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11.
公开(公告)号:US4670535A
公开(公告)日:1987-06-02
申请号:US875044
申请日:1986-06-17
申请人: Akitoshi Sugio , Takao Kawaki , Katsushige Hayashi
发明人: Akitoshi Sugio , Takao Kawaki , Katsushige Hayashi
IPC分类号: C08G73/00 , C08F290/00 , C08F299/02 , C08G73/10 , C08G73/12 , G03F7/038 , C08G16/00
CPC分类号: C08G73/1082 , G03F7/0387
摘要: The photosensitive polyimide precursor of the invention has a recurring unit represented by the following general formula [I]: ##STR1## (R.sub.1 represents a tetravalent aromatic hydrocarbon residue; R.sub.2 and R.sub.3 each represent a divalent aromatic or aliphatic hydrocarbon residue; and R.sub.4 represents a divalent aromatic hydrocarbon residue represented by ##STR2## wherein R.sub.5, R.sub.6, R.sub.7, R.sub.8, R.sub.9, R.sub.10, R.sub.11 and R.sub.12, identical or different, each represent hydrogen atom, a halogen group or an alkyl group). The photosensitive polyimide precursor of the invention has a viscosity of 50 centipoises or above as measured at 23.degree. C. in the state of a 10% (by weight) solution in N,N-dimethylacetamide. Its photosensitivity is as high as about 20-100 times that of prior products. After heat cyclization, it exhibits a heat resistance of 400.degree. C. or above.The photosensitive polyimide precursor of the invention can be produced by subjecting a tetracarboxylic acid dianhydride and a diamino compound to a polycondensation reaction in an organic polar solvent.
摘要翻译: 本发明的光敏聚酰亚胺前体具有由以下通式[I]表示的重复单元:(R 1表示四价芳烃残基; R 2和R 3各自表示二价芳族或脂族烃 R4代表由下式表示的二价芳烃残基:其中R5,R6,R7,R8,R9,R10,R11和R12相同或不同,分别代表氢原子,卤素基团或烷基)。 本发明的光敏聚酰亚胺前体在23℃下的粘度为10厘泊(N,N-二甲基乙酰胺)溶液的状态下的粘度为50厘泊或更高。 其光敏度高达现有产品的约20-100倍。 热环化后,其耐热性为400℃以上。 本发明的感光性聚酰亚胺前体可以通过在有机极性溶剂中使四羧酸二酐和二氨基化合物进行缩聚反应来制造。
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公开(公告)号:US06255436B1
公开(公告)日:2001-07-03
申请号:US09444933
申请日:1999-11-22
申请人: Masatoshi Kimura , Michio Kawai , Hiroshi Takeguchi , Hiroshi Nakano , Masayuki Nakajima , Katsushige Hayashi
发明人: Masatoshi Kimura , Michio Kawai , Hiroshi Takeguchi , Hiroshi Nakano , Masayuki Nakajima , Katsushige Hayashi
IPC分类号: C08G6400
CPC分类号: C08G64/307
摘要: An aromatic polycarbonate of the present invention is produced by reacting an aromatic dihydroxy compound with a compound capable of introducing a carbonate bond, and has a viscosity-average molecular weight of 12,000 to 40,000 and a content of a cyclic oligomer represented by the formula (1) of not more than 1,000 ppm, in which the percentage of the content of said cyclic oligomer represented by the formula (1) based on the total contents of the cyclic oligomer represented by the formula (1), an oligomer represented by the formula (2) and an oligomer represented by the formula (3) satisfies the following relational formula [I]: 0
摘要翻译: 本发明的芳香族聚碳酸酯是通过使芳香族二羟基化合物与能够引入碳酸酯键的化合物反应而制造的,粘均分子量为12,000〜40,000,由式(1)表示的环状低聚物的含量 )不超过1000ppm,其中由式(1)表示的所述环状低聚物的含量的百分比基于由式(1)表示的环状低聚物的总含量,由式(1)表示的低聚物 2)和式(3)表示的低聚物满足以下关系式[I]:其中(1),(2)和(3)是由上式(1),(2)表示的低聚物的含量, 和(3)分别; Mv是所述芳族聚碳酸酯的粘均分子量。
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公开(公告)号:US5380907A
公开(公告)日:1995-01-10
申请号:US69604
申请日:1993-06-01
IPC分类号: B01J27/08 , B01J27/13 , B01J31/04 , B01J31/12 , B01J31/24 , C07B61/00 , C07C68/00 , C07C69/96
CPC分类号: C07C68/005
摘要: A process for producing an aromatic carbonate which comprises:reacting(a) an aromatic hydroxy compound with(b) carbon monoxide in the presence of(c) an oxidation agent,(d) a catalyst comprising a palladium compound or impregnated palladium catalyst,(e) a co-catalyst comprising a manganese compound, a cobalt compound or a copper compound, and(f) at least one nitrile compoundat a temperature of 20.degree. to 300.degree. C.
摘要翻译: 一种制备芳族碳酸酯的方法,其包括:(a)芳族羟基化合物与(b)一氧化碳在(c)氧化剂存在下反应,(d)包含钯化合物或浸渍的钯催化剂的催化剂( e)包含锰化合物,钴化合物或铜化合物的助催化剂,和(f)至少一种腈化合物,温度为20-300℃。
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公开(公告)号:US5051309A
公开(公告)日:1991-09-24
申请号:US512182
申请日:1990-04-20
申请人: Takao Kawaki , Ryozo Kawai , Katsushige Hayashi , Masaki Nagata
发明人: Takao Kawaki , Ryozo Kawai , Katsushige Hayashi , Masaki Nagata
CPC分类号: G02B1/04 , G02B27/281 , G02B5/3033 , Y10S428/913 , Y10T428/26 , Y10T428/31507 , Y10T428/31935
摘要: An anti-dazzling polycarbonate polarizing plate is formed with a polarizing thin layer composed of a polymeric film having a dichroic substance adsorbed on and oriented in the polymeric film, and a polycarbonate sheet having a retardation value of at least 2000 nm bonded to one or both surfaces of the polarizing thin layer.
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