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公开(公告)号:US20190202704A1
公开(公告)日:2019-07-04
申请号:US16029170
申请日:2018-07-06
Applicant: PetroChina Company Limited
Inventor: Baoliang Peng , Zongtao Zhang , Pingmei Wang , Runwei Wang , Bin Ding , Jianhui Luo , Lipeng He , Ying Wang , Xiangfei Geng
CPC classification number: C01B39/026 , C01B39/38 , C01P2002/72 , C01P2004/03 , C01P2004/04 , C01P2004/90 , C01P2006/16
Abstract: The present invention provides an amphiphilic molecular sieve containing a lipophilic group on the outside and a hydrophilic group on the inside and a production method thereof. The production method comprises: dispersing the nano-ZSM-5 molecular sieve into toluene, adding an organosilane containing a lipophilic group and reacting at 60-100° C. for 4-16 h, to obtain a molecular sieve containing a lipophilic group; placing the molecular sieve containing a lipophilic group in a mixed solution of sodium hydroxide solution and ethanol and reacting at 60-95° C. for 20-60 min, to obtain a molecular sieve containing a lipophilic group on the outside; dispersing the molecular sieve containing a lipophilic group on the outside into toluene, adding an organosilane containing a hydrophilic group and reacting at 60-100° C. for 4-16 h, to obtain the amphiphilic molecular sieve containing a lipophilic group on the outside and a hydrophilic group on the inside. The present invention also provides a molecular sieve obtained by the above production method, which does not destroy the characteristics of the original molecular sieve and has hydrophilic and lipophilic amphiphilic properties.
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12.
公开(公告)号:US11802233B2
公开(公告)日:2023-10-31
申请号:US17433839
申请日:2020-10-29
Applicant: PetroChina Company Limited
Inventor: Bin Ding , Chunming Xiong , Xiangfei Geng , Baoshan Guan , Falin Wei , Jingjun Pan , Baocheng Wu , Jingfeng Dong , Youguo Yan
CPC classification number: C09K8/584 , E21B43/16 , C09K2208/10
Abstract: A permeability-enhancing flooding system for tight oil reservoirs and preparation and use thereof are disclosed. The permeability-enhancing flooding system is present in a state of oil-in-water droplet and composed of a surfactant, an oil-soluble substance and water, and has an outer phase that is an aqueous solution containing the surfactant, and an inner phase that is the oil-soluble substance; and the surfactant comprises one of nonionic gemini surfactants and anionic gemini surfactants, or a combination of two or more thereof. The preparation process for the permeability-enhancing flooding system is simple to operate, suitable for industrialized production, and low in overall cost, and has obvious application prospects in the field of tight oil reservoirs for an enhanced oil recovery.
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13.
公开(公告)号:US20220145164A1
公开(公告)日:2022-05-12
申请号:US17433839
申请日:2020-10-29
Applicant: PetroChina Company Limited
Inventor: Bin Ding , Chunming Xiong , Xiangfei Geng , Baoshan Guan , Falin Wei , Jingjun Pan , Baocheng Wu , Jingfeng Dong , Youguo Yan
Abstract: A permeability-enhancing flooding system for tight oil reservoirs and preparation and use thereof are disclosed. The permeability-enhancing flooding system is present in a state of oil-in-water droplet and composed of a surfactant, an oil-soluble substance and water, and has an outer phase that is an aqueous solution containing the surfactant, and an inner phase that is the oil-soluble substance; and the surfactant comprises one of nonionic gemini surfactants and anionic gemini surfactants, or a combination of two or more thereof. The preparation process for the permeability-enhancing flooding system is simple to operate, suitable for industrialized production, and low in overall cost, and has obvious application prospects in the field of tight oil reservoirs for an enhanced oil recovery.
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公开(公告)号:US20200208044A1
公开(公告)日:2020-07-02
申请号:US16691942
申请日:2019-11-22
Applicant: PetroChina Company Limited
Inventor: Xiangfei GENG , Bin Ding , Jianhui LUO , Bo HUANG , Jianyong XIE , Pingmei WANG , Yongcan PENG , Baoliang PENG
Abstract: The invention discloses a nonionic Gemini surfactant, (octylphenol polyoxyethylene ether disubstituted) dicarboxylic acid diphenyl ether and its synthesis method, which nonionic Gemini surfactant has a structural formula of: and is prepared by a two-step reaction: S1, diphenyl ether 4,4′-dicarboxylic acid is subjected to an acyl chlorination reaction to obtain diphenyl ether 4,4′-dicarbonyl dichloride; S2, diphenyl ether 4,4′-dicarbonyl dichloride is subjected to an esterification reaction with octylphenol polyoxyethylene ether (OP-10) to obtain the target product (octylphenol polyoxyethylene ether disubstituted) dicarboxylic acid diphenyl ether. The surfactant of the present invention is expected to be applied in tertiary oil recovery as an alkali/surfactant, in polymer/surfactant binary composite flooding, in alkali/surfactant/polymer ternary composite flooding, as a microemulsion emulsifier and the like, and it can also be compounded with a common surfactant to reduce the use cost, and thus create conditions for its large-scale application.
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公开(公告)号:US20190202705A1
公开(公告)日:2019-07-04
申请号:US16029215
申请日:2018-07-06
Applicant: PetroChina Company Limited
Inventor: Jianhui Luo , Zongtao Zhang , Baoliang Peng , Runwei Wang , Lipeng He , Pingmei Wang , Bin Ding , Ying Wang , Xiangfei Geng
Abstract: The present invention provides an amphiphilic molecular sieve containing a hydrophilic group on the outside and a lipophilic group on the inside and a production method thereof. The production method comprises: dispersing the ZSM-5 spherical nano-molecular sieve into toluene, adding thereto an organosilane containing a hydrophilic group and reacting at 40-80° C. for 2-16 h, to obtain a molecular sieve containing a hydrophilic group; placing the molecular sieve containing a hydrophilic group in an aqueous solution of sodium hydroxide and reacting at 50-90° C. for 10-50 min, to obtain a molecular sieve containing a hydrophilic group on the outside; dispersing the molecular sieve containing a hydrophilic group on the outside into toluene, adding thereto an organosilane containing a lipophilic group and reacting at 40-80° C. for 2-12 h, to obtain the amphiphilic molecular sieve containing a hydrophilic group on the outside and a lipophilic group on the inside. The present invention also provides an amphiphilic molecular sieve obtained by the above production method, which contains a hydrophilic group on the outside and a lipophilic group on the inside.
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