Process for producing elastomeric acetal polymers
    12.
    发明授权
    Process for producing elastomeric acetal polymers 失效
    生产弹性体缩醛聚合物的方法

    公开(公告)号:US4937312A

    公开(公告)日:1990-06-26

    申请号:US448746

    申请日:1989-12-11

    IPC分类号: C08G2/18

    CPC分类号: C08G2/18

    摘要: There are provided new elastomeric copolymers of about 15 to 45 mol %, preferably about 25 to 35 mol % trioxane, about 55 to 85 mol %, preferably about 65 to 75 mol % of 1,3-dioxolane, said mol percents based on the total of trioxane and 1,3-dioxolane, and about 0.005 to 0.15 wt. %, preferably about 0.05 to 0.12 wt. % of 1,4-butanediol diglycidyl ether or butadiene diepoxide as a bifunctional monomer, based on the total weight of copolymer. The elastomeric copolymers may be prepared by mixing said monomers in a substantially dry state and under an inert atmosphere with a cationic polymerization catalyst, e.g., p-nitrobenzenediazonium tetrafluoroborate. The elastomeric copolymers have a strong interaction with moldable, crystalline acetal polymers comprising at least 85 mol % of polymerized oxymethylene units and may be used as a blending agent with such crystalline acetal polymers or as a bonding agent to improve the adhesiveness of the crystalline acetal polymer to other materials.

    摘要翻译: 提供了约15至45摩尔%,优选约25至35摩尔%三恶烷,约55至85摩尔%,优选约65至75摩尔%的1,3-二氧戊环的新的弹性体共聚物,所述摩尔百分比基于 三恶烷和1,3-二氧戊环的总量,以及约0.005至0.15wt。 %,优选约0.05至0.12wt。 %的1,4-丁二醇二缩水甘油醚或丁二烯二环氧化物作为双功能单体,基于共聚物的总重量。 弹性体共聚物可以通过将基本上干燥的状态和惰性气氛下的所述单体与阳离子聚合催化剂如对硝基苯基氮鎓四氟硼酸盐混合来制备。 弹性体共聚物与包含至少85摩尔%的聚合甲醛单元的可模塑的结晶缩醛聚合物具有强相互作用,并且可以用作与这种结晶缩醛聚合物或粘合剂的共混剂,以改善结晶缩醛聚合物的粘合性 到其他材料。