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公开(公告)号：US5352819A
公开(公告)日：1994-10-04
申请号：US63677
申请日：1993-05-20
IPC分类号： C07C253/30 , C07C293/30
CPC分类号： C07C253/30
摘要： Branched saturated dinitrile byproducts, e.g. 2-methylglutaronitrile, 2-ethylsuccinonitrile and mixtures thereof, are converted into useful ethylenic nitriles by dehydrocyanating same, in vapor phase, in the presence of an at least partially acidified cation exchange substrate, notably a molecular sieve, clay, acid oxide or lamellar phosphate.
摘要翻译： 支链饱和二腈副产物，例如 2-甲基戊二腈，2-乙基琥珀腈及其混合物通过在气相中，在至少部分酸化的阳离子交换基质，特别是分子筛，粘土，酸性氧化物或层状磷酸盐存在下，通过其脱氢氰化而转化为有用的烯属腈 。
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公开(公告)号：US08431750B2
公开(公告)日：2013-04-30
申请号：US12663344
申请日：2008-06-03
IPC分类号： C07C45/39
CPC分类号： C07C45/39 , B01J23/70 , B01J2531/16 , B01J2531/842 , B01J2531/845 , B01J2531/847 , C07C45/29 , C07C45/294 , C07C47/58
摘要： Hydroxyaromatic aldehydes are prepared by oxidation of a corresponding mandelic derivative carried out in a basic medium and in the presence of a catalytic system containing at least two metal elements.
摘要翻译： 羟基芳族醛通过氧化在碱性介质中进行的相应的扁桃酸衍生物和在含有至少两种金属元素的催化体系的存在下制备。
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23.发明授权Compounds with a guanidine structure and use thereof for as organopolysiloxane polycondensation catalysts 有权具有胍结构的化合物及其用作有机聚硅氧烷缩聚催化剂公开(公告)号：US08372935B2
公开(公告)日：2013-02-12
申请号：US12809024
申请日：2008-12-18
IPC分类号： C08G77/26
CPC分类号： C07F7/1804 , C07F7/0838
摘要： The invention relates to novel compounds with a guanidine structure, and more particularly nontoxic compounds with a silylated guanidine structure.
摘要翻译： 本发明涉及具有胍结构的新化合物，更具体地说是具有甲硅烷基化胍结构的无毒化合物。
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24.发明申请SILICONE COMPOSITION SUITABLE FOR CROSS-LINKING BY DEHYDROCONDENSATION IN THE PRESENCE OF A METAL CATALYST 有权用于在金属催化剂存在下通过去离子交联的硅酮组合物公开(公告)号：US20120172472A1
公开(公告)日：2012-07-05
申请号：US13379304
申请日：2010-06-15
申请人： Christian Maliverney
发明人： Christian Maliverney
CPC分类号： B01J31/2234 , B01J2531/842 , C08G77/12 , C08G77/16 , C08G2101/00 , C08K5/56 , C08L83/04 , C08L2205/02 , C09D183/04 , C08L83/00
摘要： A silicone composition is described that includes components having SiH/SiOH group and that can be polymerized/cross-linked by a dehydrocondensation reaction in the presence of a catalyst such as an iron-based complex or salt, requiring a low activation temperature.
摘要翻译： 描述了一种硅氧烷组合物，其包括具有SiH / SiOH基团的组分，并且可以在需要低活化温度的催化剂如铁基络合物或盐的存在下通过脱氢缩合反应进行聚合/交联。
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公开(公告)号：US20110306802A1
公开(公告)日：2011-12-15
申请号：US12663344
申请日：2008-06-03
IPC分类号： C07C45/39
CPC分类号： C07C45/39 , B01J23/70 , B01J2531/16 , B01J2531/842 , B01J2531/845 , B01J2531/847 , C07C45/29 , C07C45/294 , C07C47/58
摘要： Hydroxyaromatic aldehydes are prepared by oxidation of a corresponding mandelic derivative carried out in a basic medium and in the presence of a catalytic system containing at least two metal elements.
摘要翻译： 羟基芳族醛通过氧化在碱性介质中进行的相应的扁桃酸衍生物和在含有至少两种金属元素的催化体系的存在下制备。
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26.发明申请COMPOUNDS WITH A GUANIDINE STRUCTURE AND USE THEREOF FOR AS ORGANOPOLYSILOXANE POLYCONDENSATION CATALYSTS 有权具有胍基结构的化合物及其作为有机聚硅氧烷聚合催化剂的用途公开(公告)号：US20110046299A1
公开(公告)日：2011-02-24
申请号：US12809024
申请日：2008-12-18
CPC分类号： C07F7/1804 , C07F7/0838
摘要： The invention relates to novel compounds with a guanidine structure, and more particularly nontoxic compounds with a silylated guanidine structure.
摘要翻译： 本发明涉及具有胍结构的新化合物，更具体地说是具有甲硅烷基化胍结构的无毒化合物。
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公开(公告)号：US20110040034A1
公开(公告)日：2011-02-17
申请号：US12809538
申请日：2008-12-18
CPC分类号： C08K5/0091 , B01J31/2234 , B01J2531/16 , B01J2531/17 , B01J2531/35 , B01J2531/38 , B01J2531/54 , B01J2531/64 , B01J2531/72 , B01J2531/842 , B01J2540/225 , C08L83/04
摘要： The present invention relates to an organopolysiloxane composition that can be vulcanized at room temperature into an elastomer that is crosslinked by polycondensation and that does not contain alkyltin-based catalysts and also to novel organopolysiloxane polycondensation catalysts.
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28.发明申请ORGANOPOLYSILOXANE COMPOSITION ROOM TEMPERATURE VULCANIZABLE TO ELASTOMER AND NEW ORGANOPOLYSILOXANE POLYCONDENSATION CATALYSTS 有权可溶于弹性体和新型有机硅氧烷聚合催化剂的有机聚硅氧烷组合物室温公开(公告)号：US20110040032A1
公开(公告)日：2011-02-17
申请号：US12809325
申请日：2008-12-18
CPC分类号： C08K5/0091 , C08G77/02 , C08G77/16 , C08K5/5425 , C08K5/56 , C08K5/57 , C08L83/04
摘要： The present invention relates to an organopolysiloxane composition that can be vulcanized at room temperature into an elastomer that is crosslinked by polycondensation and that does not contain alkyltin-based catalysts and also to novel organopolysiloxane polycondensation catalysts.
摘要翻译： 本发明涉及可在室温下硫化成通过缩聚交联并且不含烷基锡基催化剂的弹性体以及新型有机聚硅氧烷缩聚催化剂的有机聚硅氧烷组合物。
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29.发明授权Method for preparing carbene in solution, novel stable form of carbene obtained in particular by means of said method, and uses thereof in catalysis 有权在溶液中制备卡宾的方法，特别是通过所述方法获得的新的稳定形式的卡宾及其在催化中的用途公开(公告)号：US09499643B2
公开(公告)日：2016-11-22
申请号：US13520834
申请日：2011-01-07
申请人： Christian Maliverney , Laurent Saint-Jalmes , Sophie Gojon , Tsuyoshi Kato , Antoine J. Baceiredo
发明人： Christian Maliverney , Laurent Saint-Jalmes , Sophie Gojon , Tsuyoshi Kato , Antoine J. Baceiredo
IPC分类号： C07D233/58 , C08F4/80 , C07D233/06 , C08F4/00
CPC分类号： C08F4/80 , C07D233/06 , C07D233/58 , C08F4/00
摘要： The invention relates to a method for preparing carbene by means of deprotonation of a precursor salt using a strong base. A purpose of the invention is to enhance the synthesis of carbenes, i.e. to simplify same, to make said synthesis more economical and to obtain a liquid or solid, stable and pure form constituting a catalytic system that is easy to store and use and that has a higher efficiency, higher yield and higher selectivity than carbene catalysts of the prior art. In order to do so, the method comprises deprotonation in a solvent including an alcohol. The invention also relates to an alcohol-containing solution and carbene, and to a solid that can be obtained from the solution, e.g. by means of sublimation.
摘要翻译： 本发明涉及通过使用强碱将前体盐去质子化制备卡宾的方法。 本发明的目的是增强卡宾的合成，即为了简化合成，使得所述合成更经济并且获得构成易于储存和使用的催化体系的液体或固体，稳定和纯的形式，并且具有 比现有技术的卡宾催化剂更高的效率，更高的产率和更高的选择性。 为了这样做，该方法包括在包括醇的溶剂中去质子化。 本发明还涉及含醇溶液和卡宾，以及可以从溶液获得的固体，例如， 通过升华。
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30.发明申请SILICONE COMPOSITION THAT CAN BE CROSS-LINKED BY MEANS OF DEHYDROGENATIVE CONDENSATION IN THE PRESENCE OF A CARBENE-TYPE CATALYST 有权通过碳氢化合物催化剂存在下的脱氢缩合方法可以交联的硅酮组合物公开(公告)号：US20140377569A1
公开(公告)日：2014-12-25
申请号：US14130746
申请日：2012-07-06
IPC分类号： C09D183/06 , C08F4/00 , C08J9/00
CPC分类号： C08K3/0033 , C08F4/00 , C08G73/0616 , C08G77/08 , C08G77/12 , C08G77/16 , C08J9/0023 , C08J9/02 , C08J2201/026 , C08J2383/04 , C08J2383/05 , C08J2383/06 , C08K3/013 , C08L83/04 , C09D183/04 , C09D183/06 , Y10T428/31663
摘要： The invention relates to a silicone composition comprising components bearing ≡SiH/≡SiOH groups, which can be polymerised/cross-linked by means of a dehydrogenative condensation reaction in the presence of a carbene-type catalyst in solution.
摘要翻译： 本发明涉及包含含有≡SiH/≡SiOH基团的组分的硅氧烷组合物，其可以在溶液中的卡宾型催化剂存在下通过脱氢缩合反应进行聚合/交联。
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