公开(公告)号：US07022884B2

公开(公告)日：2006-04-04

申请号：US10203836

申请日：2001-02-16

申请人： Thomas Ostrowski ,  Kathrin Harre ,  Georg Heinrich Grosch ,  Jürgen Winkler

发明人： Thomas Ostrowski ,  Kathrin Harre ,  Georg Heinrich Grosch ,  Jürgen Winkler

IPC分类号： C07C41/03

CPC分类号： B01J27/26 ,  B01J19/18 ,  B01J2219/00085 ,  B01J2219/00092 ,  B01J2219/00094 ,  C08G65/2663 ,  C08G65/2696

摘要： Polyetherpolyols are prepared by reacting diols or polyols with ethylene oxide, propylene oxide, butylene oxide or a mixture thereof in the presence of a multimetal cyanide complex catalyst by a process which is carried out in a vertical, highly cylindrical reactor having a central stirrer and having heat exchanger plates through which a heat-exchange medium flows and which are arranged essentially in the longitudinal direction of the reactor, at an angle α of from 0 to 70° in the direction of rotation of the stirrer relative to the reactor radius.

摘要翻译： 聚醚多元醇通过二醇或多元醇与环氧乙烷，环氧丁烷，环氧丁烷或其混合物在多金属氰化物配合物催化剂存在下反应来制备，所述方法是在具有中心搅拌器的垂直，高度圆柱形的反应器中进行，并且具有 热交换介质流过热交换介质，其基本上沿反应器的纵向布置，在搅拌器相对于反应器半径的旋转方向上以0至70°的角度α。

公开(公告)号：US06673972B2

公开(公告)日：2004-01-06

申请号：US10169683

申请日：2002-07-05

申请人： Thomas Ostrowski ,  Kathrin Harre ,  Peter Zehner ,  Jörn Müller ,  Dieter Stützer ,  Georg Heinrich Grosch ,  Jürgen Winkler ,  Stephan Bauer

发明人： Thomas Ostrowski ,  Kathrin Harre ,  Peter Zehner ,  Jörn Müller ,  Dieter Stützer ,  Georg Heinrich Grosch ,  Jürgen Winkler ,  Stephan Bauer

IPC分类号： C07C4311

CPC分类号： C08G65/2696 ,  B01J27/26 ,  C08G65/2663

摘要： Polyetherpolyols are prepared by reacting diols or polyols with ethylene oxide, propylene oxide, butylene oxide or a mixture thereof in the presence of a multimetal cyanide complex catalyst by a process which is carried out in a vertical upright cylindrical reactor comprising a jet nozzle which is arranged in the upper reactor region and is directed downward and via which the starting materials and the reaction mixture are fed in, and comprising a take-off, preferably in the lower reactor region, via which the reaction mixture is fed back to the jet nozzle in an external circulation by means of a pump via an equilibration container, comprising a concentric guide tube which extends over the total length of the reactor, except for the reactor ends, and comprising a heat exchanger integrated in the annular space.

摘要翻译： 聚醚多元醇通过二元醇或多元醇与环氧乙烷，环氧丙烷，环氧丁烷或其混合物在多金属氰化物配合物催化剂存在下反应来制备，该方法是在包括喷嘴的立式圆柱形反应器中进行的方法， 在上反应器区域中并且向下引导起始材料和反应混合物，并且优选在较低的反应器区域中包含起飞物料，反应混合物经反应器区域被反馈到喷嘴中 通过平衡容器通过泵的外部循环，包括在反应器的整个长度上延伸的同心引导管，除了反应器端部，并且包括集成在环形空间中的热交换器。