Abstract:
Trace amount levels of non-volatile mercury in crude oil are reduced by contacting the crude oil with a water stream containing at least a monatomic water-soluble sulfur species such as sulfides and hydrosulfides. The non-volatile mercury is extracted into the water phase forming a mercury rich wastewater, yielding a treated crude oil having at less than 50% of the original non-volatile mercury level. The wastewater can disposed or recycled by injection into a reservoir. In one embodiment, the water stream consists essentially of produced water.
Abstract:
Trace element levels of heavy metals such as mercury in crude oil are reduced by contacting the crude oil with an iodine source, generating a water soluble heavy metal complex for subsequent removal from the crude oil. In one embodiment, the iodine source is generated in-situ in an oxidation-reduction reaction, by adding the crude oil to an iodine species having a charge and a reductant or an oxidant depending on the charge of the iodine species. In one embodiment with an iodine species having a positive charge and a reducing reagent, a complexing agent is also added to the crude oil to extract the heavy metal complex into the water phase to form water soluble heavy metal complexes which can be separated from the crude oil, for a treated crude oil having reduced levels of heavy metals.
Abstract:
A method and device for detecting mercury or other material deposits on an inner surface of an enclosed passage are provided. The device includes a detection unit that is adapted to be transported through the passage, and the detection unit includes a radiation source and an x-ray fluorescence detector. The radiation source is configured to emit a radiation emission toward the inner surface of the passage to excite a portion of the inner surface, and the x-ray fluorescence detector is configured to detect a resulting x-ray emission from the portion of the inner surface to identify a material deposit on the inner surface. The detection unit can identify material deposits at successive positions along a length of the passage and thereby generate a plurality of data points, each data point providing an indication of a material deposit existence for a corresponding position along the length of the passage.