Use of hydroxyaromatics as safeners
    22.
    发明申请
    Use of hydroxyaromatics as safeners 失效
    使用羟基芳烃作为安全剂

    公开(公告)号:US20050037922A1

    公开(公告)日:2005-02-17

    申请号:US10911706

    申请日:2004-08-04

    摘要: Compounds of the formula (I) or salts thereof in which R1 is carboxyl or a derivative of a carboxyl group, preferably a radical of the formula —CN, —C(═X)—Y—R or —C(═X)-Het, in which X is O, S or NRa or N—NRaRb, Y is O, S, NRc or NRc—NRdRe, R is H, a (subst.) hydrocarbon radical (HR) or acyl, and Het is an aliphatic nitrogen heterocycle, where each of the radicals Ra, Rb, Rc, Rd and Re is as defined for R or a radical of the formula —OR*, where R* is as defined for R, R2 is H or (subst.) HR or a heterocyclic radical, or, if Z=O or S, also an acyl radical, (R3)n are n radicals R3, as defined in claim 1, Z is a group of the formula O or S(O)x, where x=0, 1 or 2, and n is an integer 0, 1, 2, 3 or 4, as safeners for crop plants or useful plants against phytotoxic actions of agrochemicals, preferably as safeners against the action of pesticides, such as herbicides, in these plants.

    摘要翻译: 式(I)的化合物或其盐,其中R 1是羧基或羧基的衍生物,优选式-CN,-C(= X)-YR或-C(= X)的基团, -Het,其中X是O,S或NR,或N-NR a R b,Y是O,S,NR c或NR c -NR d R e >,R为H,(基)烃基(HR)或酰基,Het为脂族氮杂环,其中基团R a,R b,R c,R d, 并且R e如R定义或式-OR *的基团,其中R *如R所定义,R 2是H或(取代的)HR或杂环基,或如果 Z = O或S也是酰基,(R 3)n是如权利要求1中定义的n个基团R 3,Z是式O或S(O)x的基团,其中x = 0,1或2,以及n为整数0,1,2,3或4,作为农作物或有用植物的抗病毒剂,以防止农药的植物毒性作用,优选作为安全剂抵抗杀虫剂如除草剂的作用,在这些 植物。

    Herbicidal compositions for tolerant or resistant cereal crops
    23.
    发明授权
    Herbicidal compositions for tolerant or resistant cereal crops 有权
    用于耐受或抗性谷物作物的除草组合物

    公开(公告)号:US06723681B2

    公开(公告)日:2004-04-20

    申请号:US09371770

    申请日:1999-08-10

    IPC分类号: A01N2532

    CPC分类号: A01N57/20 A01N2300/00

    摘要: Herbicide combinations (A)+(B), if appropriate in the presence of safeners, with an effective content of (A) broad-spectrum herbicides from the group (A1) glufosinate (salts) and related compounds (A2) glyphosate (salts) and related compounds such as sulfosate, (A3) imidazolinones such as imazethapyr, imazapyr, imazaquin, imazamox or their salts and (A4) herbicidal azoles from the group of the protoporphyrinogen oxidase inhibitors (PPO inhibitors) and (B) one or more herbicides from the group of the compounds consisting of (B0) one or more structurally different herbicides from the abovementioned group (A) and/or (B1) foliar- and/or soil-acting herbicides which are particularly effective selectively in cereals against monocotyledonous harmful plants and/or (B2) predominantly foliar-acting herbicides which are effective selectively in cereals against monocotyledonous and dicotyledonous harmful plants and/or (B3) foliar- and soil-acting herbicides which are effective selectively in cereals against dicots and monocots and/or (B4) foliar-acting herbicides which are effective selectively in cereals against monocotyledonous and dicotyledonous harmful plants, are suitable for controlling harmful plants in cereal which consists of tolerant or resistant mutants or transgenic cereal plants and the cereal crops are tolerant to the herbicides (A) and (B), if appropriate in the presence of safeners, which are contained in the combination.

    摘要翻译: (A)+(B),如果适合,在安全剂存在下,有效含量(A)来自(A1)草铵膦(盐)和相关化合物(A2)的广谱除草剂草甘膦(盐) 和(A)来自原卟啉原氧化酶抑制剂(PPO抑制剂)和(B)的一种或多种除草剂的相关化合物例如磺酸盐,(A3)咪唑啉酮如咪草烟,咪草烟,咪唑啉,咪唑氧胺或其盐和(A4)除草唑) 由(B0)组成的一组化合物来自上述组(A)的一种或多种结构上不同的除草剂和/或(B1)叶面和/或土壤作用除草剂,其对于单子叶有害植物在谷物中特别有效, /或(B2)主要是叶面作用的除草剂,其对谷类中单子叶和双子叶有害植物有选择性有效和/或(B3)叶面和土壤作用除草剂,其有效选择性地在谷物中有效 在单子叶和双子叶有害植物的谷物中有效选择性的双子叶植物和单子叶植物和/或(B4)叶面作用除草剂适用于控制由耐受性或抗性突变体或转基因谷物植物组成的谷物中的有害植物,并且谷类作物是 对于除草剂(A)和(B),如果合适的话,在组合物中包含的安全剂存在下可以耐受。

    Processes for preparing aminophenylsulfonylureas, and intermediates therefor
    25.
    发明授权
    Processes for preparing aminophenylsulfonylureas, and intermediates therefor 有权
    制备氨基苯磺酰脲的方法及其中间体

    公开(公告)号:US06500952B1

    公开(公告)日:2002-12-31

    申请号:US09664201

    申请日:2000-09-18

    IPC分类号: C07D23942

    摘要: The invention relates to the preparation of compounds (I) in which A=H or acyl and R1, R21, R3, R, n, X, Y and Z are as defined in claim 1 by halogenation and rearrangement of compounds (II) (optionally salt) to give compounds (III) a) ammonolysis of (III) to (IV), reduction of the nitro group and reaction with carbamate (salts) (VI) of the formula Ar—OCO—N(M)—Het, where Ar=phenyl, M=H or cation and Het=heterocycle from formula (I), to give compounds (I) (A=H), or b) ammonolysis of (III) to (IV), reaction with carbamate (salt) (VI) and reduction of resulting compounds (VII) at the NO2 group to give compounds (I) (A=H), or c) reaction of (III) with cyanates and amines (VIII) of the formula HNR3—Het and reduction of the resulting compound (VII) at the NO2 group to give compounds (I) (A=H) and optional acylation if A is to be other than H. Compounds of the formulae (I) (A=H), (III), (IV), (V), (VI) (M=cation) and (VII) are novel.

    摘要翻译: 本发明涉及化合物(Ⅰ)的制备,其中A = H或酰基,R 1,R 21,R 3,R 4,n,X,Y和Z如权利要求1中所定义,通过卤化和重排化合物 任选的盐),得到化合物(III)a)(III)至(IV)的氨解,硝基的还原和与式Ar-OCO-N(M)-Het的氨基甲酸酯(盐)(VI)的反应, 其中Ar =苯基,M = H或阳离子和Het =来自式(I)的杂环,得到(III)至(IV)化合物(I)(A = H),orb)氨解,与氨基甲酸酯 (VI)和还原所得化合物(VII)在NO 2基团上得到化合物(I)(A = H),orc)(III)与式HNR3-Het的氰酸酯和胺(VIII)的反应,还原 所得到的化合物(Ⅶ)在NO2基团上得到化合物(I)(A = H),任选的酰化如果A不为H.式(I)(A = H),(III) (IV),(V),(VI)(M =阳离子)和(VII)是新颖的。

    (Het) arylsulfonylureas having an amino function, their presentation and their use as herbicides and plant growth regulators
    26.
    发明授权
    (Het) arylsulfonylureas having an amino function, their presentation and their use as herbicides and plant growth regulators 失效
    (Het)芳基磺酰脲具有氨基功能,它们的表现及其作为除草剂和植物生长调节剂的用途

    公开(公告)号:US06410482B1

    公开(公告)日:2002-06-25

    申请号:US08855251

    申请日:1997-05-13

    IPC分类号: C07D40112

    摘要: (Het)Arylsulfonylureas having an imino function, their preparation, and their use as herbicides and plant growth regulators Compounds of the formula (I) and salts thereof in which A is a (hetero)aromatic or heterocyclic bridge linked to the group SO2 by a direct bond, or via O, S, NH, CH2 or via alkylated NH or alkylated methylene, B is a group having an imino-containing fragment N═C—N, N═C—S, N═C—O or N═C—C which is linked to A by one of the nitrogen atoms of the fragment, R═H or an aliphatic radical, W═O or S and X, Y and Z are as defined in claim 1 are suitable as herbicides and plant growth regulators. The preparation is carried out for example similarly to known processes via novel intermediates of the formula (XII) (cf. claims 6 and 10),

    摘要翻译: (Het)具有亚氨基功能的芳基磺酰脲,它们的制备及其作为除草剂和植物生长调节剂的用途式(I)化合物及其盐,其中A是通过直接连接到基团SO 2上的(杂)芳族或杂环桥 或通过O,S,NH,CH 2或通过烷基化NH或烷基化亚甲基,B是具有亚氨基的片段N = CN,N = CS,N = CO或N = CC的基团,其通过 所述片段的氮原子之一R = H或脂族基,W = O或S和X,Y和Z如权利要求1中所定义,适合作为除草剂和植物生长调节剂。 通过式(XII)的新型中间体(参见权利要求6和10)类似于已知方法进行制备,

    Substituted quinoline compounds and their use as safeners
    30.
    发明授权
    Substituted quinoline compounds and their use as safeners 失效
    取代的喹啉化合物及其作为安全剂的用途

    公开(公告)号:US5756422A

    公开(公告)日:1998-05-26

    申请号:US535028

    申请日:1995-10-18

    摘要: Substituted quinoline compounds, processes for their preparation, composition containing them, and their use as safeners Compounds of the formula I and salts thereof ##STR1## in which R.sup.1 �lacuna! CN, C(.dbd.Z)--Q(A.sub.i X.sub.i).sub.q --R, --C(.dbd.Z)--QR*, 1,2,3,4-tetrazol-5-yl, 1,3,4-triazol-2-yl, 1,3-oxazol-2-yl, and the remaining radicals are as defined in claim 1, are suitable for use as safeners for protecting crop plants such as, for example, cereals, rice and maize, against herbicide damage. Some of the compounds are known and some are novel and they can be prepared from quinolin-8-oxy derivatives by the processes of claim 7.

    摘要翻译: PCT No.PCT / EP94 / 01396 Sec。 371 1995年10月18日第 102(e)日期1995年10月18日PCT 1994年5月2日PCT PCT。 第WO94 / 26716号公报 日期:1994年11月24日取代喹啉化合物,其制备方法,含有它们的组合物及其作为安全剂的用途式I化合物及其盐其中R1 [lacuna] CN,C(= Z) -Q(AiXi)qR,-C(= Z)-QR *,1,2,3,4-四唑-5-基,1,3,4-三唑-2-基,1,3-恶唑-2 并且剩余的基团如权利要求1中所定义,适合用作安全剂,用于保护作物植物,例如谷物,水稻和玉米,以防止除草剂损害。 一些化合物是已知的,一些是新的,它们可以通过权利要求7的方法由喹啉-8-氧基衍生物制备。