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公开(公告)号：US20080027221A1
公开(公告)日：2008-01-31
申请号：US11631188
申请日：2005-06-29
申请人： Yasuhiro Ishiwata
发明人： Yasuhiro Ishiwata
IPC分类号： C07D513/04
CPC分类号： C09B29/0081 , C07D513/04 , C09B29/12 , C09B29/26
摘要： An azo dye represented by the following formula (I): wherein, in formula (I), R1, R2, R3, and R4 each independently represent a hydrogen atom, an aliphatic group, an aryl group, a halogen atom, an acyl group, a cyano group, an acylamino group, an aliphatic oxycarbonyl group, an aryloxycarbonyl group, a carbamoyl group, an aliphatic sulfonyl group, an arylsulfonyl group, a sulfamoyl group, an aliphatic oxycarbonylamino group, an aryloxycarbonylamino group, a sulfo group, a carboxyl group, a carbamoylamino group, a sulfamoylamino group, or an aliphatic- or aromatic-sulfonylamino group, wherein R1 and R2 and/or R3 and R4 may be combined with each other to form a five- or six-membered aromatic ring or non-aromatic ring; X represents a carbon atom or a nitrogen atom, wherein n is 0 when X is a nitrogen atom and n is 1 when X is a carbon atom; A, B, C, and D each represent a carbon atom or a nitrogen atom, provided that at least one of A, B, C and D represents a nitrogen atom; Y represents a substituent; and m denotes an integer from 0 to 3.
摘要翻译： 由下式（I）表示的偶氮染料：其中，在式（I）中，R 1，R 2，R 3， R 4各自独立地表示氢原子，脂肪族基团，芳基，卤素原子，酰基，氰基，酰基氨基，脂肪族氧基羰基，芳氧基羰基， 氨基甲酰基，脂族磺酰基，芳基磺酰基，氨磺酰基，脂族氧基羰基氨基，芳氧基羰基氨基，磺基，羧基，氨基甲酰基氨基，氨磺酰基氨基或脂族 - 或芳族 - 磺酰基氨基 基团，其中R 1和R 2和/或R 3和R 4可以彼此结合 形成五元或六元芳香环或非芳香环; X表示碳原子或氮原子，当X为氮原子时，当X为碳原子时，n为1时，n为0; A，B，C和D各自表示碳原子或氮原子，条件是A，B，C和D中的至少一个表示氮原子; Y表示取代基; 并且 m表示0〜3的整数。
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公开(公告)号：US07220857B2
公开(公告)日：2007-05-22
申请号：US11280345
申请日：2005-11-17
IPC分类号： C09B17/00 , C07D237/36 , C07D513/04 , C07D487/04 , C07D471/12
CPC分类号： C07D471/04 , C07D237/36 , C07D471/14 , C07D487/04 , C07D513/04 , C09B37/00
摘要： A compound represented by formula (I):Formula (I) wherein Z1 and Z2 each are atoms necessary for forming an aromatic ring; V1 and V2 each are a substituent W1 or W2; when at least one V1 is W1, at least one V2 is W2, or when at least one V1 is W2, at least one V2 is W1; r is 1 to 4; s is 1 to 4; M1 is a counter ion; m1 is the number necessary for neutralizing charge; W1 is a hydroxyl, primary- or secondary- or tertiary-amino, acylamino, or sulfonamido group; W2 is a nitro, cyano, alkoxycarbonyl, aryloxycarbonyl, alkyl- or aryl-sulfonyl, carbamoyl, sulfamoyl, alkenyl, alkynyl, aryl, heterocyclic, sulfo, carboxyl, heterocyclic oxy, ammonio, alkyl- or aryl-sulfinyl, alkyl- or aryl-sulfonyl, acyl, or aryl- or heterocyclic-azo group; and the aromatic ring may have a substituent other than V1 and V2.
摘要翻译： 式（I）表示的化合物：式（I）其中Z 1和Z 2各自为形成芳环所必需的原子; V 1和V 2各自为取代基W 1或W 2; 当至少一个V 1是W 1时，至少一个V 2是W 2 2，或者当在 至少一个V 1是W 2，至少一个V 2是W 1; r为1〜4; s是1到4; M 1是抗衡离子; m 1 是中和电荷所需的数量; W 1是羟基，伯或仲或叔氨基，酰氨基或亚磺酰氨基; W 2是硝基，氰基，烷氧基羰基，芳氧基羰基，烷基 - 或芳基 - 磺酰基，氨基甲酰基，氨磺酰基，烯基，炔基，芳基，杂环，磺基，羧基，杂环氧基，氨基，烷基 - 或 芳基 - 亚磺酰基，烷基 - 或芳基 - 磺酰基，酰基或芳基 - 或杂环 - 偶氮基; 芳环可以具有除V 1和V 2以外的取代基。
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公开(公告)号：US20060111568A1
公开(公告)日：2006-05-25
申请号：US11280399
申请日：2005-11-17
IPC分类号： C07D487/04
CPC分类号： C07D487/04
摘要： A compound represented by formula (I): Formula (I) wherein Z1 is atoms necessary for forming an aromatic ring; Z2 is atoms necessary for forming an aromatic hetero ring; V1 and V2 each are a substituent, and at least one of V1 and V2 is a hydroxyl, primary- or secondary- or tertiary-amino, acylamino, or sulfonamido group; r is 1 to 4; s is 1 to 4; the ring formed by Z1 or Z2 may have a substituent other than V1 or V2; M1 is a counter ion; m1 is the number necessary for neutralizing charge; and X1 and X2 each are a carbon or hetero atom, and at least one of X1 and X2 is a hetero atom.
摘要翻译： 由式（I）表示的化合物：式（I）其中Z 1是形成芳环所必需的原子; Z 2是形成芳族杂环所必需的原子; V 1和V 2各自为取代基，V 1和V 2 2中的至少一个为 羟基，伯或仲 - 或叔 - 氨基，酰氨基或亚磺酰氨基; r为1〜4; s是1到4; 由Z 1或Z 2形成的环可以具有除V 1或V 2以外的取代基; M 1是抗衡离子; m 1 是中和电荷所需的数量; X 1和X 2各自为碳或杂原子，X 1和X 2 2中的至少一个为碳原子或杂原子， SUB>是杂原子。
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公开(公告)号：US20060024624A1
公开(公告)日：2006-02-02
申请号：US11190925
申请日：2005-07-28
IPC分类号： G03C7/32
CPC分类号： G03C8/408
摘要： A heat-developable color light-sensitive material containing light-sensitive silver halide grains, a binder, at least one compound of formula (I), and at least one dye-providing compound of formula (II), on a support, wherein at least one of layers containing the light-sensitive silver halide grains contains the binder, the compound of formula (I), and the dye-providing compound of formula (II) and, wherein the heat-developable color light-sensitive material contains no compound that participates in a coupling reaction with an oxidized product of the compound of formula (I): Formula (I) wherein Z represents a carbamoyl, acyl, alkoxycarbonyl, aryloxycarbonyl, sulfonyl, or sulfamoyl group; and Q1 represents a group of atoms necessary to form an unsaturated ring; Formula (II) wherein DYE represents a dye or dye precursor group; Y represents a specific group; X represents a simple bond or a connecting group; p denotes 1 or more, and q denotes 1 or 2.
摘要翻译： 包含感光卤化银颗粒，粘合剂，至少一种式（I）化合物和至少一种提供式（II）化合物的染料提供化合物的热可显影颜色光敏材料，其中在 含有感光卤化银颗粒的层的至少一层含有粘合剂，式（I）化合物和式（II）的染料提供化合物，其中可热显色的感光材料不含化合物 其参与与式（I）化合物的氧化产物的偶联反应：式（I）其中Z表示氨基甲酰基，酰基，烷氧基羰基，芳氧基羰基，磺酰基或氨磺酰基; 且Q 1表示形成不饱和环所必需的一组原子; 式（II）其中DYE表示染料或染料前体基团; Y表示特定组; X表示简单的键或连接组; p表示1以上，q表示1或2。
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15.发明授权公开(公告)号：US06989439B2
公开(公告)日：2006-01-24
申请号：US10359132
申请日：2003-02-06
IPC分类号： C09B29/033
CPC分类号： C07D271/07 , C09B29/0066 , C09B29/26 , C09B29/28 , C09B29/325 , C09B29/36 , G03C1/42 , G03C7/413
摘要： A color-developing agent of the formula (1-1): wherein X represents a hydrogen atom or a substituent, and Z represents a carbamoyl, acyl, alkoxycarbonyl, or aryloxycarbonyl group. An azo dye of the formula (2-1): wherein R1 represents a hydrogen atom or a substituent, and A represents a group of atoms necessary to form the azo dye by the compound of formula (2-1). A silver halide photographic light-sensitive material containing any of the color-developing agent and the azo dye in at least one photographic constitutional layer.
摘要翻译： 式（1-1）的显色剂：其中X表示氢原子或取代基，Z表示氨基甲酰基，酰基，烷氧基羰基或芳氧基羰基。 式（2-1）的偶氮染料：其中R 1表示氢原子或取代基，A表示通过式（2）的化合物形成偶氮染料所需的原子团 -1）。 在至少一个照相结构层中含有任何显色剂和偶氮染料的卤化银照相感光材料。
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公开(公告)号：US07896931B2
公开(公告)日：2011-03-01
申请号：US12598790
申请日：2008-06-27
IPC分类号： A61Q5/10
CPC分类号： A61K8/49 , A61K8/494 , A61K8/4946 , A61K2800/4322 , A61K2800/4324 , A61Q5/065 , A61Q5/10
摘要： The present invention relates to a hair dye composition containing a dissociative azo dye which has high dyeing power, is capable of imparting a vivid color to the hair firmly, has excellent fastness to light, shampooing, sweat, friction, and heat, and fades less with the passage of time because the dye is stable against an alkali agent or an oxidizing agent and does not decompose during hair dyeing; and a hair dyeing method using the hair dye composition.
摘要翻译： 本发明涉及一种含有具有高染色力的离解偶氮染料的染发剂组合物，能够使头发牢固地赋予头发鲜艳的色泽，具有优异的耐光性，洗发剂，汗液，摩擦和热量，并且减少 随着时间的推移，因为染料对碱剂或氧化剂是稳定的，并且在染发期间不分解; 和使用染发组合物的染发方法。
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公开(公告)号：US07651538B2
公开(公告)日：2010-01-26
申请号：US11816422
申请日：2006-02-10
IPC分类号： A61Q5/10 , C07D275/02
CPC分类号： A61K8/49 , A61K8/69 , A61K2800/4322 , A61Q5/065 , C07D513/04 , C09B29/0081 , C09B29/14 , C09B29/3626
摘要： A hair dye composition containing an azo dye (1) or a salt thereof, (wherein R1 to R4 represents H, aliphatic hydrocarbon group, aryl group, halogen atom, acyl group, cyano group, acylamino group, or the like, wherein R1 and R2, and/or R3 and R4 may be coupled to form a 5- or 6-membered ring; X represents C or N, with the proviso that when X represents C, n stands for 1, and when X represents N, n stands for 0; A1, A2, A3 and A4 each represents N or represents C substituted by Y or having H, with the proviso that at least one of A1, A2, A3 and A4 is a nitrogen atom; and Y represents a substituent with the proviso that m stands for an integer from 0 to 3).
摘要翻译： 含有偶氮染料（1）或其盐（其中R 1至R 4表示H，脂族烃基，芳基，卤原子，酰基，氰基，酰氨基等）的染发剂组合物，其中R1和 R 2和/或R 3和R 4可以连接形成5-或6-元环; X表示C或N，条件是当X表示C时，n表示1，当X表示N时，n表示 对于0; A1，A2，A3和A4各自表示N或表示被Y取代或具有H的C，条件是A1，A2，A3和A4中的至少一个为氮原子; Y表示与 条件是m代表0至3的整数）。
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公开(公告)号：US07629459B2
公开(公告)日：2009-12-08
申请号：US11280399
申请日：2005-11-17
IPC分类号： C07D487/04 , C09B29/00
CPC分类号： C07D487/04
摘要： A compound represented by formula (I):Formula (I) wherein Z1 is atoms necessary for forming an aromatic ring; Z2 is atoms necessary for forming an aromatic hetero ring; V1 and V2 each are a substituent, and at least one of V1 and V2 is a hydroxyl, primary- or secondary- or tertiary-amino, acylamino, or sulfonamido group; r is 1 to 4; s is 1 to 4; the ring formed by Z1 or Z2 may have a substituent other than V1 or V2; M1 is a counter ion; m1 is the number necessary for neutralizing charge; and X1 and X2 each are a carbon or hetero atom, and at least one of X1 and X2 is a hetero atom.
摘要翻译： 由式（I）表示的化合物：式（I）其中Z 1是形成芳环所必需的原子; Z2是形成芳族杂环所必需的原子; V1和V2各自为取代基，V1和V2中的至少一个为羟基，伯或仲或叔氨基，酰氨基或亚磺酰氨基; r为1〜4; s是1到4; 由Z1或Z2形成的环可以具有除V1或V2以外的取代基; M1是抗衡离子; m1是中和电荷所需的数字; X 1和X 2各自为碳原子或杂原子，X 1和X 2中的至少一个为杂原子。
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公开(公告)号：US07476261B2
公开(公告)日：2009-01-13
申请号：US11722750
申请日：2005-12-20
IPC分类号： A61Q5/10 , C07D285/14
摘要： A hair dye composition containing an azo dye (1) or a salt thereof: wherein R represents a coupler moiety, R1 and R3 each independently represent —SO3M, —SO2NR4R5 or a hydrogen atom, R2, R4 and R5 each independently represent a hydrogen atom or a substituent, and M represents a hydrogen atom, metal atom or ammonium, with a proviso that R1 and R3 are not hydrogen atoms at the same time.
摘要翻译： 含有偶氮染料（1）或其盐的染发剂组合物：其中R表示成色剂部分，R 1和R 3各自独立地表示-SO 3 M，-SO 2 NR 4 R 5或氢原子，R 2，R 4和R 5各自独立地表示氢原子 或取代基，M表示氢原子，金属原子或铵，条件是R1和R3不同时为氢原子。
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公开(公告)号：US07358344B2
公开(公告)日：2008-04-15
申请号：US10980786
申请日：2004-11-04
IPC分类号： C09B29/033 , C09B29/036 , C09B29/039 , C09B29/12
CPC分类号： C09B29/0074 , C09B29/0025
摘要： An azo dye represented by formula (I): A-N═N—B formula (I) wherein, A represents a group having a substituent required for inducing an intramolecular nucleophilic substitution reaction with a nitrogen atom of a reduced azo group as a nucleophilic species when the azo group is reductively decomposed, the group forming a compound containing the nitrogen atom in a ring structure, and B represents an aromatic or hetero ring which is bound to the azo group through a carbon atom.
摘要翻译： 由式（I）表示的偶氮染料：<？in-line-formula description =“In-line formula”end =“lead”？> ANNB formula（I）<？in-line-formula description =“In-line 式“end =”tail“？>其中，A表示当偶氮基被还原分解时，具有作为亲核物质的还原偶氮基团的氮原子诱导分子内亲核取代反应所需的取代基的基团， 在环结构中含有氮原子的化合物，B表示通过碳原子与偶氮基结合的芳香族或杂环。
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