Abstract:
Cellulosic pulps are bleached with ozone in an ozone bleaching stage in an aqueous medium containing an additive in an effective amount not exceeding 5% weight concentration of the aqueous medium. The additive is selected from a group consisting of N-alkylated ureas, N-alkylated lactams and N-alkylated amides. pH in the Z stage is operated under conventional ozone bleaching conditions, but preferably at high consistency and at low temperature, below 5.degree. C.
Abstract:
A chemical pulp which contains reactants capable of generating dioxirane within the pulp is produced in a process which comprises mixing a pulp with reactants comprising a carbonyl compound, preferably acetone, and an oxygen donor, preferably monoperoxysulfate, in proportions which produce a water-soluble dioxirane having a molecular diameter of less than 140 angstrom units. Such a pulp bleaching process which employs dioxirane as a bleaching agent is rendered environmentally and economically acceptable by recycling the reactants employed to produce the dioxirane.
Abstract:
A method of bleaching a chemical pulp by adjusting the pH of the pulp to 1.5-3.5, chelating the pulp and then treating the pulp in an N stage with nitric oxide (NO) in the amount of at least 1.5% by weight of the oven dried pulp at a consistency of between 30 and 55% and further treating the pulp in a Z stage with ozone to produce a bleach pulp having a higher viscosity for a given permanganate number compared with a similar pulp bleached without using the N stage.
Abstract:
Process for color stripping and bleaching of colored waste paper by treatment by means of monoperoxysulphuric acid or of one of its salts, according to which the treatment is performed in the presence of a halide ion.
Abstract:
A process is provided for peroxygen bleaching of high yield pulp in which sodium carbonate replaces sodium hydroxide and sodium silicate. The process employs a chelating agent as a substitute for the silicate normally required so that the process can operate as a closed cycle system.
Abstract:
Delignification and bleaching of lignocellulosic material is enhanced after the pulp has been treated with peroxomonosulfuric acid. The starting pH of the reaction with peroxomonosulfuric acid is between 7 and 11, and the reaction is continued until a final pH of 3 to 5 obtained. Subsequently the pulp is delignified and bleached with peroxide and/or oxygen.
Abstract:
The present invention provides a process for bleaching and delignifying cellulose-containing products with peroxides and/or oxygen and/or ozone, wherein there is additionally used 0.01 to 2.5% by weight of cyanamide and/or cyanamide salts, referred to the dry weight of the cellulose.
Abstract:
A METHOD FOR THE DELIGNIFICATION AND BLEACHING OF LIGNOCELLULOSIC MATERIALS UNDER THE ACTION OF OXYGEN AND ALKALI IN AN ALKALINE MEDIUM AND IN THE PRESENCE OF FROM ABOUT 0.005% TO ABOUT 5.0%, BY WEIGHT, BASED ON THE WEIGHT OF SAID MATERIAL, OF A COPPER-CONTAINING MATERIAL WHICH CONVERTS, AT LEAST IN PART, TO COPPER OXIDE IN THE PRESENCE OF SAID ALKALI IN SAID ALKALINE MEDIUM.
Abstract:
Delignification and bleaching of chemical pulp is achieved by treating the pulp in a single stage with oxygen at elevated temperature and pressure in the presence of a protector selected from the group consisting of Na2S2O4 and Na2Sx, where x is an integer from 1 to 4.
Abstract translation:化学纸浆的脱木质素和漂白是通过在选自Na 2 S 2 O 4和Na 2 S x的保护剂存在下,在升高的温度和压力下用氧处理单阶段的纸浆来实现的,其中x是1至4的整数。