摘要:
A processing method is disclosed, comprising development-processing a photographic material comprising a support having thereon a silver halide emulsion layer or a constituent layer adjacent to the emulsion layer which contains (i) a silver halide composition comprising at least one of silver bromochloride, silver chloroiodide, or silver bromochloroiodide each having a silver chloride content of 90 mole % or more, or silver chloride, and (ii) a compound represented by the following Formula (I) ##STR1## wherein R.sub.1 represents a hydrogen atom, an ammonium group or an alkali metal atom; and R.sub.2 represents a hydrogen atom, an alkyl group or an aryl group, with a developing solution containing (1) a dihydroxybenzene compound, and (2) an ascorbic acid or a derivative thereof in an amount of at least 5 mole % based on the amount of the dihydroxybenzene compound.
摘要:
Disclosed is a method of developing a transmission black-and-white silver halide photographic material with an automatic processor, in which a developer having a bromide ion concentration of 0.01 mol/liter or less and having a pH value of 9.8 or less is used with replenishment of the developer being in an amount of about 200 ml or less per m.sup.2 of the material being processed. Though the amount of the replenisher to the developer used is small in the method, the photographic properties of the processed material are stable and the processed material is fogged little.
摘要:
A novel process for the formation of a high contrast negative image is provided which comprises processing a silver halide photographic material with a developing solution, wherein said developing solution contains a dihydroxybenzene developing agent, a 1-phenyl-3-pyrazolidone auxiliary developing agent and/or p-aminophenol auxiliary developing agent, 0.3 mol/liter or more of sulfite, and a compound represented by formula (I) ##STR1## wherein Y and Z, which may be the same or different, each represents N or CR.sup.2 wherein R.sup.2 represents a substituted or unsubstituted alkyl or aryl group; R.sup.1 represents an alkyl, aryl or heterocyclic group which is substituted by at least one group selected from the group consisting of --SO.sub.3 M, --COOM, --OH, --NHSO.sub.2 R.sup.3, --SO.sub.2 NR.sup.3 R.sup.4 and --NR.sup.5 CONR.sup.3 R.sup.4 or a group formed by alkyl groups, aryl groups or heterocyclic groups via linkage groups; R.sup.3, R.sup.4 and R.sup.5, which may be the same or different, each represents a hydrogen atom or a lower alkyl group containing from 1 to 4 carbon atoms; and M represents a hydrogen atom, an alkali metal atom, quaternary ammonium, or quaternary phosphonium.
摘要翻译:提供了一种用于形成高对比度负像的新方法,其包括用显影液处理卤化银照相材料,其中所述显影液含有二羟基苯显影剂,1-苯基-3-吡唑烷酮辅助显影剂和/ 或对氨基苯酚辅助显影剂,0.3摩尔/升以上的亚硫酸盐和式(I)表示的化合物其中Y和Z可以相同或不同,各自表示N或CR 2 其中R2表示取代或未取代的烷基或芳基; R 1表示被选自-SO 3 M,-COOM,-OH,-NHSO 2 R 3,-SO 2 NR 3 R 4和-NR 5 CONR 3 R 4中的至少一个基团或由烷基形成的基团,芳基取代的烷基,芳基或杂环基 或杂环基团; R 3,R 4和R 5可以相同或不同,表示氢原子或含有1至4个碳原子的低级烷基; M表示氢原子,碱金属原子,季铵或季鏻。
摘要:
Silver halide photographic light-sensitive materials containing a hydrazine derivative is developed in high contrast by means of an automatic processor, wherein a replenisher less active than a starting developer used at the beginning of development is supplied in a predetermined amount per unit time and, in the case where further replenishment is done in excess of said predetermined amount in said unit time, a replenisher having activity substantially equivalent to that of said starting developer used at the beginning of development is then supplied. Stable treatment results are attained for a long time.
摘要:
A silver halide photographic material containing a hydrazine derivative of the general formula (I):R.sub.1 --NHNHCHO (I)wherein R.sub.1 is a substituted or unsubstituted aryl group, is developed with high contrast by the use of an aqueous alkaline developer having a pH value of 10.5 to 12.3 and comprising the following components (1) through (5):(1) a dihydroxybenzene type developing agent;(2) a p-aminophenol type developing agent;(3) at least 0.3 mol/l of a sulfite preservative;(4) 0.05 to 0.30 mol/l of an alkanolamine of the general formula (II):(C.sub.2 H.sub.5).sub.2 N--R.sub.2 (II) wherein R.sub.2 is a hydroxyalkyl group having 2 to 10 carbon atoms; and(5) 10.sup.-4 to 10.sup.-2 mol/l of a mercapto compound of the general formula (III); ##STR1## where M.sub.1 and M.sub.2 are the same or different and each is a hydrogen atom, an alkali metal atom or an ammonium group;whereby a negative image of high contrast may be formed on said photographic material.
摘要:
A silver halide photographic light-sensitive material and a developing process used in connection with that material are disclosed. The material is comprised of a support having thereon a silver halide emulsion layer containing a silver halide emulsion in which at least 80 mole % of the whole silver halide is composed of silver chloride, the mean grain size thereof is less than 0.4 .mu.m, and which contains more than 1.times.10.sup.-6 mole of a water-soluble rhodium salt per mole of silver at an optional period before finishing the first ripening in the production step for the silver halide emulsion. The material also contains 1.times.10.sup.-5 to 1.times.10.sup.-2 mole of polyalkylene oxide having a molecular weight of at least 600 or a derivative thereof per mole of silver. The process involves imagewise exposing the material and processing it in a developer containing 0.05 to 0.5 mole/liter of a dihydroxybenzene series developing agent, 0 to 0.05 g/liter of an auxiliary developing agent, at least 0.25 mole/liter of a free sulfite ion, at least 20 mg/liter of 5- or 6-nitroindazole, and an alkali of an amount sufficient for keeping the pH of the developer higher than 10.5. The material and processing are capable of providing good letter image quality in a short developing time.
摘要:
High-contrast photographic images are obtained by developing with a developer containing at least one dihydroxybenzene and sulfite ion and then treating with a solution of an oxidizing agent.
摘要:
The invention provides a photothermographic material including: a support and an image-forming layer including a non-photosensitive silver salt, a photosensitive silver halide, a binder, and a reduction agent disposed on the support, wherein a silver iodide content in the photosensitive silver halide is in a range from 40 mol % to 100 mol %; and an average sphere-equivalent diameter of the photosensitive silver halide is in a range from 0.3 μm to 5.0 μm. The photothermographic material may further include a silver iodide complex forming agent as a compound which substantially reduces visible light absorption caused by the photosensitive silver halide after thermal development. At least 50%, in terms of a projected area, of the photosensitive silver halide may be occupied by tabular silver halide grains having an aspect ratio of from 2 to 50 and being deposited with a silver salt in an epitaxial growth manner.
摘要:
A photothermographic material including an image forming layer containing at least a photosensitive silver halide, a non-photosensitive organic silver salt, a reducing agent and a binder on the same surface of a support, wherein the photothermographic material contains a compound having an adsorption group to silver halide and a reducing group, or a precursor of the compound, and satisfies one of the following conditions: 1) the photothermographic material contains a development accelerator; 2) the non-photosensitive organic silver contains silver behenate in an amount of not less than 80% by mole, and the binder has a glass transition temperature (Tg) of 45° C. or less; or 3) the photothermographic material contains at least one compound represented by the following formula (H); Q-(Y)n—C(Z1)(Z2)X wherein, in formula (H), Q represents an alkyl group, an aryl group or a heterocyclic group; Y represents a divalent linking group; n represents 0 or 1; Z1 and Z2 each independently represent a halogen atom; and X represents a hydrogen atom or an electron attracting group.
摘要:
A silver halide emulsion comprises at least a dispersion medium, water and a silver halide grain, wherein grains occupying from 40 to 100% of the total projected area of said gains have an AgI content of 85 to 100 mol %, a single kind of outer shape except for size and the equivalent-circle projected diameter of from 0.002 to 20 μm.