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11.发明授权Process for making ethers from alkoxide anions or precursors of alkoxide anions 有权从醇盐阴离子或醇盐阴离子前体制备醚的方法公开(公告)号：US08957256B2
公开(公告)日：2015-02-17
申请号：US12680022
申请日：2008-09-22
摘要： Improved methods for making ethers. In particular, an alkoxide can be more effectively converted into an ether by reaction with a hydrocarbyl halide in the presence of a substantial excess of a hygroscopic base such as NaOH. When present in such an unconventional excess, the base serves multiple functions. As a consequence, the alkoxide is extensively converted to the desired ether rapidly at excellent yields. The reaction environment also aids later product isolation. The use of the NaOH rather than Na metal allows the ether product to be separated from water soluble impurities such as salt products, left over base, left over hydrocarbyl halide, formates, etc. by liquid-liquid extraction among aqueous and organic phases.
摘要翻译： 改进制备醚的方法。 特别地，在大量过量的吸湿性碱如NaOH的存在下，通过与烃基卤化物反应，可以更有效地将醇盐转化为醚。 当这种非常规的超量存在时，该基座具有多种功能。 因此，醇盐以极好的收率快速地转化为所需的醚。 反应环境还有助于后期产品分离。 使用NaOH而不是Na金属允许醚产物与水溶性杂质如盐产物分离，残留在碱，残留在烃基卤化物，甲酸盐等上，通过液相萃取在水相和有机相中。
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公开(公告)号：US08569530B2
公开(公告)日：2013-10-29
申请号：US13078889
申请日：2011-04-01
摘要： Various embodiments of the present invention are directed to processes and methods for converting lipids comprising fatty acids into fatty esters. According to various embodiments of the invention, the saponifiable lipids are reacted with a base to form alkali soaps. The alkali soaps are then reacted with an acid to form fatty esters. Both the base reaction and the acid reaction may occur in the presence of one or more alcohols. Following the acid reaction, a solvent may be added to effect a separation of the fatty esters, which may then be recovered.
摘要翻译： 本发明的各种实施方案涉及将包含脂肪酸的脂质转化成脂肪酯的方法和方法。 根据本发明的各种实施方案，可皂化的脂质与碱反应形成碱性皂。 然后将碱皂与酸反应形成脂肪酯。 碱反应和酸反应都可以在一种或多种醇的存在下进行。 在酸反应之后，可以加入溶剂以分解脂肪酯，然后可以回收脂肪酯。
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