公开(公告)号：US5128005A

公开(公告)日：1992-07-07

申请号：US796757

申请日：1991-11-25

申请人： William R. Jones ,  Petr Jandik ,  Michael Merion ,  Andrea Weston

发明人： William R. Jones ,  Petr Jandik ,  Michael Merion ,  Andrea Weston

IPC分类号： G01N27/447

CPC分类号： G01N27/44721

摘要： A technique for separating, identifying and measuring ions in solution by capillary zone electrophoresis is described, which provides improved sensitivity and resolution of anionic and cationic species. The method involves introducing a sample containing the ionic species into a narrow core capillary filled with a carrier electrolyte containing a selected light-absorbing anion or cation to an electrical current in a capillary column causing the ions to elute according to their ionic mobility. Both UV absorbing and UV-transparent ions can be detected and quantitated by UV/Visible photometric monitoring.

摘要翻译： 描述了通过毛细管区域电泳分离，鉴定和测量溶液中的离子的技术，其提供阴离子和阳离子物质的改进的灵敏度和分辨率。 该方法包括将含有离子物质的样品引入填充有含有选择的吸光阴离子或阳离子的载体电解质的窄芯毛细管中，使毛细管柱中的电流根据其离子迁移率而洗脱。 可以通过紫外/可见光度监测来检测和定量UV吸收和UV透明离子。

公开(公告)号：US5104506A

公开(公告)日：1992-04-14

申请号：US471535

申请日：1990-01-29

申请人： William R. Jones ,  Petr Jandik ,  Michael Merion

发明人： William R. Jones ,  Petr Jandik ,  Michael Merion

IPC分类号： G01N27/447

CPC分类号： G01N27/44721

摘要： A technique for separating, identifying and measuring ions in solution by capillary zone electrophoresis is described, which provides improved sensitivity and resolution of anionic species. The method involves subjecting a sample containing the ionic species a light-absorbing material and a quaternary ammonium salt to an electrical current in a capillary column causing the ions to elute according to their ionic mobility. The ionic species are detected and quantitated by UV/Visible photometric monitoring.

摘要翻译： 描述了通过毛细管区带电泳分离，鉴定和测量溶液中的离子的技术，其提供阴离子物质的改进的灵敏度和分辨率。 该方法包括使含有离子物质的样品为光吸收材料和季铵盐的毛细管柱中的电流，使得离子根据其离子迁移率而洗脱。 通过UV /可见光度监测来检测和定量离子物质。

公开(公告)号：US4699718A

公开(公告)日：1987-10-13

申请号：US821154

申请日：1986-01-21

申请人： William R. Jones ,  Allan L. Heckenberg ,  Petr Jandik

发明人： William R. Jones ,  Allan L. Heckenberg ,  Petr Jandik

IPC分类号： G01N30/02 ,  B01D15/08 ,  G01N30/96

CPC分类号： G01N30/96

摘要： A method and apparatus for the simultaneous analysis of borate and chloride ions in a liquid sample, such as a sample of nuclear reactor water, by ion chromatographic techniques are disclosed. The ion chromatographic system employed includes an exclusion column, an anion exchange column, and means for alternately directing effluent from said exclusion column to refractive index detecting means or void volume from the exclusion column and second eluent through the anion exchange column to conductivity detecting means.

摘要翻译： 公开了一种通过离子色谱技术同时分析液体样品中的硼酸盐和氯离子的方法和装置，例如核反应堆水样品。 所使用的离子色谱系统包括排除柱，阴离子交换柱和用于将来自所述排阻柱的流出物交替地引导至折射率检测装置或排除柱的空隙体积和通过阴离子交换柱至导电性检测装置的第二洗脱液的装置。