-
21.发明授权
公开(公告)号：US5296431A
公开(公告)日：1994-03-22
申请号：US737741
申请日：1991-07-30
CPC分类号： C08F10/00
摘要： Ziegler-Natta-type catalyst systems containing, as active constituents,a) a titanium-containing solid component which also contains magnesium, halogen and a carboxylic acid ester as electron donor,b) an aluminum component,c) a further electron-donor component, and, as an additional component,d) an organometallic compound of the general formula A or B ##STR1## where M.sup.1 is an element f rom main group I, and M.sup.2 is an element from main group II of the Periodic Table, and R.sup.1 and R.sup.2 are identical or different C.sub.1 -C.sub.10 -alkyl, C.sub.6 -C.sub.12 -aryl, C.sub.6 -C.sub.12 -arylalkyl, or 5- to 7-membered cycloalkyl, which may itself carry C.sub.1 -C.sub.8 -alkyl groups,can be used to prepare polymers which have, in particular, a low proportion of very fine grains.
摘要翻译： 含有作为活性组分的齐格勒 - 纳塔型催化剂体系a）含镁的固体组分，其还含有镁，卤素和羧酸酯作为电子给体，b）铝组分，c）另外的电子给体组分 ，作为附加成分，d）通式A或B的有机金属化合物M1R1（A）M2R1R2（B），其中M1是主要组I的元素，M2是来自主组II的元素 周期表，R 1和R 2是相同或不同的C 1 -C 10 - 烷基，C 6 -C 12 - 芳基，C 6 -C 12 - 芳基烷基或5-至7-元环烷基，其本身可带有C 1 -C 8烷基， 用于制备具有特别低比例非常细晶粒的聚合物。
-
22.发明授权Preparation of homo- and copolymers of propene by means of a Ziegler-Natta catalyst system 失效通过齐格勒 - 纳塔催化剂体系制备丙烯的均聚物和共聚物
公开(公告)号：US5288824A
公开(公告)日：1994-02-22
申请号：US934848
申请日：1992-08-25
申请人： Juergen Kerth , Rainer Hemmerich , Peter Koelle , Patrik Mueller
发明人： Juergen Kerth , Rainer Hemmerich , Peter Koelle , Patrik Mueller
CPC分类号： C08F10/06
摘要： Polymers of propene are prepared using a Ziegler-Natta catalyst system comprising (1) titanium component which is based on a finely divided, shape-imparting silica gel and contains titan- ium, magnesium, chlorine and a benzenecarboxylic acid derivative, (2) an aluminum component and (3) a silane component. The process employs a titanium component (1) which is obtained by a method in which (1.1) first (I) a carrier is prepared from (Ia) a silica gel which has a relatively high moisture content, (Ib) an organomagnesium compound and (Ic) a gaseous chlorinating agent in a manner such that (1.1.1) first (Ia) is reacted with (Ib), (1.1.2) then (Ic) is passed into the mixture obtained from (1.1.1), (1.2) then a solid-phase intermediate is prepared from (I), (II) an alkanol, (III) titanium tetrachloride and (IV) a phthalic acid derivative in a manner such that (1.2.1) first (I) is reacted with (II), (1.2.2) then (III) is introduced into the mixture resulting from (1.2.1), with the proviso that (IV) is also introduced in (1.2.1) or (1.2.2), (1.3) then the solid-phase intermediate resulting from (1.2) is extracted with titanium tetrachloride or with a titanium tetrachloride/-hydrocarbon mixture and (1.4) finally the solid-phase product resulting from (1.3) is washed with a liquid hydrocarbon.
摘要翻译： 使用齐格勒 - 纳塔催化剂体系制备丙烯聚合物，该催化剂体系包括（1）基于精细分散的形状赋予硅胶并含有钛，镁，氯和苯甲酸衍生物的钛组分，（2） 铝成分和（3）硅烷成分。 该方法采用通过以下方法得到的钛组分（1）：其中（1.1）第一（I）载体由（Ia）由具有相对高的水分含量的硅胶制备，（Ib）有机镁化合物和 （Ic）气态氯化剂，使得（1.1.1）第一（Ia）与（Ib），（1.1.2）反应，然后（Ic）进入从（1.1.1）获得的混合物中， （1.2），然后以（I），（II）烷醇，（III）四氯化钛和（IV）邻苯二甲酸衍生物的方式制备固相中间体，使得（1.2.1）第一（I）为 与（II）反应，（1.2.2）然后将（III）引入由（1.2.1）得到的混合物中，条件是（IV）也引入（1.2.1）或（1.2.2） ，（1.3），然后用四氯化钛或四氯化钛/ - 烃混合物萃取由（1.2）得到的固相中间体，（1.4）最后将由（1.3）得到的固相产物用液体烃 。
-
23.发明授权Preparation of homopolymers and copolymers of propene using a Ziegler-Natta catalyst system 失效使用齐格勒 - 纳塔催化剂体系制备丙烯的均聚物和共聚物
公开(公告)号：US5162465A
公开(公告)日：1992-11-10
申请号：US646493
申请日：1991-01-28
申请人： Juergen Kerth , Ralf Zolk , Rainer Hemmerich
发明人： Juergen Kerth , Ralf Zolk , Rainer Hemmerich
CPC分类号： C08F10/06 , Y10S526/901
摘要： Polymers of propene are prepared using a Ziegler-Natta catalyst system consisting of (1) a titanium component which is based on a finely divided, shape-imparting silica gel and contains, in addition to titanium, magnesium, chlorine and a benzenecarboxylic acid derivative, (2) an aluminum component and (3) a silane component. In this process, a titanium component (1) is used which is obtained by a method in which (1.1) first (I) a carrier is prepared from (Ia) a silica gel, (Ib) an alkanol, (Ic) an organomagnesium compound and (Id) a gaseous chlorinating agent by a procedure in which (1.1.1) first (Ia) is reacted with (Ib), (1.1.2) then the mixture obtained in (1.1.1) is combined with (Ic), (1.1.3) then (Id) is passed into the mixture obtained in (1.1.2) and (I) is isolated, (1.2) thereafter a solid-phase intermediate is prepared from (I), (II) an alkanol, (III) titanium tetrachloride and (IV) a phthalic acid drivative by a procedure in which (1.2.1) first (I) is reacted with (II), (1.2.2) then (III) is introduced into the mixture resulting from (1.2.1), with the proviso that (IV) is also introduced during (1.2.1) and/or (1.2.2), (1.3) then the solid-phase product resulting from (1.2) is extracted with titanium tetrachloride and (1.4) finally the solid-phase product resulting from (1.3) is washed with a liquid hydrocarbon.
摘要翻译： 丙烯聚合物使用齐格勒 - 纳塔催化剂体系制备，该催化剂体系由以下组成：（1）基于精细分散的形状赋予硅胶的钛组分，除钛，镁，氯和苯甲酸衍生物外， （2）铝成分和（3）硅烷成分。 在该方法中，使用通过以下方法获得的钛组分（1）：其中（1.1）第一（I）载体由（Ia）硅胶制备，（Ib）烷醇，（Ic）有机镁 化合物和（Id）气态氯化剂，其中（1.1.1）第一（Ia）与（Ib），（1.1.2）反应，然后将（1.1.1）中获得的混合物与（Ic ），（1.1.3）然后（Id）进入（1.1.2）中获得的混合物中，（I）分离，（1.2）之后，从（I），（II）制备固相中间体 链烷醇，（III）四氯化钛和（IV）通过其中（1.2.1）第一（I）与（II），（1.2.2）然后（III）反应的方法将邻苯二甲酸驱动物引入混合物 （1.2.1）产生，条件是在（1.2.1）和/或（1.2.2），（1.3）中也引入了（IV），则从（1.2）得到的固相产物用 四氯化钛和（1.4）最后由（1.3）产生的固相产物用液体洗涤 加油
-
24.发明授权Preparation of homopolymers and copolymers of propene by means of a Ziegler-Natta catalyst system 失效通过齐格勒 - 纳塔催化剂体系制备丙烯的均聚物和共聚物
公开(公告)号：US5006620A
公开(公告)日：1991-04-09
申请号：US400350
申请日：1989-08-30
申请人： Ralf Zolk , Juergen Kerth , Rainer Hemmerich
发明人： Ralf Zolk , Juergen Kerth , Rainer Hemmerich
CPC分类号： C08F10/00 , C08F10/06 , Y10S526/909
摘要： Polymers of propene are prepared by means of a Ziegler-Natta catalyst system composed of (1) a titanium component based on a finely divided shape-dictating silica gel and containing titanium, magnesium, chlorine and a benzenecarboxylic acid derivative, (2) an aluminum component and (3) a silane component, the titanium component (1) being obtained by (1.1) first preparing (I) a carrier material from (Ia) a silica gel, (Ib) an organomagnesium compound (Ic) a gaseous chlorinating agent and (Id) a specific phthalic acid derivative by (1.1.1) first reacting (Ia) with (Ib), then (1.1.2) passing (Ic) into the product of (1.1.1) together with the phthalic acid derivative (Id) and isolating (I), (1.2) preparing a solid-phase intermediate from (I), (II) an alkanol and (III) titanium tetrachloride by (1.2.1) first reacting (I) with (II), then (1.2.2) introducing (III) into the product resulting from (1.2.1), then (1.3) extracting the solid-phase result from (1.2) with titanium tetrachloride or a titanium tetrachloride/ethylbenzene mixture, and finally (1.4) washing the solid-phase result from (1.3) with a liquid hydrocarbon.
摘要翻译： 丙烯聚合物通过齐格勒 - 纳塔催化剂体系制备，该催化剂体系由（1）基于精细分散形状的硅胶组成的钛组分，含有钛，镁，氯和苯甲酸衍生物，（2）铝 组分和（3）硅烷组分，钛组分（1）通过（1.1）首先制备（I）载体材料从（Ia）硅胶获得，（Ib）有机镁化合物（Ic），气态氯化剂 和（Id）通过（1.1.1）首先使（Ia）与（Ib）反应的（1.1.1）特定的邻苯二甲酸衍生物，然后（1.1.2）将（Ic）与（1.1.1）的产物一起与邻苯二甲酸衍生物 （I）和（II），（I）与（II）反应制备（I），（1.2）从（I），（II）烷基醇和（III）四氯化钛制备固相中间体（1.2.1） 然后（1.2.2）将（III）引入到由（1.2.1）得到的产物中，然后（1.3）从（1.2）中提取四氯化钛的固相或 四氯化钛/乙苯混合物，最后（1.4）用液态烃洗涤（1.3）的固相结果。
-
公开(公告)号：US4900798A
公开(公告)日：1990-02-13
申请号：US97068
申请日：1987-09-16
CPC分类号： C08F10/02 , Y10S526/901 , Y10S526/903 , Y10S526/904
摘要： Finely divided ethane polymers are prepared using a Ziegler catalyst system consisting of (1) a titanium-containing catalyst component which has been obtained by (1.1) precipitation in an organic liquid comprising (1.1.1) a solution of titanium tetrachloride in a hydrocarbon, (1.1.2) a solution of a certain organoaluminum compound in a hydrocarbon and (1.1.3) an alpha-monoalkene, and (2) an aluminum-containing catalyst component. In this process, the component (1) used is a component where (1.1) precipitation has been carried out at relatively low temperatures in an organic liquid which has a relatively high viscosity at the precipitation temperature and conists of (1) a liquid hydrocarbon an (b) small amounts of a polymer of an alpha-monoalkene dissolved therein, with the provisos that (i) specific amounts of the organic liquid, of the organoaluminum compound and of the alpha-monoalkene are used per g mol of the titanium tetrachloride used in total, and (ii) per molar unit of the titanium tetrachloride used in total, specific amounts per minute are precipitated and specific amounts per minute of the alpha-monoalkene are introduced, and (1.2) the substance precipitated according to (1.1) has been reacted with a lithiumalkyl.
摘要翻译： 使用齐格勒催化剂体系制备精细分散的乙烷聚合物，该齐格勒催化剂体系由（1）通过（1.1）在有机液体中沉淀得到的含钛催化剂组分，所述有机液体包含（1.1.1）四氢化钛在烃中的溶液， （1.1.2）某些有机铝化合物在烃中的溶液和（1.1.3）α-单链烯烃，和（2）含铝催化剂组分。 在该方法中，使用的组分（1）是在相对低的温度下在沉淀温度下具有较高粘度的有机液体中进行沉淀的组分，（1）液体烃 （b）少量其中溶解有α-单链烯烃的聚合物，条件是（i）有机铝化合物和α-单链烯烃的特定量的有机铝化合物与每摩尔所用的四氯化钛相比使用 和（ii）每摩尔单位使用的四氯化钛，每分钟的特定量被沉淀，并且每分钟的特定量的α-单链烯烃被引入，（1.2）根据（1.1）沉淀的物质具有 与烷基锂反应。
-
-
-
-
搜索结果
25 条记录 (耗时 0.019 秒)
