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11.发明授权Hydroxymethylfurfural reduction methods and methods of producing furandimethanol 有权羟甲基糠醛还原方法和生产呋喃二甲醇的方法公开(公告)号：US08367851B2
公开(公告)日：2013-02-05
申请号：US13173942
申请日：2011-06-30
IPC分类号： C07D307/02
CPC分类号： C07D307/42 , C07D307/46
摘要： A method of reducing hydroxymethylfurfural (HMF) where a starting material containing HMF in a solvent comprising water is provided. H2 is provided into the reactor and the starting material is contacted with a catalyst containing at least one metal selected from Ni, Co, Cu, Pd, Pt, Ru, Ir, Re and Rh, at a temperature of less than or equal to 250° C. A method of hydrogenating HMF includes providing an aqueous solution containing HMF and fructose. H2 and a hydrogenation catalyst are provided. The HMF is selectively hydrogenated relative to the fructose at a temperature at or above 30° C. A method of producing tetrahydrofuran dimethanol (THFDM) includes providing a continuous flow reactor having first and second catalysts and providing a feed comprising HMF into the reactor. The feed is contacted with the first catalyst to produce furan dimethanol (FDM) which is contacted with the second catalyst to produce THFDM.
摘要翻译： 提供一种还原羟甲基糠醛（HMF）的方法，其中含有HMF的原料在包含水的溶剂中。 将H2置于反应器中，并使原料与含有至少一种选自Ni，Co，Cu，Pd，Pt，Ru，Ir，Re和Rh的金属的催化剂在小于或等于250的温度下接触 氢化HMF的方法包括提供含有HMF和果糖的水溶液。 H2和氢化催化剂。 在30℃或更高的温度下，HMF相对于果糖选择性地氢化。制备四氢呋喃二甲醇（THFDM）的方法包括提供具有第一和第二催化剂的连续流动反应器，并向反应器提供包含HMF的进料。 进料与第一催化剂接触以产生与第二催化剂接触以产生THFDM的呋喃二甲醇（FDM）。
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12.发明授权Hydroxymethylfurfural reduction methods and methods of producing furandimethanol 有权羟甲基糠醛还原方法和生产呋喃二甲醇的方法公开(公告)号：US08742144B2
公开(公告)日：2014-06-03
申请号：US13174181
申请日：2011-06-30
IPC分类号： C07D307/02
CPC分类号： C07D307/42 , C07D307/46
摘要： A method of reducing hydroxymethylfurfural (HMF) where a starting material containing HMF in a solvent comprising water is provided. H2 is provided into the reactor and the starting material is contacted with a catalyst containing at least one metal selected from Ni, Co, Cu, Pd, Pt, Ru, Ir, Re and Rh, at a temperature of less than or equal to 250° C. A method of hydrogenating HMF includes providing an aqueous solution containing HMF and fructose. H2 and a hydrogenation catalyst are provided. The HMF is selectively hydrogenated relative to the fructose at a temperature at or above 30° C. A method of producing tetrahydrofuran dimethanol (THFDM) includes providing a continuous flow reactor having first and second catalysts and providing a feed comprising HMF into the reactor. The feed is contacted with the first catalyst to produce furan dimethanol (FDM) which is contacted with the second catalyst to produce THFDM.
摘要翻译： 提供一种还原羟甲基糠醛（HMF）的方法，其中含有HMF的原料在包含水的溶剂中。 将H2置于反应器中，并使原料与含有至少一种选自Ni，Co，Cu，Pd，Pt，Ru，Ir，Re和Rh的金属的催化剂在小于或等于250的温度下接触 氢化HMF的方法包括提供含有HMF和果糖的水溶液。 H2和氢化催化剂。 在30℃或更高的温度下，HMF相对于果糖选择性地氢化。制备四氢呋喃二甲醇（THFDM）的方法包括提供具有第一和第二催化剂的连续流动反应器，并向反应器提供包含HMF的进料。 进料与第一催化剂接触以产生与第二催化剂接触以产生THFDM的呋喃二甲醇（FDM）。
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公开(公告)号：US08193382B2
公开(公告)日：2012-06-05
申请号：US12712100
申请日：2010-02-24
IPC分类号： C07D307/48
CPC分类号： C07D307/48 , C07D307/44
摘要： A method of oxidizing hydroxymethylfurfural (HMF) includes providing a starting material which includes HMF in a solvent comprising water into a reactor. At least one of air and O2 is provided into the reactor. The starting material is contacted with the catalyst comprising Pt on a support material where the contacting is conducted at a reactor temperature of from about 50° C. to about 200° C. A method of producing an oxidation catalyst where ZrO2 is provided and is calcined. The ZrO2 is mixed with platinum (II) acetylacetonate to form a mixture. The mixture is subjected to rotary evaporation to form a product. The product is calcined and reduced under hydrogen to form an activated product. The activated product is passivated under a flow of 2% O2.
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公开(公告)号：US08193381B2
公开(公告)日：2012-06-05
申请号：US12712095
申请日：2010-02-24
IPC分类号： C07D307/02 , C07D307/48
CPC分类号： C07D307/48 , C07D307/44
摘要： A method of oxidizing hydroxymethylfurfural (HMF) includes providing a starting material which includes HMF in a solvent comprising water into a reactor. At least one of air and O2 is provided into the reactor. The starting material is contacted with the catalyst comprising Pt on a support material where the contacting is conducted at a reactor temperature of from about 50° C. to about 200° C. A method of producing an oxidation catalyst where ZrO2 is provided and is calcined. The ZrO2 is mixed with platinum (II) acetylacetonate to form a mixture. The mixture is subjected to rotary evaporation to form a product. The product is calcined and reduced under hydrogen to form an activated product. The activated product is passivated under a flow of 2% O2.
摘要翻译： 氧化羟甲基糠醛（HMF）的方法包括在包含水的溶剂中提供包含HMF的原料进入反应器。 将空气和O2中的至少一个提供到反应器中。 起始材料与包含Pt的催化剂在载体材料上接触，其中接触在约50℃至约200℃的反应器温度下进行。制备其中提供ZrO 2并被煅烧的氧化催化剂的方法 。 将ZrO 2与乙酰丙酮化铂（II）混合以形成混合物。 将混合物进行旋转蒸发以形成产物。 将产物在氢气下煅烧和还原以形成活化产物。 活化产物在2％O 2的流量下钝化。
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公开(公告)号：US20100152469A1
公开(公告)日：2010-06-17
申请号：US12712095
申请日：2010-02-24
IPC分类号： C07D307/68
CPC分类号： C07D307/48 , C07D307/44
摘要： A method of oxidizing hydroxymethylfurfural (HMF) includes providing a starting material which includes HMF in a solvent comprising water into a reactor. At least one of air and O2 is provided into the reactor. The starting material is contacted with the catalyst comprising Pt on a support material where the contacting is conducted at a reactor temperature of from about 50° C. to about 200° C. A method of producing an oxidation catalyst where ZrO2 is provided and is calcined. The ZrO2 is mixed with platinum (II) acetylacetonate to form a mixture. The mixture is subjected to rotary evaporation to form a product. The product is calcined and reduced under hydrogen to form an activated product. The activated product is passivated under a flow of 2% O2.
摘要翻译： 氧化羟甲基糠醛（HMF）的方法包括在包含水的溶剂中将包含HMF的原料提供到反应器中。 将空气和O2中的至少一个提供到反应器中。 起始材料与包含Pt的催化剂在载体材料上接触，其中接触在约50℃至约200℃的反应器温度下进行。制备其中提供ZrO 2并被煅烧的氧化催化剂的方法 。 将ZrO 2与乙酰丙酮化铂（II）混合以形成混合物。 将混合物进行旋转蒸发以形成产物。 将产物在氢气下煅烧和还原以形成活化产物。 活化产物在2％O 2的流量下钝化。
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