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    Reduction of HMF ethers with metal catalyst
    2.
    发明授权
    Reduction of HMF ethers with metal catalyst 有权
    用金属催化剂还原HMF醚

    公开(公告)号：US08709286B2

    公开(公告)日：2014-04-29

    申请号：US13096348

    申请日：2011-04-28

    申请人： Paul D. Bloom ,  Alexandra Sanborn

    发明人： Paul D. Bloom ,  Alexandra Sanborn

    IPC分类号： C07D307/12

    CPC分类号： C07D307/54 ,  C07C41/26 ,  C07C43/13 ,  C07D307/12 ,  C07D307/16 ,  C07D307/44 ,  C08K5/06 ,  C09K3/00

    摘要： Methods of making reduced derivatives of hydroxymethyl furfural using metal catalysts are described. The derivatives may have tetrahydrofuran or furan nucleus with alkoxymethyl ether or ester moieties on the 5′ carbon and methanol on the 2′ carbon. Suitable metal catalyst include Raney nickel, a nickel catalyst with a zirconium promoter, a chromite catalyst with a barium, a palladium catalyst, such as palladium on carbon, or a ruthenium catalyst. Also provided are a new class of compounds, which are n-alkoxy hexane diols (i.e., 1,2 or 1,5 hexane diol ethers) and methods of making the same by reduction of furan or tetrahydrofuran derivatives.

    摘要翻译： 描述了使用金属催化剂制备羟甲基糠醛的还原衍生物的方法。 衍生物可以在2'碳上的5'碳和甲醇上具有含有烷氧基甲基醚或酯部分的四氢呋喃或呋喃核。 合适的金属催化剂包括阮内镍，具有锆促进剂的镍催化剂，具有钡的铬铁催化剂，钯催化剂如钯碳或钌催化剂。 还提供了一类新的化合物，它们是正烷氧基己二醇（即1,2或1,5-己二醇醚）和通过还原呋喃或四氢呋喃衍生物制备该化合物的方法。

    Method for producing alcohol compound
    3.
    发明授权
    Method for producing alcohol compound 有权
    醇化合物的制备方法

    公开(公告)号：US08697881B2

    公开(公告)日：2014-04-15

    申请号：US13126390

    申请日：2008-12-11

    申请人： Hideo Shimizu

    发明人： Hideo Shimizu

    IPC分类号： C07D211/70 ,  C07D211/82 ,  C07D213/46 ,  C07D307/00 ,  C07D317/00 ,  C07D323/02 ,  B01J31/00

    CPC分类号： C07D307/42 ,  C07C29/141 ,  C07D307/44 ,  C07C33/14 ,  C07C33/30 ,  C07C33/22

    摘要： Disclosed is a practical method for efficiently producing an alcohol compound by hydrogenating an aldehyde by using a homogeneous copper catalyst which is an easily-available low-cost metal species. Specifically disclosed is a method for producing an alcohol compound, which is characterized in that a hydrogenation reaction of an aldehyde compound is performed in the presence of a homogeneous copper catalyst, a monophosphine compound and an alcohol selected from the group consisting of primary alcohols, secondary alcohols and mixtures of those.

    摘要翻译： 公开了通过使用易于获得的低成本金属种类的均匀铜催化剂氢化醛来有效生产醇化合物的实用方法。 具体公开了一种醇化合物的制造方法，其特征在于，在均匀的铜催化剂，单膦化合物和选自伯醇，二次碳酸酯的醇的存在下，进行醛化合物的氢化反应 醇和它们的混合物。

    Hydroxymethyl furfural oxidation methods
    6.
    发明授权
    Hydroxymethyl furfural oxidation methods 有权
    羟甲基糠醛氧化法

    公开(公告)号：US07700788B2

    公开(公告)日：2010-04-20

    申请号：US11932436

    申请日：2007-10-31

    申请人： Michael A. Lilga ,  Richard T. Hallen ,  Jianli Hu ,  James F. White ,  Michel J. Gray

    发明人： Michael A. Lilga ,  Richard T. Hallen ,  Jianli Hu ,  James F. White ,  Michel J. Gray

    IPC分类号： C07D307/44

    CPC分类号： C07D307/48 ,  C07D307/44

    摘要： A method of oxidizing hydroxymethylfurfural (HMF) includes providing a starting material which includes HMF in a solvent comprising water into a reactor. At least one of air and O2 is provided into the reactor. The starting material is contacted with the catalyst comprising Pt on a support material where the contacting is conducted at a reactor temperature of from about 50° C. to about 200° C. A method of producing an oxidation catalyst where ZrO2 is provided and is calcined. The ZrO2 is mixed with platinum (II) acetylacetonate to form a mixture. The mixture is subjected to rotary evaporation to form a product. The product is calcined and reduced under hydrogen to form an activated product. The activated product is passivated under a flow of 2% O2.

    摘要翻译： 氧化羟甲基糠醛（HMF）的方法包括在包含水的溶剂中将包含HMF的原料提供到反应器中。 将空气和O2中的至少一个提供到反应器中。 起始材料与包含Pt的催化剂在载体材料上接触，其中接触在约50℃至约200℃的反应器温度下进行。制备其中提供ZrO 2并被煅烧的氧化催化剂的方法 。 将ZrO 2与乙酰丙酮化铂（II）混合以形成混合物。 将混合物进行旋转蒸发以形成产物。 将产物在氢气下煅烧和还原以形成活化产物。 活化产物在2％O 2的流量下钝化。

    Heterocyclic compounds produced from biomass
    10.
    发明授权
    Heterocyclic compounds produced from biomass 失效
    由生物质生产的杂环化合物

    公开(公告)号：US06603026B2

    公开(公告)日：2003-08-05

    申请号：US09923644

    申请日：2001-08-07

    申请人： Gene E. Lightner

    发明人： Gene E. Lightner

    IPC分类号： C07D30746

    CPC分类号： C07D307/44 ,  C07D307/50

    摘要： Sugars derived from acidic hydrolysis of biomass consist of glucose and xyloses which are subjected to dehydration, within the hydrolysis environment, to form heterocyclic compounds, furfural and hydroxymethylfurfural. By providing a vessel for hydrolysis of biomass, a hydrolysate containing acid and heterocyclic compounds is formed. Upon withdrawing the hydrolysate from the vessel, and employment of separating means for removing heterocyclic compounds from the hydrolysate, a hydrolysate substantially devoid of heterocyclic compounds is provided for recycle to the vessel and will provide heterocyclic compounds. By withdrawing solids, containing lignins remaining from hydrolysis of biomass, from the vessel, and filtering the solids, to result in a filtrate for recycle to the vessel and provide filtered solids for subsequent processing. Thereby, heterocyclic compounds are derived from a biomass and withdrawn from the hydrolysis vessel, and solids, remaining from hydrolysis of biomass, are withdrawn from the hydrolysis vessel.

    摘要翻译： 衍生自生物质酸性水解的糖由葡萄糖和木糖组成，在水解环境中脱水，形成杂环化合物，糠醛和羟甲基糠醛。 通过提供用于水解生物质的容器，形成含有酸和杂环化合物的水解产物。 当从容器中取出水解产物并使用从水解产物中除去杂环化合物的分离装置时，提供基本上不含杂环化合物的水解产物用于再循环到容器中并提供杂环化合物。 通过从容器中除去含有从生物质水解中残留的木质素并且过滤固体的固体，以产生用于再循环到容器中的滤液并提供过滤的固体用于后续处理。 因此，杂环化合物衍生自生物质并从水解容器中排出，并且从水解生物质中残留的固体从水解容器中排出。