公开(公告)号：US08703244B2

公开(公告)日：2014-04-22

申请号：US12138729

申请日：2008-06-13

申请人： Shirou Asada ,  Hisao Koba ,  Akihiro Ito ,  Kazutami Mitani ,  Kimihiro Ikezaki ,  Koki Wakabayashi

发明人： Shirou Asada ,  Hisao Koba ,  Akihiro Ito ,  Kazutami Mitani ,  Kimihiro Ikezaki ,  Koki Wakabayashi

IPC分类号： B05D3/12

CPC分类号： C08K9/08 ,  B29B15/10 ,  B29C37/0075 ,  C08J5/24

摘要： A reinforced-fiber sheet impregnated with a matrix resin, a protective film having an irregular surface is applied to at least one surface of the reinforced-fiber sheet impregnated with the matrix resin such that the irregular surface faces the reinforced-fiber sheet. The thus-formed reinforced-fiber sheet covered with a protective film is kept at a temperature of 50-130° C. for four hours or more such that the viscosity of the impregnated resin is 100-10000 poise.

摘要翻译： 将浸渍有基质树脂的增强纤维片材，具有不规则表面的保护膜施加到浸渍有基质树脂的增强纤维片材的至少一个表面，使得不规则表面面向增强纤维片材。 将由保护膜覆盖的如此形成的增强纤维片材保持在50-130℃的温度下4小时以上，使得浸渍树脂的粘度为100-100泊。

公开(公告)号：US20050101748A1

公开(公告)日：2005-05-12

申请号：US11016742

申请日：2004-12-21

申请人： Takashi Kaneko ,  Kazutami Mitani

发明人： Takashi Kaneko ,  Kazutami Mitani

IPC分类号： C08G59/38 ,  C08G59/50 ,  C08L63/00 ,  C08G59/04

CPC分类号： C08G59/38 ,  C08G59/5033 ,  C08L63/00 ,  Y10T428/24994

摘要： An epoxy resin composition according to the present invention is an epoxy resin composition with a viscosity at 25° C. of no more than 1000 mPa·s, incorporating (A) at least one of a bisphenol type epoxy resin (A1) and a phenol novolak type epoxy resin (A2), a polyvalent epoxy resin formed from a mononuclear aromatic backbone (B) and an aromatic amine curing agent (C), wherein a cured product produced by curing the epoxy resin composition displays a breaking elongation of at least, 5%. The epoxy resin composition has a low viscosity at room temperature which can be sustained with good stability for long periods. Furthermore, a cured product produced by curing the epoxy resin composition displays excellent heat resistance and mechanical characteristics, and is consequently ideally suited for use as a matrix resin for fiber reinforced composite materials.

摘要翻译： 根据本发明的环氧树脂组合物是在25℃下的粘度不超过1000mPa.s的环氧树脂组合物，其中（A）至少一种双酚型环氧树脂（A1）和苯酚 酚醛清漆型环氧树脂（A2），由单核芳香骨架（B）和芳香胺固化剂（C）形成的多价环氧树脂，其中通过固化环氧树脂组合物制备的固化产物至少显示出断裂伸长率， 5％。 环氧树脂组合物在室温下具有低粘度，可长时间保持良好的稳定性。 此外，通过固化环氧树脂组合物生产的固化产物显示出优异的耐热性和机械特性，因此理想地适合用作纤维增强复合材料的基质树脂。

公开(公告)号：US06875825B2

公开(公告)日：2005-04-05

申请号：US10148873

申请日：2000-12-13

申请人： Takashi Kaneko ,  Kazutami Mitani

发明人： Takashi Kaneko ,  Kazutami Mitani

IPC分类号： C08G59/38 ,  C08G59/50 ,  C08L63/00 ,  B32B17/04 ,  B32B27/04 ,  C08L63/02 ,  C08L63/04

CPC分类号： C08G59/38 ,  C08G59/5033 ,  C08L63/00 ,  Y10T428/24994

摘要： A composition useful as a matrix for fiber-reinforced composites possesses a viscosity at 25° C. of no more than 1000 mPa's, and provides a cured product displays a breaking elongation of at least 5%. The composition comprises (A) at least one of a bisphenol epoxy resin (A1) and a phenol novolak type epoxy resin (A2), a polyvalent epoxy resin formed from a mononuclear aromatic backbone (B), and an aromatic amine curing agent (C).

摘要翻译： 用作纤维增强复合材料的基质的组合物在25℃下的粘度不超过1000mPa，并且提供固化产物显示至少5％的断裂伸长率。 组合物包含（A）双酚环氧树脂（A1）和苯酚酚醛清漆型环氧树脂（A2）中的至少一种，由单核芳香骨架（B）形成的多价环氧树脂和芳香族胺固化剂（C ）。

公开(公告)号：US4678813A

公开(公告)日：1987-07-07

申请号：US928163

申请日：1986-11-07

申请人： Hajime Itoh ,  Kazutami Mitani

发明人： Hajime Itoh ,  Kazutami Mitani

IPC分类号： B01D67/00 ,  C08J9/40 ,  C08J9/26

CPC分类号： B01D67/0088 ,  B01D67/0093 ,  C08J9/405

摘要： The present invention discloses a hydrophilized porous polyolefin membrane with a polymer of a monomer, which has an HLB value of 2-20, held on at least a part of the pore walls of a porous polyolefin membrane as well as its production process. This hydrophilized porous polyolefin membrane has long-lasting hydrophilicity and good mechanical strength.

摘要翻译： 本发明公开了一种具有HLB值为2-20的单体聚合物的亲水化多孔聚烯烃膜，其保持在多孔聚烯烃膜的孔壁的至少一部分上以及其制备方法。 该亲水化多孔聚烯烃膜具有持久的亲水性和良好的机械强度。

公开(公告)号：US20080248204A1

公开(公告)日：2008-10-09

申请号：US12138729

申请日：2008-06-13

申请人： Shirou Asada ,  Hisao Koba ,  Akihiro Ito ,  Kazutami Mitani ,  Kimihiro Ikezaki ,  Koki Wakabayashi

发明人： Shirou Asada ,  Hisao Koba ,  Akihiro Ito ,  Kazutami Mitani ,  Kimihiro Ikezaki ,  Koki Wakabayashi

IPC分类号： B05D5/02

CPC分类号： C08K9/08 ,  B29B15/10 ,  B29C37/0075 ,  C08J5/24

摘要： The present invention relates to a prepreg which is free from the phenomenon that air is trapped between layers to generate voids, has good handling characteristics and can produce molded articles having any complicated shape and also relates to a method of producing the prepreg. A reinforced-fiber sheet is impregnated with a matrix resin so as to form a continuous resin layer at least in the inside thereof, and then, a protective film having an irregular surface is applied to at least one surface of the reinforced-fiber sheet impregnated with the matrix resin such that the irregular surface faces the reinforced-fiber sheet. In this state, the prepreg is allowed to leave at 30 to 60° C. under the atmosphere for 12 hours or more. The resulting prepreg (1) is provided with a continuous resin layer (3a) which exists therein, wherein at least one surface of one side of the prepreg is constituted of a resin-impregnated part (3b) where the impregnated resin substantially exists and a fiber part (2a) where no resin substantially exists.

摘要翻译： 本发明涉及一种预浸料坯，其没有空气被捕获在层之间以产生空隙的现象，具有良好的处理特性，并且可以生产具有任何复杂形状的模制品，并且还涉及制备预浸料的方法。 增强纤维片材用基质树脂浸渍，以便至少在其内部形成连续的树脂层，然后将具有不规则表面的保护膜施加到浸渍的增强纤维片材的至少一个表面上 基体树脂使得不规则表面面向增强纤维片材。 在这种状态下，允许预浸料在30〜60℃下在大气中离开12小时以上。 所得到的预浸料坯（1）上设置有存在于其中的连续树脂层（3a），其中预浸料坯一侧的至少一个表面由浸渍树脂基本存在的树脂浸渍部分（3b）构成 以及基本上不存在树脂的纤维部分（2a）。

公开(公告)号：US07230052B2

公开(公告)日：2007-06-12

申请号：US11016742

申请日：2004-12-21

申请人： Takashi Kaneko ,  Kazutami Mitani

发明人： Takashi Kaneko ,  Kazutami Mitani

IPC分类号： B32B17/04 ,  B32B27/04 ,  C08L63/02 ,  C08L63/04

CPC分类号： C08G59/38 ,  C08G59/5033 ,  C08L63/00 ,  Y10T428/24994

摘要： A composition useful as a matrix for fiber-reinforced composites possesses a viscosity at 25° C. of no more than 1000 mPa·s and provides a cured product displaying a breaking elongation of at least 5%. The composition comprises (A) at least one of a bisphenol epoxy resin (A1) and a phenol novolak epoxy resin (A2), a polyvalent epoxy resin formed from a mononuclear aromatic backbone (B), an aromatic amine curing agent (C), and a rubber (D).

摘要翻译： 用作纤维增强复合材料的基质的组合物在25℃下的粘度不超过1000mPa.s，并提供显示至少5％的断裂伸长率的固化产物。 该组合物包含（A）双酚环氧树脂（A1）和酚醛清漆环氧树脂（A2）中的至少一种，由单核芳香骨架（B），芳香胺固化剂（C）形成的多价环氧树脂， 和橡胶（D）。

公开(公告)号：US06828016B2

公开(公告)日：2004-12-07

申请号：US10742898

申请日：2003-12-23

申请人： Kazutami Mitani ,  Kazuya Goto

发明人： Kazutami Mitani ,  Kazuya Goto

IPC分类号： B32B1504

CPC分类号： B32B27/34 ,  B29B11/16 ,  B29C70/086 ,  B29C70/48 ,  B29L2009/00 ,  B32B3/22 ,  B32B5/26 ,  Y10T428/24612 ,  Y10T428/24744 ,  Y10T428/2476 ,  Y10T428/24851 ,  Y10T428/249924 ,  Y10T428/249953 ,  Y10T428/249994 ,  Y10T428/25 ,  Y10T428/253 ,  Y10T428/254 ,  Y10T428/269 ,  Y10T428/27 ,  Y10T428/2913 ,  Y10T428/2918 ,  Y10T428/2967

摘要： A preform can be molded by resin transfer molding and yields a composite material having excellent strength and excellent interlaminar debonding resistance. The preform, which is for producing a fiber-reinforced composite, comprises layers of laminated structure of a reinforcing material comprising reinforcement fibers and has, between these layers, a layer comprising a thermoplastic resin and having space so as not to inhibit a liquid resin from flowing therethrough. The preform is molded to yield a fiber-reinforced composite material.

公开(公告)号：US4961853A

公开(公告)日：1990-10-09

申请号：US378571

申请日：1989-06-23

申请人： Hajime Itoh ,  Kouzi Ohbori ,  Kazutami Mitani ,  Hiroshi Takahashi ,  Kouji Takehashi ,  Kunihiro Aoki

发明人： Hajime Itoh ,  Kouzi Ohbori ,  Kazutami Mitani ,  Hiroshi Takahashi ,  Kouji Takehashi ,  Kunihiro Aoki

IPC分类号： B01D67/00 ,  C08J9/40 ,  C08J9/42 ,  G01N30/52

CPC分类号： B01D67/0088 ,  B01D67/0093 ,  C08J9/405 ,  C08J9/42 ,  B01D2323/30 ,  C08J2323/02 ,  C08J2425/00 ,  G01N2030/527

摘要： Disclosed are heat-resisting porous membranes or hydrophilized heat-resisting porous membranes comprising a polyolefin, especially a polyethylene or a polypropylene membrane having a crosslinked polymer held thereon, the crosslinked polymer being composed principally of (a) a polymerizable monomer containing one acid anhydride group or two esterified carboxyl groups or a monomer having at least one carboxylic group and (b) divinylbenzene, or of (a), (b) and further (c) styrene or a derivative thereof, or of (b) and (c). These membranes are prepared by thermally polymerizing some of monomer components from (a) through (c) held on at least a part of the surface of the porous membranes and optionally by further hydrophilizing the crosslinked polymer. The resulting porous membranes are useful for membrane separation requiring steam sterilization and for membrane separation of water of a high temperature.

公开(公告)号：US4717479A

公开(公告)日：1988-01-05

申请号：US30745

申请日：1987-03-27

申请人： Hajime Itoh ,  Kazutami Mitani

发明人： Hajime Itoh ,  Kazutami Mitani

IPC分类号： B01D67/00 ,  C08J9/40 ,  B01D25/04

CPC分类号： B01D67/0088 ,  B01D67/0093 ,  C08J9/405

摘要： The present invention discloses a hydrophilized porous polyolefin membrane with a polymer of a monomer, which has an HLB value of 2-20, held on at least a part of the pore walls of a porous polyolefin membrane as well as its production process. This hydrophilized porous polyolefin membrane has long-lasting hydrophilicity and good mechanical strength.

公开(公告)号：US4695592A

公开(公告)日：1987-09-22

申请号：US70

申请日：1987-01-02

申请人： Hajime Itoh ,  Kazutami Mitani

发明人： Hajime Itoh ,  Kazutami Mitani

IPC分类号： B01D67/00 ,  B01D69/12 ,  C08J9/40

CPC分类号： B01D67/0088 ,  B01D69/125 ,  C08J9/40 ,  Y10S521/905

摘要： The present invention discloses a hydrophilized porous membrane with a crosslinked hydrophilic polymer, which is composed principally of diacetone acrylamide, held physically on at least a part of the pore walls of a starting porous polyolefin membrane, as well as its production process. This hydrophilized porous polyolefin membrane has long-lasting hydrophilicity and good mechanical strength. Its components are dissolved out only minimally in application.

摘要翻译： 本发明公开了一种具有交联亲水性聚合物的亲水化多孔膜，其主要由双丙酮丙烯酰胺构成，物理地保留在起始多孔聚烯烃膜的孔壁的至少一部分上，以及其制备方法。 该亲水化多孔聚烯烃膜具有持久的亲水性和良好的机械强度。 其组分在应用中只能最小程度地溶解。