by passing the silica through a flame in order to alter the surface characteristics. The chromium can be present during the flame treatment or added later. The result is a catalyst capable of giving a broader molecular weight distribution polymer which is of particular value with the silica-titania coprecipitated catalyst used in slurry olefin polymerization.
摘要翻译： 对铬烯烃聚合催化剂的二氧化硅基料进行高温处理，例如通过使二氧化硅通过火焰以改变表面特性。 铬可以在火焰处理期间存在或稍后加入。 结果是能够产生更广泛的分子量分布聚合物的催化剂，其与用于淤浆烯烃聚合中的二氧化硅 - 二氧化钛共沉淀催化剂具有特别的价值。
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119.发明授权Polymerization process using chromium on a support treated with titanium polymer 失效在用钛聚合物处理的载体上使用铬的聚合方法
公开(公告)号：US4405768A
公开(公告)日：1983-09-20
申请号：US422780
申请日：1982-09-24
申请人： Max P. McDaniel
发明人： Max P. McDaniel
CPC分类号： C08F10/00
摘要： A catalyst suitable for olefin polymerization is produced by combining an inorganic support with a titanium polymer to produce a support for chromium-containing catalyst. The resulting chromium-containing catalyst is activated in a conventional manner. This process allows incorporation of relatively high concentrations of titanium which is beneficial in achieving high melt index values in slurry polymerization systems.
摘要翻译： 通过将无机载体与钛聚合物组合以产生含铬催化剂的载体来制备适用于烯烃聚合的催化剂。 所得到的含铬催化剂以常规方式活化。 该方法允许引入相对高浓度的钛，这有利于实现淤浆聚合体系中的高熔体指数值。
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公开(公告)号：US4397761A
公开(公告)日：1983-08-09
申请号：US221752
申请日：1980-12-31
申请人： Max P. McDaniel , Marvin M. Johnson
发明人： Max P. McDaniel , Marvin M. Johnson
IPC分类号： B01J27/198 , B01J31/14 , C08F10/00 , B01J23/22 , C08F4/02
CPC分类号： B01J31/143 , C08F10/00
摘要： A supported vanadium catalyst comprising a vanadium compound on a phosphate-containing base. This catalyst in conjunction with an organoaluminum cocatalyst is capable of giving good activity and producing a polymer having broad molecular weight distribution. The catalyst system is sufficiently sensitive to hydrogen to allow broad leeway in controlling the molecular weight of the resulting polymers.
摘要翻译： 在含磷酸盐的碱上含有钒化合物的负载型钒催化剂。 该催化剂与有机铝助催化剂结合能够提供良好的活性并产生具有宽分子量分布的聚合物。 催化剂体系对氢足够敏感，以便在控制所得聚合物的分子量方面具有广泛的余地。
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