公开(公告)号：US20240316542A1

公开(公告)日：2024-09-26

申请号：US18603475

申请日：2024-03-13

Applicant: The Regents of the University of California

Inventor： Ji Yang ,  Ji Su

IPC: B01J29/78 ,  B01J23/26 ,  B01J37/00 ,  B01J37/04 ,  B01J37/08 ,  C01B32/40 ,  C01B39/02 ,  C07C5/42

CPC classification number: B01J29/783 ,  B01J23/26 ,  B01J37/0036 ,  B01J37/04 ,  B01J37/08 ,  C01B32/40 ,  C01B39/026 ,  C07C5/42 ,  B01J2229/38 ,  C07C2529/78

Abstract: This disclosure provides systems, methods, and apparatus related to catalysts. In one aspect, a catalyst is a ZnxMy/zeolite catalyst, with ½≤x/y≤4, and M being a metal from a group Cr, Mo, and W. Zn is an oxide, M is an oxide, and there are at least some ZnMOx oxides.

公开(公告)号：US20240300820A1

公开(公告)日：2024-09-12

申请号：US18593677

申请日：2024-03-01

Applicant: ExxonMobil Technology and Engineering Company

Inventor： Trong D. Pham ,  Eugene A. Terefenko ,  Mary Abdulkarim

IPC: C01B39/48 ,  B01J29/70 ,  B01J29/86 ,  B01J35/63 ,  B01J37/00 ,  B01J37/03 ,  B01J37/04 ,  C01B37/00 ,  C01B39/02 ,  C07D471/04

CPC classification number: C01B39/48 ,  B01J29/70 ,  B01J29/86 ,  B01J35/633 ,  B01J37/0018 ,  B01J37/031 ,  B01J37/04 ,  C01B37/007 ,  C01B39/026 ,  C07D471/04 ,  C01P2002/72 ,  C01P2004/03 ,  C01P2004/12 ,  C01P2004/20 ,  C01P2006/12 ,  C01P2006/14

Abstract: Molecular sieves, designated as EMM-74, characterized by a unique powder XRD pattern, methods of making the same, and uses thereof.

公开(公告)号：US20240116038A1

公开(公告)日：2024-04-11

申请号：US18262884

申请日：2022-01-30

Applicant: BASF Corporation

Inventor： Xiaoduo Qi ,  Lihua Shi ,  Vivek Vattipalli ,  Mingming Wei ,  Haitao Liu ,  Jin Li

IPC: B01J29/76 ,  B01D53/94 ,  B01J37/00 ,  B01J37/03 ,  B01J37/04 ,  B01J37/08 ,  B01J37/30 ,  C01B39/02 ,  C01B39/48 ,  F01N3/20 ,  F01N3/28

CPC classification number: B01J29/763 ,  B01D53/9418 ,  B01J37/0018 ,  B01J37/031 ,  B01J37/04 ,  B01J37/08 ,  B01J37/30 ,  C01B39/026 ,  C01B39/48 ,  F01N3/2066 ,  F01N3/2803 ,  B01D2255/20761 ,  B01D2255/50 ,  B01D2255/9207 ,  B01D2257/404 ,  B01D2258/01 ,  B01J2229/186 ,  C01P2002/72 ,  C01P2002/74 ,  C01P2002/78 ,  C01P2004/03 ,  C01P2006/12 ,  F01N2370/04

Abstract: The present invention relates to a CHA-like zeolitic material having an X-ray diffraction pattern including the following peaks in Table 1 in its as-synthesized form, and to a process for preparing the zeolitic material, and use of the zeolitic material for the selective catalytic reduction of NOx.

公开(公告)号：US11904282B2

公开(公告)日：2024-02-20

申请号：US17149823

申请日：2021-01-15

Applicant: KOREA UNIVERSITY RESEARCH AND BUSINESS FOUNDATION

Inventor： Jungkyu Choi ,  Kwan Young Lee ,  Minseong Lee

IPC: B01D67/00 ,  B01D53/22 ,  C02F1/44 ,  C01B39/02 ,  C01B39/48 ,  B01J20/18 ,  B01J20/28 ,  B01J20/30 ,  C10L3/10 ,  B01D69/10 ,  B01D71/02 ,  C02F101/34

CPC classification number: B01D67/0083 ,  B01D53/228 ,  B01D67/0051 ,  B01D67/0095 ,  B01D69/107 ,  B01D69/108 ,  B01D71/0281 ,  B01J20/183 ,  B01J20/28033 ,  B01J20/3057 ,  B01J20/3078 ,  C01B39/026 ,  C01B39/48 ,  C02F1/44 ,  C10L3/104 ,  C10L3/105 ,  C02F2101/34 ,  C10L2290/548

Abstract: The present invention relates to a method of controlling a defect structure in a chabazite (CHA) zeolite membrane, the CHA zeolite membrane having a controlled defect structure by the method and a method of separating CO2, H2, or He and water from a mixture of water and an organic solvent using the CHA zeolite membrane, and more particularly, to a method of controlling a defect structure in a CHA zeolite membrane that improves the separation performance by reducing the amount and size of defects formed in the CHA membrane structure when removing organic-structure-directing agents in the membrane through calcination at a low temperature using ozone.

公开(公告)号：US20230390755A1

公开(公告)日：2023-12-07

申请号：US18037464

申请日：2021-04-30

Applicant: CATLION CO., LTD.

Inventor： Qiang GONG ,  Yongheng YUAN

IPC: B01J47/016 ,  C01B39/02 ,  B01J47/15

CPC classification number: B01J47/016 ,  C01B39/026 ,  B01J47/15

Abstract: Provided are a continuous crystal transformation and ion exchange device and process, belonging to the technical field of molecular sieve manufacturing. The continuous crystal transformation and ion exchange device comprises M+N reaction tanks which are in serial connection, wherein a feed opening of a latter reaction tank communicates with a discharge opening of a former reaction tank by means of a reaction solution circulation pipeline, and a discharge opening of an M+Nth reaction tank communicates with a feed opening of a first reaction tank by means of a reaction solution circulation pipeline. No more than M reaction tanks are used for a crystal transformation process, and no more than N reaction tanks are used for an ion exchange process. The method is used for preparing a finished zeolite molecular sieve product, and has the advantages of high exchange capacity, simple process, low cost and the like.

公开(公告)号：US11767225B2

公开(公告)日：2023-09-26

申请号：US16324296

申请日：2017-08-10

Applicant: Research Triangle Institute

Inventor： Ignacio Luz Minguez ,  Mustapha Soukri ,  Marty Lail

IPC: C01B39/02 ,  C01B39/48 ,  B01J29/06 ,  C01B39/00 ,  B01J20/22 ,  B01J20/10 ,  B01J20/32 ,  B01J31/16

CPC classification number: C01B39/026 ,  B01J20/103 ,  B01J20/226 ,  B01J20/3236 ,  B01J20/3265 ,  B01J29/06 ,  B01J31/1691 ,  C01B39/00 ,  C01B39/02 ,  C01B39/48 ,  B01D2253/108 ,  B01D2253/204 ,  B01D2259/4583

Abstract: A method, comprising i) contacting an aqueous solution of an organic ligand salt of the formula AX(L−X) with a mesoporous material (MPM) to form an impregnated mesoporous salt material of the formula AX(L−X)/MPM, ii) treating the impregnated mesoporous salt material with an aqueous acidic solution to form an impregnated mesoporous acid material of the formula HX(L−X)/MPM, iii) contacting an aqueous solution of a metal precursor of the formula M+y(B)y with the impregnated mesoporous acid material to form an impregnated mesoporous metal organic framework precursor of the formula [M+y(B)y][Hx(L−x)]/MPM, and iv) at least one of 1) heating the impregnated mesoporous metal organic framework precursor in the absence of a solvent or 2) exposing the impregnated mesoporous metal organic framework precursor to a volatile vapor in the absence of a solvent such that the heating or the exposing forms a hybrid material of the formula (M+yL−x)/MPM, wherein the hybrid material comprises a nano-crystalline metal organic framework (MOF) embedded within the mesoporous material.

公开(公告)号：US11753307B2

公开(公告)日：2023-09-12

申请号：US17230532

申请日：2021-04-14

Applicant: Saudi Arabian Oil Company ,  King Abdullah University of Science and Technology

Inventor： Robert Peter Hodgkins ,  Omer Refa Koseoglu ,  Jean-Marie Maurice Basset ,  Kuo-Wei Huang ,  Anissa Bendjeriou Sedjerari ,  Sathiyamoorthy Murugesan ,  Manouj K. Gangwar

IPC: C01B39/00 ,  C01B39/40 ,  B01J29/40 ,  B01J37/16 ,  B01J37/02 ,  B01J35/10 ,  B01J35/02 ,  C01B39/02

CPC classification number: C01B39/40 ,  B01J29/405 ,  B01J35/023 ,  B01J35/1061 ,  B01J35/1066 ,  B01J37/0203 ,  B01J37/16 ,  C01B39/026 ,  C01P2002/72 ,  C01P2002/82 ,  C01P2002/86 ,  C01P2004/03 ,  C01P2004/04 ,  C01P2004/62 ,  C01P2004/64 ,  C01P2006/16

Abstract: Disclosed herein are modified zeolites and methods for making modified zeolites. In one or more embodiments disclosed herein, a modified zeolite may include a microporous framework including a plurality of micropores having diameters of less than or equal to 2 nm. The microporous framework may include at least silicon atoms and oxygen atoms. The modified zeolite may further include organometallic moieties each bonded to a nitrogen atom of a secondary amine functional group comprising a nitrogen atom and a hydrogen atom. The organometallic moieties may comprise a hafnium atom that is bonded to the nitrogen atom of the secondary amine functional group. The nitrogen atom of the secondary amine function group may bridge the hafnium atom of the organometallic moiety and a silicon atom of the microporous framework.

公开(公告)号：US20230150826A1

公开(公告)日：2023-05-18

申请号：US17527771

申请日：2021-11-16

Applicant: Saudi Arabian Oil Company

Inventor： Mansour Ahmed Al-Shafei ,  Tulay Inan ,  Wala Ali Algozeeb ,  Adel Mastoor Alsolami ,  Shouwen Shen

IPC: C01B39/02 ,  B01J29/06

CPC classification number: C01B39/026 ,  B01J29/06

Abstract: A method of enriching nano-bentonite from a raw bentonite composition comprises the steps of mixing the raw bentonite composition with water to produce a bentonite solution, increasing the temperature of the bentonite solution to produce a warm bentonite solution, mixing the warm bentonite solution at a mixing rate to produce a colloidal solution, filtering the colloidal solution with a micro-sieve to produce a filtered colloidal solution, centrifuging the filtered colloidal solution at a centrifuge rate for a centrifuge time to produce a separated colloidal solution, wherein the nano-sized impurities are selected from the group consisting of quartz, feldspar, cristbalite, calcite, iron oxides, magnetite, calcium carbonate, and combinations of the same, and drying the separated colloidal solution to remove water to produce the nano-bentonite.

公开(公告)号：US20180311652A1

公开(公告)日：2018-11-01

申请号：US15583380

申请日：2017-05-01

Applicant: Saudi Arabian Oil Company

Inventor： Ke Zhang ,  Sergio Fernandez

IPC: B01J29/70 ,  B01J35/10 ,  B01J37/00 ,  B01J37/04 ,  C01B39/48 ,  C01B39/02 ,  C07C5/25

CPC classification number: B01J29/7007 ,  B01J29/041 ,  B01J35/1023 ,  B01J35/1057 ,  B01J35/1061 ,  B01J35/109 ,  B01J37/0018 ,  B01J37/04 ,  B01J37/10 ,  B01J2229/10 ,  B01J2229/30 ,  B01J2229/34 ,  B01J2229/36 ,  B01J2229/38 ,  C01B39/026 ,  C01B39/48 ,  C01P2006/12 ,  C01P2006/16 ,  C07C5/2518 ,  C07C2529/70

Abstract: Methods for producing mesoporous beta zeolites from parent beta zeolites having a Si/Al molar ratio of at least 10 comprise selecting a target average mesoporous size between 2 nm and 8 nm for the parent beta zeolites, selecting a pore directing agent (PDA) based on the target average mesopore size, where a non-ionic surfactant, a small cationic surfactant has a molecular weight of greater than 100 grams/mole, or both may be selected as the PDA when the target average mesopore size is at least 5 nm, and a large cationic surfactant having a molecular weight of less than 100 grams/mole may be selected as the PDA when the target average mesopore size is less than 5 nm. The method further comprises adding the selected PDA to an alkaline solution to form a PDA-base mixture, and adding the parent beta zeolites to the PDA-base mixture to produce the mesoporous beta zeolites.

公开(公告)号：US20180201514A1

公开(公告)日：2018-07-19

申请号：US15839966

申请日：2017-12-13

Applicant: Chevron U.S.A. Inc.

Inventor： Dan Xie

IPC: C01B39/48

CPC classification number: C01B39/48 ,  B01D53/8628 ,  B01D53/9418 ,  B01J29/70 ,  B01J29/72 ,  B01J29/74 ,  B01J29/76 ,  B01J29/78 ,  C01B39/026 ,  C01P2002/72

Abstract: A novel synthetic crystalline molecular sieve designated as SSZ-108 is disclosed. SSZ-108 may be synthesized using a structure directing agent comprising one or more of 1-butyl-1-methylpyrrolidinium cations and 1-butyl-1-methylpiperidinium cations. Molecular sieve SSZ-108 may be used in catalytic and sorptive processes.