Azonaphthalene sulfonates as polymerization catalysts
    12.
    发明授权
    Azonaphthalene sulfonates as polymerization catalysts 失效
    偶氮萘磺酸盐作为聚合催化剂

    公开(公告)号:US06639043B1

    公开(公告)日:2003-10-28

    申请号:US10180581

    申请日:2002-06-27

    IPC分类号: C08G6400

    CPC分类号: C08G64/307

    摘要: The present invention relates to a synthetic method comprising contacting at least one diaryl carbonate with one or more dihydroxy aromatic compounds in the presence of a transesterification catalyst under melt polymerization conditions to afford a product polycarbonate. The transesterifcation catalysts used according to the method of the present invention are azonaphthalene sulfonates in combination with tetraalkylammonium or tetraalkylphosphonium compounds which serve as co-catalysts. The transesterification catalysts employed according to the method of the present invention provide polycarbonates having reduced levels of Fries rearrangement product relative to conventionally employed catalysts such as sodium hydroxide in combination with tetramethylammonium hydroxide co-catalyst.

    摘要翻译: 本发明涉及一种合成方法,其包括在熔融聚合条件下在酯基转移催化剂存在下使至少一种碳酸二芳基酯与一种或多种二羟基芳族化合物接触,得到产物聚碳酸酯。 根据本发明方法使用的酯交换催化剂是与用作助催化剂的四烷基铵或四烷基鏻化合物组合的氮杂萘磺酸盐。 根据本发明的方法使用的酯交换催化剂提供了相对于常规使用的催化剂如氢氧化钠与四甲基氢氧化铵助催化剂的组合,具有降低的Fries重排产物水平的聚碳酸酯。

    Salts of heterocyclic diols as catalysts for melt polycarbonate

    公开(公告)号:US06608164B2

    公开(公告)日:2003-08-19

    申请号:US10007229

    申请日:2001-10-25

    IPC分类号: C08G6400

    CPC分类号: C08G64/307

    摘要: The present invention relates to a synthetic method in which one or more diaryl carbonates is reacted with one or more dihydroxy aromatic compounds in the presence of a transesterification catalyst under melt polymerization conditions to afford a product polycarbonate. The transesterifcation catalysts used according to the method of the present invention are alkali metal salts and alkaline earth metal salts of heterocyclic diols in combination with tetraalkylammonium or tetraalkylphosphonium compounds which serve as co-catalysts. The furan diol derivative dimethyl 3,4-dihydroxy-2,5-furandiacarboxylate disodium salt, structure IV, was shown to possess excellent activity as a transesterifcation catalyst for the preparation of polycarbonate under melt polymerization conditions. The catalysts employed according to the method of the present invention provide polycarbonates having substantial molecular weight (Mn˜8000-10000 daltons) and reduced levels of Fries rearrangement product relative to conventionally prepared melt polycarbonate having a similar molecular weight.

    Salts of organic polyacids as polymerization catalysts
    14.
    发明授权
    Salts of organic polyacids as polymerization catalysts 失效
    有机多元酸作为聚合催化剂的盐

    公开(公告)号:US06569986B1

    公开(公告)日:2003-05-27

    申请号:US10007228

    申请日:2001-10-25

    IPC分类号: C08G6400

    CPC分类号: C08G64/307

    摘要: The present invention relates to a synthetic method comprising contacting at least one diaryl carbonate with one or more dihydroxy aromatic compounds in the presence of a transesterification catalyst under melt polymerization conditions to afford a product polycarbonate. The transesterifcation catalysts used according to the method of the present invention are alkali metal salts and alkaline earth metal salts of organic polyacids in combination with tetraalkyl ammonium or tetraalkyl phosphonium compounds which serve as co-catalysts. The transesterification catalysts are derived from polyacids containing both CO2H groups and SO3H groups and from polyacids containing exclusively CO2H groups or exclusively SO3H groups. The catalysts employed according to the method of the present invention provide polycarbonates having reduced levels of Fries rearrangement product relative to conventionally employed catalysts such as sodium hydroxide.

    摘要翻译: 本发明涉及一种合成方法,其包括在熔融聚合条件下在酯基转移催化剂存在下使至少一种碳酸二芳基酯与一种或多种二羟基芳族化合物接触,得到产物聚碳酸酯。 根据本发明方法使用的酯交换催化剂是作为助催化剂的四烷基铵或四烷基鏻化合物的有机多酸的碱金属盐和碱土金属盐。 酯交换催化剂衍生自含有CO 2 H基团和SO 3 H基团的多酸和仅含有CO 2 H基团或仅含有SO 3 H基团的多酸。 根据本发明的方法使用的催化剂提供了相对于常规使用的催化剂如氢氧化钠具有降低的Fries重排产物含量的聚碳酸酯。