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    Ink, inkjet ink, inkjet recording method and method for improving weather resistance of color image material
    1.
    发明授权
    Ink, inkjet ink, inkjet recording method and method for improving weather resistance of color image material 有权
    油墨，喷墨油墨，喷墨记录方法和改善彩色图像材料耐候性的方法

    公开(公告)号：US08070868B2

    公开(公告)日：2011-12-06

    申请号：US12161225

    申请日：2007-01-19

    申请人： Keiichi Tateishi

    发明人： Keiichi Tateishi

    IPC分类号： C09D11/00 ,  C09D11/02

    CPC分类号： C09B29/36 ,  B41M5/5218 ,  C09B33/12 ,  C09D11/328

    摘要： An ink includes at least one coloring matter represented by a formula (I): wherein R1 represents one of an alkyl group, an alkenyl group, an alkynyl group, an aralkyl group, an aryl group, a heterocyclic group, an acyl group, an alkyloxycarbonyl group, an aryloxycarbonyl group, a carbamoyl group, an alkylsulfonyl group, an arylsulfonyl group and a sulfamoyl group, which may have a substituent; X1 represents one of —CR2═ and a nitrogen atom, R2 represents one of a hydrogen atom and a substituent, and when R2 represents a substituent, R2 may have a substituent; X2 represents one of —CR3═ and a nitrogen atom, and R3 represents an electron-withdrawing group having a σp value of 0.20 or more; when X1 represents —CR2═, a pair of R1 and R2 and/or when X2 represents —CR3═, a pair of R2 and R3 each may combine to form a 5- to 7-membered ring; the coloring matter may form one of a dimer and a trimer through R1, R2, R3 or A; and A represents a prescribed aryl group or heterocyclic group etc.

    摘要翻译： 油墨包括由式（I）表示的至少一种着色剂：其中R1表示烷基，烯基，炔基，芳烷基，芳基，杂环基，酰基， 烷氧基羰基，芳氧基羰基，氨基甲酰基，烷基磺酰基，芳基磺酰基和氨磺酰基，其可以具有取代基; X1表示-CR2 =和氮原子之一，R2表示氢原子和取代基中的一个，当R2表示取代基时，R2可以具有取代基。 X2代表-CR3 =和氮原子之一，R3表示具有0.20以上p值的吸电子基团; 当X1表示-CR2 =时，一对R1和R2和/或当X2表示-CR3 =时，一对R2和R3各自可以组合形成5-至7-元环; 着色剂可以通过R1，R2，R3或A形成二聚体和三聚体之一; A表示规定的芳基或杂环基等。

    Method for preparing light-absorbing polymeric compositions
    4.
    发明申请
    Method for preparing light-absorbing polymeric compositions 失效
    光吸收聚合物组合物的制备方法

    公开(公告)号：US20010023938A1

    公开(公告)日：2001-09-27

    申请号：US09751766

    申请日：2000-12-29

    发明人： Max Allen ,  James John Krutak SR. ,  Brian Edison Maxwell ,  Gerry Foust Rhodes ,  Samuel David Hilbert ,  Jean Carroll Fleischer ,  William Whitfield Parham

    IPC分类号： F21V009/00

    CPC分类号： C09B31/02 ,  C09B1/32 ,  C09B1/585 ,  C09B1/62 ,  C09B5/14 ,  C09B29/0007 ,  C09B29/0025 ,  C09B29/08 ,  C09B29/36 ,  C09B69/101 ,  C09B69/106 ,  C09B69/109

    摘要： The present invention recites a method comprising reacting in a solvent in the presence of a base a) at least one diacidic monomer comprising about 1 to 100 mole % of at least one light-absorbing monomer having a light absorption maximum between about 300 nm and about 1200 nm and 99-0 mole % of a non-light absorbing monomer which does not absorb significant light at wavelengths above 300 nm or has a light absorption maximum below 300 nm, with b) an organic compound of Formula II XnullBnullX1 wherein B is a divalent organic radical to form a light absorbing composition comprising a mixture of a polymer having the formula 1 and a cyclic compound having the general formula 2 wherein B is as defined above; n is at least 2, m is 1, 2, 3 or 4 and A comprises the residue of a diacidic monomer comprising about 1 to 100 mole % of at least one light-absorbing monomer having a light absorption maximum between about 300 nm and about 1000 nm and wherein the remaining portion of A comprises the residue of a non-light absorbing monomer which does not absorb significant light at wavelengths above 300 nm or has a light absorption maximum below 300 nm.

    摘要翻译： 本发明描述了一种方法，包括在碱的存在下在溶剂中反应a）至少一种二酸单体，其包含约1至100摩尔％的至少一种光吸收单体，其光吸收最大值在约300nm至约 1200nm和99-0摩尔％的非光吸收单体，其不吸收波长高于300nm或在300nm以下的光吸收最大值的显着光，其中b）式II的有机化合物<第lvl =“ 其中B是二价有机基团以形成光吸收组合物，其包含具有下式的聚合物和具有一般的环状化合物的混合物的光吸收组合物 其中B如上所定义; n至少为2，m为1,2,3或4，A包含二酸单体的残基，该二酸单体包含约1至100摩尔％的至少一种光吸收单体的光吸收最大值在约300nm至约 1000nm，并且其中A的剩余部分包含不吸收波长高于300nm或在300nm以下的光吸收最大值的不吸收光的非光吸收单体的残基。

    Method for preparing light-absorbing polymeric compositions
    5.
    发明授权
    Method for preparing light-absorbing polymeric compositions 失效
    光吸收聚合物组合物的制备方法

    公开(公告)号：US06197223B1

    公开(公告)日：2001-03-06

    申请号：US09320002

    申请日：1999-05-26

    申请人： Max Allen Weaver ,  James John Krutak, Sr. ,  Brian Edison Maxwell ,  Gerry Foust Rhodes ,  Samuel David Hilbert ,  Jean Carroll Fleischer ,  William Whitfield Parham

    发明人： Max Allen Weaver ,  James John Krutak, Sr. ,  Brian Edison Maxwell ,  Gerry Foust Rhodes ,  Samuel David Hilbert ,  Jean Carroll Fleischer ,  William Whitfield Parham

    IPC分类号： F21V900

    CPC分类号： C09B31/02 ,  C09B1/32 ,  C09B1/585 ,  C09B1/62 ,  C09B5/14 ,  C09B29/0007 ,  C09B29/0025 ,  C09B29/08 ,  C09B29/36 ,  C09B69/101 ,  C09B69/106 ,  C09B69/109

    摘要： The present invention recites a method comprising reacting in a solvent in the presence of a base a) at least one diacidic monomer comprising about 1 to 100 mole % of at least one light-absorbing monomer having a light absorption maximum between about 300 nm and about 1200 nm and 99-0 mole % of a non-light absorbing monomer which does not absorb significant light at wavelengths above 300 nm or has a light absorption maximum below 300 nm, with b) an organic compound of Formula II X—B—X1 wherein B is a divalent organic radical to form a light absorbing composition comprising a mixture of a polymer having the formula and a cyclic compound having the general formula wherein B is as defined above; n is at least 2, m is 1, 2, 3 or 4 and A comprises the residue of a diacidic monomer comprising about 1 to 100 mole % of at least one light-absorbing monomer having a light absorption maximum between about 300 nm and about 1000 nm and wherein the remaining portion of A comprises the residue of a non-light absorbing monomer which does not absorb significant light at wavelengths above 300 nm or has a light absorption maximum below 300 nm.

    摘要翻译： 本发明描述了一种方法，包括在碱的存在下在溶剂中反应至少一种二酸单体，其包含约1至100摩尔％的至少一种光吸收单体，其光吸收最大值在约300nm至约1200 nm和99-0摩尔％的非光吸收单体，其不吸收波长高于300nm的显着光或具有300nm以下的光吸收最大值，b）式II的有机化合物，其中B是二价有机基团， 形成包含具有下式的聚合物和具有通式化合物B的环状化合物的混合物的光吸收组合物如上所定义; n至少为2，m为1,2,3或4，A包含二酸单体的残基，该二酸单体包含约1至100摩尔％的至少一种光吸收单体的光吸收最大值在约300nm至约 1000nm，并且其中A的剩余部分包含不吸收波长高于300nm或在300nm以下的光吸收最大值的不吸收光的非光吸收单体的残基。

    Monoazo dyes which are free from water-solubilizing groups and which contain a fluorosulphonyl group and process for colouring polyamides and polyester materials therewith
    6.
    发明授权
    Monoazo dyes which are free from water-solubilizing groups and which contain a fluorosulphonyl group and process for colouring polyamides and polyester materials therewith 失效
    不含水溶性基团并含有氟磺酰基的单偶氮染料和聚酰胺和聚酯材料着色的方法

    公开(公告)号：US5739299A

    公开(公告)日：1998-04-14

    申请号：US676234

    申请日：1996-07-15

    申请人： Nigel Hall

    发明人： Nigel Hall

    IPC分类号： C07D333/36 ,  C07D231/38 ,  C07D275/02 ,  C07D275/04 ,  C07D277/20 ,  C07D277/50 ,  C07D277/70 ,  C07D285/08 ,  C07D285/12 ,  C07D285/135 ,  C07D307/12 ,  C07D333/38 ,  C09B29/00 ,  C09B29/01 ,  C09B29/033 ,  C09B29/08 ,  C09B29/095 ,  C09B29/15 ,  C09B29/36 ,  C09B62/825 ,  D06P1/04 ,  D06P1/38 ,  D06P3/26 ,  D06P3/82

    CPC分类号： D06P3/8233 ,  C09B29/0003 ,  C09B29/0014 ,  C09B29/0025 ,  C09B29/0811 ,  C09B29/0838 ,  C09B29/095 ,  C09B29/10 ,  C09B29/36 ,  C09B62/825 ,  D06P3/26

    摘要： A process for coloring a synthetic textile material or fibre blend thereof which comprises applying to the synthetic textile material a compound or mixture thereof, which is free from water solubilizing groups, of Formula (1): A--N.dbd.N--D Formula (1) wherein A and D each independently is an optionally substituted heterocyclic or carbocyclic group and at least one of A or D carries directly at least one --SO.sub.2 F group or carries a substituent to which at least one --SO.sub.2 F group is attached except for 4-(4-fluorosulphonylphenylazo)-N,N-dimethylaniline, provided that one of A or D is not 3,5-difluorosulphonylthien-2-yl, optionally substituted 1-phenyl-pyrazol-4-yl-5-one or ##STR1## or that one of A or D does not carry an --NCH.sub.2 CH(OH)CH.sub.2 Cl, --NCOCH.sub.2 Cl or --NCH.sub.2 CH.sub.2 SO.sub.2 F substituent. The presence of one or more --SO.sub.2 F groups in a dye molecule generally improves the properties of that dye and confers surprisingly good wet fastness and light fastness properties.

    摘要翻译： PCT No.PCT / GB94 / 02831 Sec。 371日期：1996年7月15日 102（e）日期1996年7月15日PCT 1994年12月30日PCT PCT。 第WO95 / 20014号公报 日期1995年7月27日一种用于着色合成纺织材料或其纤维混合物的方法，其包括向合成纺织品材料施加式（1）的无水溶性基团的化合物或其混合物：AN = N-DFormula （1）其中A和D各自独立地是任选取代的杂环或碳环基团，并且A或D中的至少一个直接携带至少一个-SO 2 F基团或携带至少一个-SO 2 F基团连接的取代基，除了4 - （4-氟磺酰基苯偶合）-N，N-二甲基苯胺，条件是A或D之一不是3,5-二氟磺酰基噻吩-2-基，任选取代的1-苯基 - 吡唑-4-基-5-酮或或A或D中的一个不携带-NCH 2 CH（OH）CH 2 Cl，-NCOCH 2 Cl或-NCH 2 CH 2 SO 2 F取代基。 染料分子中一个或多个-SO 2 F基团的存在通常改善了该染料的性质，并赋予令人惊奇的良好的耐湿牢度和耐光性能。

    Azo compounds having a 5-substituted-4-chlorothiazolyl-2-diazo component radical
    7.
    发明授权
    Azo compounds having a 5-substituted-4-chlorothiazolyl-2-diazo component radical 失效
    具有5-取代-4-氯噻唑基-2-重氮组分基团的偶氮化合物

    公开(公告)号：US4505857A

    公开(公告)日：1985-03-19

    申请号：US242506

    申请日：1981-03-10

    申请人： Robert Egli

    发明人： Robert Egli

    IPC分类号： C09B29/042 ,  C09B29/00 ,  C09B29/06 ,  C09B29/15 ,  C09B29/36 ,  C09B56/00 ,  C09B56/16 ,  C09B29/09 ,  C09B29/095 ,  D06P1/18

    CPC分类号： C09B29/0085 ,  C09B29/06 ,  C09B29/10 ,  C09B29/36

    摘要： Compounds of the formula ##STR1## in which K is the radical of a coupling component of the aniline, .alpha.-naphthylamine, pyrazolone, aminopyrazole, indole, tetrahydroquinoline, thiazole, phenol, naphthol, pyridine or pyridone series.R is --CHO, --CH.dbd.C(CN)--R.sub.1, --CH.dbd.CH--R.sub.2, --CH.dbd.C(NO.sub.2)--R.sub.3, --CH.dbd.NOH or --CN,wherein R.sub.1 is (C.sub.1-10 alkoxycarbonyl; (C.sub.1-10 alkoxy)carbonyl monosubstituted by chloro, bromo, cyano, hydroxy, C.sub.1-2 alkoxy, (C.sub.1-2 alkyl)carbonyloxy or (C.sub.1-2 alkoxy)carbonyl; (C.sub.1-10 alkoxy)carbonyl disubstituted by hydroxy and by chloro or bromo; (C.sub.3-8 alkenyl)oxycarbonyl; (C.sub.3-8 chloroalkenyl)oxycarbonyl; (C.sub.3-8 bromoalkenyl)oxycarbonyl; propynyloxycarbonyl; benzyloxycarbonyl; chlorobenzyloxycarbonyl; nitrobenzyloxycarbonyl; C.sub.1-4 alkylsulfonyl; phenylsulfonyl; tolylsulfonyl; carbamoyl; (C.sub.1-2 alkyl)carbamoyl; di(C.sub.1-2 alkyl)carbamoyl; phenylcarbamoyl; aminothiocarbonyl; benzimidazolyl-2; cyano; acetyl; phenyl; benzoyl or phenyl or benzoyl substituted by 1, 2 or 3 substituents each of which is independently chloro, bromo or nitro, with the proviso that the maximum number of nitro groups is two, andR.sub.2 is phenyl; benzoyl or phenyl or benzoyl substituted by 1, 2 or 3 substituents each of which is independently chloro, bromo or nitro, with the proviso that the maximum number of nitro groups is two, andR.sub.3 is hydrogen, methyl or ethyl, andm is 0 or 1, useful as disperse dyes for dyeing and printing textile substrates comprising or consisting of synthetic or semi-synthetic, hydrophobic, high molecular weight, organic materials such as linear aromatic polyesters, cellulose 21/2 acetate, cellulose triacetate and synthetic polyamides, with those wherein R is formyl also being useful for dyeing wool.

    摘要翻译： 式（I）的化合物其中K是苯胺，α-萘胺，吡唑啉酮，氨基吡唑，吲哚，四氢喹啉，噻唑，苯酚，萘酚，吡啶或吡啶酮系列的偶联组分的基团。 R为-CHO，-CH = C（CN）-R1，-CH = CH-R2，-CH = C（NO2）-R3，-CH = NOH或-CN，其中R1为（C1-10烷氧基羰基;（C1 （C1-2烷基）羰基氧基或（C1-2烷氧基）羰基;被羟基和氯或溴二取代的（C1-10烷氧基）羰基;（C3-烷氧基）羰基，被氯，溴，氰基，羟基， （C 3-8）烯基）氧羰基;（C3-8溴链烯基）氧羰基;（C3-8溴链烯基）氧羰基;丙炔氧羰基;苄氧羰基;氯苄氧基羰基;硝基苄氧羰基; C1-4烷基磺酰基;苯基磺酰基;甲苯磺酰基;氨基甲酰基;（C1-2烷基）氨基甲酰基; 苯基氨基甲酰基;氨基硫代羰基;苯并咪唑基-2;氰基;乙酰基;苯基;苯甲酰基或被1,2或3个取代基取代的苯甲酰基，其各自独立地为氯，溴或硝基，条件是硝基的最大数目为 两个，R 2是苯基;苯甲酰基或被1,2或3个取代基取代的苯甲酰基，各自独立地是氯，溴或硝基，与 条件是硝基的最大数目为2，R3为氢，甲基或乙基，m为0或1，可用作染色和印刷纺织基材的分散染料，包含合成或半合成，疏水， 高分子量的有机材料，例如线性芳族聚酯，纤维素21/2乙酸酯，三醋酸纤维素和合成聚酰胺，其中R是甲酰基也可用于染色羊毛。

    Color photographic recording material containing a non-diffusible dye releaser from which a complexible azo dye is released during development
    9.
    发明授权
    Color photographic recording material containing a non-diffusible dye releaser from which a complexible azo dye is released during development 失效
    包含非扩散性染料释放剂的彩色照相记录材料，在显影过程中从其中释放可络合的偶氮染料

    公开(公告)号：US4461827A

    公开(公告)日：1984-07-24

    申请号：US455319

    申请日：1983-01-03

    申请人： Peter Bergthaller ,  Gunther Schenk ,  Gerhard Wolfrum

    发明人： Peter Bergthaller ,  Gunther Schenk ,  Gerhard Wolfrum

    IPC分类号： C09B29/01 ,  C09B29/36 ,  C09B45/14 ,  G03C8/10 ,  G03C5/54 ,  G03C1/40 ,  G03C7/00

    CPC分类号： C09B29/36 ,  C09B29/0007 ,  C09B45/14 ,  G03C8/10

    摘要： Metal complexes, particularly copper and nickel complexes, of azo dyes corresponding to formula suitable for use as magenta-colored image dyes for the production of colored images by the dye diffusion transfer process. The dyes are linked (in non-metallized form) to a carrier radical provided with a ballast group as so-called color-providing compounds which are associated with a photosensitive silver halide emulsion layer. During development, the metallizable dyes are released imagewise and, after diffusion into an image-receiving layer, are converted into the corresponding metal complexes. ##STR1## In formula II, R.sup.1, R.sup.2, R.sup.3 and R.sup.4 represent H, F, Cl, Br, --CN, --NO.sub.2, --CF.sub.3, --OCH.sub.3, --SCF.sub.3, alkyl, alkoxy, alkylthio, acylamino, alkyl sulphonyl, aryl sulphonyl, --CO--X or --SO.sub.2 Y; or two adjacent radicals from the group of radicals R.sup.1 to R.sup.4 together represent a fused benzene ring;R.sup.5 represents H, alkyl, alkoxy, aryl, alkoxy carbonyl, carbamoyl or cyano,R.sup.6 and R.sup.7 represent H, halogen, alkyl, --CF.sub.3 or --SO.sub.2 --Y,G represents --OH or a hydrolyzable precursor thereof,X represents --OH, alkoxy or an amino group;Y represents H, --OH, an amino group or a group of the formula --NH--SO.sub.2 --R.sup.8 whereR.sup.8 represents alkyl, aryl or an amino group; andm=0 or 1.

    摘要翻译： 金属络合物，特别是铜和镍络合物，对应于适合用作品红色图像染料的式的偶氮染料，用于通过染料扩散转移方法生产彩色图像。 将染料以非金属化形式连接到具有镇流器基团的载体基团上，所述载体基团与感光卤化银乳剂层相关联的所谓的提供色彩的化合物。 在显影过程中，金属化染料被成像释放，并且在扩散到图像接收层中后，转化成相应的金属络合物。 式II中，R 1，R 2，R 3和R 4表示H，F，Cl，Br，-CN，-NO 2，-CF 3，-OCH 3，-SCF 3，烷基，烷氧基，烷硫基，酰氨基，烷基磺酰基， 芳基磺酰基，-CO-X或-SO 2 Y; 或者R 1〜R 4基团的两个相邻基团一起表示稠合苯环; R5代表H，烷基，烷氧基，芳基，烷氧基羰基，氨基甲酰基或氰基，R6和R7表示H，卤素，烷基，-CF3或-SO2-Y，G表示-OH或其可水解的前体，X表示-OH， 烷氧基或氨基; Y表示H，-OH，氨基或式-NH-SO 2 -R 8的基团，其中R 8表示烷基，芳基或氨基; m = 0或1。

    Electrophotographic plate having azo compound photosensitive layer
    10.
    发明授权
    Electrophotographic plate having azo compound photosensitive layer 失效
    具有偶氮化合物感光层的电子照相板

    公开(公告)号：US4396696A

    公开(公告)日：1983-08-02

    申请号：US363883

    申请日：1982-03-31

    申请人： Hideki Nagasaka ,  Tetsuo Murayama

    发明人： Hideki Nagasaka ,  Tetsuo Murayama

    IPC分类号： C07D471/06 ,  C09B29/15 ,  C09B29/36 ,  C09B35/03 ,  C09B35/378 ,  G03G5/06 ,  G03G5/09

    CPC分类号： C09B29/36 ,  C09B35/03 ,  C09B35/378 ,  G03G5/0677 ,  G03G5/0681 ,  G03G5/0688

    摘要： An electrophotographic plate comprising an electroconductive substrate and a photosensitive layer coated thereon, wherein said photosensitive layer comprises an azo compound represented by the general formula (I) ##STR1## wherein A is a divalent group of an aromatic hydrocarbon or a divalent group of a heterocyclic ring containing at least one nitrogen atom in the ring, Ar is an aromatic hydrocarbon group or a heterocyclic group which may be bonded through a connecting group, and n is an integer of 1, 2 or 3.

    摘要翻译： 一种电子照相板，包括导电基材和涂覆在其上的感光层，其中所述感光层包含由通式（I）表示的偶氮化合物，其中A是芳族烃或二价基团的二价基团 的环中含有至少一个氮原子的杂环，Ar是可以通过连接基团键合的芳族烃基或杂环基，n是1,2或3的整数。