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公开(公告)号:US11367903B2
公开(公告)日:2022-06-21
申请号:US16582141
申请日:2019-09-25
Inventor: Naoya Morisawa , Kazuhiro Iida , Masaki Deguchi , Atsushi Fukui
IPC: H01M10/00 , H01M10/0569 , H01M4/1315 , H01M4/02
Abstract: A nonaqueous electrolyte solution according to one embodiment of the present disclosure contains a lithium salt and a nonaqueous solvent; the nonaqueous solvent contains fluoroethylene carbonate and a chain carboxylic acid ester having a dielectric constant of 6.0 or more; the lithium salt contains LiPO2F2 and LiSO3F; and the respective concentrations of LiPO2F2 and LiSO3F in the non-aqueous solvent are 0.15 mol/L or more.
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公开(公告)号:US20210218064A1
公开(公告)日:2021-07-15
申请号:US17056229
申请日:2019-02-21
Inventor: Kazuhiro Iida , Takayuki Nakatsutsumi , Atsushi Fukui
IPC: H01M10/0569 , H01M4/36 , H01M4/58 , H01M10/0525 , H01M4/38
Abstract: A secondary battery includes a negative electrode containing a lithium silicate phase and silicon particles dispersed in the lithium silicate phase and an electrolytic solution containing a fluorine-containing linear carboxylic acid ester represented by R1—(CO)O—CH2—R2 (wherein R1 is an alkyl group and R2 is an alkyl group in which at least one hydrogen atom is substituted with fluorine).
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公开(公告)号:US20200020986A1
公开(公告)日:2020-01-16
申请号:US16580212
申请日:2019-09-24
Inventor: Yasuko Hirayama , Naoya Morisawa , Takanobu Chiga , Kazuhiro Iida , Atsushi Fukui
IPC: H01M10/0569 , H01M10/0568 , H01M4/525 , H01M10/0525 , H01M10/0567
Abstract: A nonaqueous electrolyte secondary battery according to one embodiment of the present disclosure comprises a positive electrode having a positive electrode active substance layer, a negative electrode having a negative electrode active substance layer, and a nonaqueous electrolyte. The nonaqueous electrolyte contains a sulfonylimide salt and a nonaqueous solvent containing a fluorinated chain carboxylic acid ester represented by a general formula. The fluorinated chain carboxylic acid ester content of the nonaqueous solvent is 80 vol % or greater and the sulfonylimide salt content is 2.4 mol or greater with respect to 1 L of the nonaqueous solvent. (In the formula, R1 and R2 are any one of H, F, and CH3-xFx (where x is 1, 2 or 3), and can be the same or different. R3 is a C1-C3 alkyl group and can contain F.)
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公开(公告)号:US20230318049A1
公开(公告)日:2023-10-05
申请号:US18028695
申请日:2021-08-18
Inventor: Hiroyuki Matsumoto , Kazuhiro Iida , Hideharu Takezawa
IPC: H01M10/42 , H01M10/0525 , H01M10/056
CPC classification number: H01M10/4235 , H01M10/0525 , H01M10/056 , H01M2300/0088
Abstract: This lithium ion secondary battery comprises a negative electrode, a positive electrode, a non-aqueous electrolyte including a lithium salt, and an aqueous electrolyte including a lithium salt, wherein: among the negative electrode and the positive electrode, the aqueous electrolyte contacts only the positive electrode; among the negative electrode and the positive electrode, the non-aqueous electrolyte contacts at least the negative electrode; the positive electrode contains a positive electrode active material; the positive electrode active material contains a lithium transition metal composite oxide and a surface modification layer formed on the surface of primary particles of the lithium transition metal composite oxide; and the surface modification layer contains an alkali earth metal element.
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公开(公告)号:US11894521B2
公开(公告)日:2024-02-06
申请号:US17056229
申请日:2019-02-21
Inventor: Kazuhiro Iida , Takayuki Nakatsutsumi , Atsushi Fukui
IPC: H01M10/0569 , H01M4/36 , H01M4/58 , H01M10/0525 , H01M4/38 , H01M4/02 , H01M4/134 , H01M10/052 , H01M4/136
CPC classification number: H01M10/0569 , H01M4/364 , H01M4/386 , H01M4/5825 , H01M10/0525 , H01M4/134 , H01M4/136 , H01M10/052 , H01M2004/027 , H01M2220/20 , H01M2300/0034 , Y02E60/10
Abstract: A secondary battery includes a negative electrode containing a lithium silicate phase and silicon particles dispersed in the lithium silicate phase and an electrolytic solution containing a fluorine-containing linear carboxylic acid ester represented by R1—(CO)O—CH2—R2 (wherein R1 is an alkyl group and R2 is an alkyl group in which at least one hydrogen atom is substituted with fluorine).
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公开(公告)号:US20220393170A1
公开(公告)日:2022-12-08
申请号:US17763102
申请日:2020-07-28
Inventor: Kazuhiro Iida , Masanobu Takeuchi
IPC: H01M4/587 , H01M10/0525 , H01M4/133
Abstract: This secondary battery comprises a positive electrode, a negative electrode, and an electrolyte. The electrolyte contains a solvent containing water, and a lithium salt. The negative electrode has a negative electrode active material that contains a carbon material. In the carbon material, the peak intensity ratio (D/G value) of a D band and a G band in the Raman spectrum obtained using Raman spectroscopy is 0.9 to 1.5. A coating is formed on the surface of the carbon material. In the coating, in the XPS spectrum measured using X-ray photoelectron spectroscopy, when the peak intensity of a 1s electron orbit of an F atom for which the binding energy appears near 685 eV is P1, and the peak intensity of the 1s electron orbit of an O atom for which the binding energy appears near 532 eV is P2, the ratio of the peak intensity P1 to the peak intensity P2 (P1/P2 value) is 0.6 to 3.0.
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公开(公告)号:US20220393169A1
公开(公告)日:2022-12-08
申请号:US17763053
申请日:2020-07-28
Inventor: Kazuhiro Iida , Masanobu Takeuchi
IPC: H01M4/587
Abstract: This secondary battery comprises a positive electrode, a negative electrode, and an electrolyte solution. The electrolyte solution includes a solvent containing water as a main component, and a lithium salt. The negative electrode has a negative electrode active material that includes a carbon material. The Raman spectrum of the carbon material, which is obtained by Raman spectroscopy, indicates that the peak intensity ratio between the D-band and the G-band (D/G) is 0.3 or greater. This secondary battery can suppress the reductive decomposition of the water-based electrolyte solution.
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公开(公告)号:US20200020985A1
公开(公告)日:2020-01-16
申请号:US16580194
申请日:2019-09-24
Inventor: Kazuhiro Iida , Takanobu Chiga , Naoya Morisawa , Atsushi Fukui
IPC: H01M10/0569 , H01M10/052 , H01M6/16
Abstract: A nonaqueous electrolyte includes a lithium salt and a nonaqueous solvent in which the lithium salt is dissolved. The nonaqueous solvent includes a fluorinated chain carboxylate ester and a dicarbonyl compound having two carbonyl groups in the molecule. The dicarbonyl compound is at least one selected from the group consisting of esters and acid anhydrides and has not more than three atoms between the two carbonyl groups.
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