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    Processes for producing oxide with higher oxidation than alcohol
    5.
    发明授权
    Processes for producing oxide with higher oxidation than alcohol 失效
    生产氧化比醇高的氧化物的方法

    公开(公告)号：US07183421B2

    公开(公告)日：2007-02-27

    申请号：US10915600

    申请日：2004-08-11

    申请人： Hideo Tanaka ,  Yutaka Kameyama

    发明人： Hideo Tanaka ,  Yutaka Kameyama

    IPC分类号： C07D309/00 ,  C07D407/00 ,  C07C67/00 ,  C07C51/16 ,  C07C45/00

    CPC分类号： C25B3/02 ,  C07B41/00 ,  C07C45/29 ,  C07C45/294 ,  C07C45/30 ,  C07C67/40 ,  C07C69/716

    摘要： The present invention provides a process for producing an oxide from an alcohol compound, the process comprising the steps of causing silica gel to carry the alcohol compound thereon and an oxidative catalyst thereon, and oxidizing the alcohol compound in the presence of an oxidizing agent, giving an oxide higher in oxidizing degree than the alcohol compound, and also provides a process for producing an oxide from an alcohol compound, the process comprising the steps of causing silica gel to carry the alcohol compound, and subjecting the alcohol compound to an electrolytic oxidation, giving an oxide higher in oxidizing degree than the alcohol compound.

    摘要翻译： 本发明提供一种由醇化合物制备氧化物的方法，该方法包括以下步骤：使硅胶在其上载有醇化合物及其上的氧化催化剂，并在氧化剂存在下氧化醇化合物，得到 氧化度高于醇化合物的氧化物，还提供了由醇化合物制造氧化物的方法，该方法包括使硅胶携带醇化合物，并对醇化合物进行电解氧化， 产生氧化度高于醇化合物的氧化物。

    Process for the production of ketones
    8.
    发明申请
    Process for the production of ketones 失效
    生产酮的方法

    公开(公告)号：US20040138506A1

    公开(公告)日：2004-07-15

    申请号：US10476025

    申请日：2003-10-27

    发明人： Georg Snullss-Fink ,  Georgiy B Shul'Pin ,  Lidia S Shul'Pina

    IPC分类号： C07C045/39

    CPC分类号： C07C45/294 ,  C07C45/29

    摘要： Aliphatic or alicyclic monoketones or alicyclic diketones of formula (I): R1nullC(nullO)nullR2, wherein R1 is a linear or branched C1-10-alkyl group and R2 is a linear or branched C1-10-alkyl group or a phenyl group, or R1 and R2 together are null(CH2)mnullnullC(nullO)nullnnull(CH2)pnull, wherein m and p independently are integers from 1 to 4 and n is 0 or 1, thus forming an alicyclic ring together with the carbonyl group of (I), are produced by oxidizing an alcohol of formula (II): R1nullnullCHOHnullR2null, in which R1null and R2null either have the same meaning as R1 and R2 above or, if R1 and R2 together are null(CH2)mnullnullC(nullOnullnnull(CH2)pnull, are together null(CH2)mnull(CHOH)nnull(CH2)pnull wherein m, n and p are as defined above, with a peroxy compound in the presence of a carboxylic acid and a manganese(IV) complex of 1,4,7-trimethyl-1,4,7-triazacyclononane.

    摘要翻译： 式（I）的脂族或脂环族单酮或脂环族二酮：R 1 -C（= O）-R 2，其中R 1是直链或支链C 1-10烷基，R 2是 是直链或支链C 1-10烷基或苯基，或R 1和R 2一起是 - （CH 2）m - [C（= O）] n - （CH 2）p - ，其中 m和p独立地为1〜4的整数，n为0或1，因此与（I）的羰基一起形成脂环式，是通过将式（II）的醇氧化而制备的：R 1 - 其中R 1'和R 2'与R 1和R 2具有相同的含义，或者如果R 1和R 2一起 是 - （CH 2）m - [C（= O）n - （CH 2）p - ） - （CH 2）m - （CHOH）n - （CH 2）p - ，其中m，n和p如上定义， 与过氧化合物在羧酸和1,4,7-三甲基-1,4,7-三氮杂环壬烷的锰（IV）络合物的存在下反应。

    Oxidation reaction process catalyzed by phase-transfer catalyst controlling reaction
    9.
    发明申请
    Oxidation reaction process catalyzed by phase-transfer catalyst controlling reaction 有权
    通过相转移催化剂控制反应催化氧化反应过程

    公开(公告)号：US20040030054A1

    公开(公告)日：2004-02-12

    申请号：US10432874

    申请日：2003-05-28

    发明人： Zuwei Xi ,  Yu Sun ,  Kunlan Li ,  Ning Zhou

    IPC分类号： C08J003/00 ,  C07B033/00

    CPC分类号： B01J27/186 ,  B01J31/006 ,  B01J31/0208 ,  B01J31/0239 ,  B01J31/0244 ,  B01J31/1815 ,  B01J31/2243 ,  B01J2531/64 ,  B01J2531/66 ,  B01J2531/96 ,  B01J2531/985 ,  C07B33/00 ,  C07C29/48 ,  C07C45/294 ,  C07C51/31 ,  C07C315/02 ,  C07C2601/14 ,  C07D301/06 ,  C07D301/12 ,  C07D303/04 ,  C07D315/00 ,  Y02P20/584 ,  C07C35/08 ,  C07C49/78 ,  C07C47/228 ,  C07C49/10 ,  C07C49/403 ,  C07C47/575 ,  C07C49/04 ,  C07C59/347 ,  C07C317/14

    摘要： The present invention relates to an oxidation reaction catalyzed by a reaction controlled phase-transfer catalyst having the general formula of null(R1)(R2)(R3)(R4)NnullxHynullAnullAnull or QmMO3(L). The catalysts themselves are not soluble in the reaction medium, but can form an active species that is soluble in the reaction medium under the action of one of the reactants. The active species can in turn react selectively with another reactant. When one of the reactants is completely consumed, the catalyst will separate out from the reacting system and can be recovered by means of simple separation method. The recovered catalyst can be recycled with comparable efficiency as that of the original catalyst. The separation of said catalyst is similar to that of heterogeneous catalyst while said catalyst will completely exhibit the characteristics of homogeneous catalyst during the reaction. The catalytic oxidation reaction system is especially suitable for the large-scale industrial production of epoxy cyclohexane from cyclohexene or of epoxy propane from propylene.

    摘要翻译： 本发明涉及由具有通式[（R 1）（R 2）（R 3）（R 3）（R 4））N] x H y的反应控制相转移催化剂催化的氧化反应 [A] A]或QmMO 3（L）。 催化剂本身不溶于反应介质，但可以在一种反应物的作用下形成可溶于反应介质的活性物质。 活性物质又可以​​选择性地与另一种反应物反应。 当其中一种反应物被完全消耗时，催化剂将从反应体系中分离出来并且可以通过简单的分离方法回收。 回收的催化剂可以与原始催化剂的效率相当的效率再循环。 所述催化剂的分离类似于非均相催化剂，而所述催化剂在反应期间将完全表现出均相催化剂的特性。 催化氧化反应体系特别适用于从环己烯或丙烯环氧丙烷大规模工业生产环氧环己烷。

    Biphasic catalysis in water/carbon dioxide micellar systems
    10.
    发明授权
    Biphasic catalysis in water/carbon dioxide micellar systems 失效
    水/二氧化碳胶束体系中的双相催化

    公开(公告)号：US06479708B1

    公开(公告)日：2002-11-12

    申请号：US09442873

    申请日：1999-11-18

    申请人： Gunilla B. Jacobson ,  William Tumas ,  Keith P. Johnston

    发明人： Gunilla B. Jacobson ,  William Tumas ,  Keith P. Johnston

    IPC分类号： C07C4500

    CPC分类号： C07C45/294 ,  C07B61/00 ,  C07C5/03 ,  C07C45/50 ,  C07C47/02

    摘要： A process is provided for catalyzing an organic reaction to form a reaction product by placing reactants and a catalyst for the organic reaction, the catalyst of a metal complex and at least one ligand soluble within one of the phases of said aqueous biphasic system, within an aqueous biphasic system including a water phase, a dense phase fluid, and a surfactant adapted for forming an emulsion or microemulsion within the aqueous biphasic system, the reactants soluble within one of the phases of the aqueous biphasic system and convertible in the presence of the catalyst to a product having low solubility in the phase in which the catalyst is soluble; and, maintaining the aqueous biphasic system under pressures, at temperatures, and for a period of time sufficient for the organic reaction to occur and form the reaction product and to maintain sufficient density on the dense phase fluid, the reaction product characterized as having low solubility in the phase in which the catalyst is soluble.

    摘要翻译： 提供了一种方法，用于催化有机反应以形成反应产物，将反应物和用于有机反应的催化剂，金属络合物的催化剂和至少一种可溶于所述水相双相体系的相之一的配体在一种 水相双相系统，包括水相，致密相流体和适于在水相双相体系内形成乳液或微乳液的表面活性剂，所述反应物可溶于水相双相体系的一相中并且在催化剂存在下可转化 涉及在催化剂可溶的相中具有低溶解度的产物; 并在保持水相双相系统的压力下，在足以使有机反应发生并形成反应产物并在密相流体上保持足够的密度的温度下持续一段时间，反应产物的特征在于溶解度低 在催化剂可溶的阶段。