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21.发明授权Monoazo dyes of the thiazole series having a heterocyclic substituent in the 4-position 失效在4位具有杂环取代基的噻唑系单偶氮染料
公开(公告)号：US4340537A
公开(公告)日：1982-07-20
申请号：US124740
申请日：1980-02-26
IPC分类号： C09B29/36 , C07C107/04
CPC分类号： C09B29/3691
摘要： Dyes of the thiazole series, having the general formula I ##STR1## where D is the radical of an aromatic diazo component,R is a heterocyclic radical andR.sup.1 and R.sup.2 are hydrogen or unsubstituted or substituted hydrocarbon radicals, which may also together form a ring, which may or may not be heterocyclic.The dyes according to the invention are particularly suitable for dyeing synthetic polyesters.
摘要翻译： 噻唑系的染料具有通式I I，其中D是芳族重氮组分的基团，R是杂环基团，R 1和R 2是氢或未取代或取代的烃基，其也可以一起形成 环，其可以是也可以不是杂环的。 根据本发明的染料特别适用于染色合成聚酯。
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22.发明授权Acid azo dyes from a 3-amino-benzisothiazole-[2,1]-5-sulfonic acid diazo component 失效来自3-氨基 - 苯并异噻唑 - [2,1] -5-磺酸重氮组分的酸偶氮染料
公开(公告)号：US4327019A
公开(公告)日：1982-04-27
申请号：US973800
申请日：1978-12-28
IPC分类号： C09B29/045 , C09B29/00 , C09B29/06 , C09B29/095 , C09B29/52 , D06P1/06 , C07C107/04 , C09B29/039
CPC分类号： C09B29/06 , C09B29/0081 , C09B29/065 , C09B29/3665 , D06P1/06
摘要： Acid monoazo dyes of the formula ##STR1## in which X is hydrogen, chloro, bromo, nitro, C.sub.1 to C.sub.4 alkyl, methoxy, ethoxy or C.sub.2 to C.sub.4 alkanoylamino and K is a radical of a coupling compound as defined below. The dyes are suitable for dyeing natural or synthetic polyamides giving colorations with very good fastness properties.
摘要翻译： 其中X是氢，氯，溴，硝基，C 1至C 4烷基，甲氧基，乙氧基或C 2至C 4烷酰基氨基并且K是如下所定义的偶合化合物的基团的式IMAMA的酸性单偶氮染料。 染料适用于染色具有非常好的牢度特性的天然或合成聚酰胺染色。
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公开(公告)号：US4547566A
公开(公告)日：1985-10-15
申请号：US478101
申请日：1983-03-23
申请人： Udo Bergmann , Guenter Hansen , Georg Zeidler
发明人： Udo Bergmann , Guenter Hansen , Georg Zeidler
摘要： Compounds which in the form of the free acid are of the general formula I ##STR1## where A is a radical of the formula ##STR2## the radicals Y independently of one another are each hydroxyl or amino, X is hydrogen, hydroxysulfonyl or a radical of the formulaD--N.dbd.N--,R is a radical of 1-aminonaphthalene-4-, -5-, -6-, -7- or -8-monosulfonic acid or of 1-aminonaphthalene-3,6-, -3,7-, -3,8-, -4,7-, or -4,8-disulfonic acid, or a Cu, Fe, Ni, Co, Mn or Cr complex thereof, and D is phenyl which is unsubstituted or substituted by methyl, methoxy, ethoxy, nitro, chlorine, bromine or sulfo, or is sulfo-substituted naphthyl. These compounds are preferably used for dyeing leather.
摘要翻译： 游离酸形式的化合物具有通式I，其中A是下式的基团，其中Y独立地为羟基或氨基，X为氢， 羟基磺酰基或式DN = N-的基团，R是1-氨基萘-4-，5-，6-，7-或8-单磺酸或1-氨基萘-3,6 - ，-3,7-，-3,8-，-4,7-或-4,8-二磺酸，或其Cu，Fe，Ni，Co，Mn或Cr络合物，D为苯基， 被甲基，甲氧基，乙氧基，硝基，氯，溴或磺基取代或被磺基取代的萘基取代。 这些化合物优选用于染色皮革。
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公开(公告)号：US4638055A
公开(公告)日：1987-01-20
申请号：US721712
申请日：1985-05-10
申请人： Udo Bergmann , Guenter Hansen , Georg Zeidler
发明人： Udo Bergmann , Guenter Hansen , Georg Zeidler
摘要： Compounds which in the form of the free acid are of the general formula I ##STR1## where A is a radical of the formula ##STR2## the radicals Y independently of one another are each hydroxyl or amino, X is hydrogen, hydroxysulfonyl or a radical of the formulaD--N.dbd.N--,R is a radical of 1-aminonaphthalene-4-, -5-, -6-, -7-or -8-monosulfonic acid or of 1-aminonaphthalene-3-6,-, -3,7-, -3,8-, -4,7- or -4,8-disulfonic acid, or a Cu, Fe, Ni, Co, Mn or Cr complex thereof, and D is phenyl which is unsubstituted or substituted by methyl, methoxy,ethoxy, nitro, chlorine, bromine or sulfo, or is sulfo-substituted naphthyl. These compounds are preferably used for dyeing leather.
摘要翻译： 游离酸形式的化合物具有通式I，其中A是下式的基团，其中Y独立地为羟基或氨基，X为氢， 羟基磺酰基或式DN = N-的基团，R是1-氨基萘-4-，-5-，6-，7-或8-单磺酸或1-氨基萘-3-6的基团 ， - ，-3,7-，-3,8-，-4,7-或-4,8-二磺酸，或其Cu，Fe，Ni，Co，Mn或Cr络合物，D为苯基， 被甲基，甲氧基，乙氧基，硝基，氯，溴或磺基取代或被磺基取代的萘基取代。 这些化合物优选用于染色皮革。
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25.发明授权Azo dyes containing 2-amino-3-cyano-5-formylthiophene derivatives as diazo components and substituted aniline compounds as coupling components 失效含有2-氨基-3-氰基-5-甲酰基噻吩衍生物作为重氮组分的偶氮染料和取代的苯胺化合物作为偶联组分
公开(公告)号：US4751288A
公开(公告)日：1988-06-14
申请号：US843397
申请日：1986-03-24
申请人： Udo Bergmann , Erwin Hahn , Guenter Hansen , Helmut Reichelt
发明人： Udo Bergmann , Erwin Hahn , Guenter Hansen , Helmut Reichelt
CPC分类号： C09B29/0809 , C09B29/0059 , C09B29/0808 , Y10S534/02
摘要： The compounds of the formula I ##STR1## where R is unsubstituted or substituted phenyl or naphthyl, R.sup.1 and R.sup.2 are each unsubstituted or substituted alkyl, alkenyl or cycloalkyl, and one of the radicals may furthermore be hydrogen, R.sup.3 is hydrogen, methyl, methoxy, ethoxy or chlorine, and R.sup.4 is acylamino, are particularly useful for dyeing polyesters.
摘要翻译： 其中R是未取代或取代的苯基或萘基，R 1和R 2各自为未取代或取代的烷基，链烯基或环烷基，并且其中一个基团可以是氢，R 3是氢， 甲基，甲氧基，乙氧基或氯，R4为酰氨基，特别适用于染色聚酯。
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公开(公告)号：US4405330A
公开(公告)日：1983-09-20
申请号：US433393
申请日：1982-10-08
CPC分类号： C09B67/0051 , C09B29/081 , C09B29/0813 , Y10S534/01 , Y10S8/922
摘要： Navy mixtures which contain dyes of the formula I ##STR1## where X is chlorine or bromine,Y is hydrogen, methoxy or ethoxy andR is N(C.sub.2 H.sub.5).sub.2, N(CH.sub.2 CH.dbd.CH.sub.2).sub.2 or N(C.sub.2 H.sub.4 OCOCH.sub.3).sub.2,the mixtures being composed of 10-70% of dyes with Y.dbd.H and R=N(C.sub.2 H.sub.5).sub.2, 5-40% of dyes with Y=OCH.sub.3 or OC.sub.2 H.sub.5 and R.dbd.N(CH.sub.2 --CH.dbd.CH.sub.2).sub.2 and 5-80% of dyes with Y=OCH.sub.3 or OC.sub.2 H.sub.5 and R=N(C.sub.2 H.sub.4 OCOCH.sub.3).sub.2.The novel mixtures have excellent tinctorial properties and give very fast dyeings on synthetic polyesters.
摘要翻译： 含有式I的染料的海军混合物，其中X是氯或溴，Y是氢，甲氧基或乙氧基，R是N（C2H5）2，N（CH2CH = CH2）2或N（C2H4OCOCH3）2， 该混合物由10-70％的具有Y = H和R = N（C 2 H 5）2的染料组成，5-40％的具有Y = OCH 3或OC 2 H 5和R = N（CH 2 -CH 2 CH 2）2和5 -80％的具有Y = OCH 3或OC 2 H 5和R = N（C 2 H 4 OCOCH 3）的染料。 新型混合物具有优异的着色性能，并在合成聚酯上产生非常快的染色。
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27.发明授权Metal complexes of dis- or trisazo compounds containing a middle component twice substituted by hydroxy and/or amino 失效含有羟基和/或氨基两次取代的中间组分的二 - 或三偶氮化合物的金属络合物
公开(公告)号：US4563520A
公开(公告)日：1986-01-07
申请号：US435661
申请日：1982-10-21
申请人： Udo Bergmann , Guenter Hansen , Dietrich Lach , Georg Zeidler
发明人： Udo Bergmann , Guenter Hansen , Dietrich Lach , Georg Zeidler
IPC分类号： C09B33/00 , C09B33/02 , C09B33/22 , C09B33/24 , C09B33/30 , C09B45/24 , C09B33/04 , C09B45/32
摘要： Compounds containing sulfonic acid groups and of the general formula I ##STR1## where D.sup.1 is a radical of a diazo component, X.sup.1 and X.sup.2 independently of one another are each hydroxyl or unsubstituted or substituted amino, Y is hydrogen, chlorine, methyl, hydroxysulfonyl or a radical of the formulaD.sup.3 --N.dbd.N--and D.sup.2 is a radical of the formula ##STR2## D.sup.3 is a radical of a diazo component from the aniline or aminonaphthalene series, K is a radical of a coupling component from the benzene or naphthalene series, and the rings in the coupling component D.sup.2 may furthermore be substituted by chlorine, methyl, methoxy, hydroxysulfonyl, aminosulfonyl, hydroxyl or acylamino, and metal complexes of such compounds, give very fast, brown dyeings, particularly on leather.
摘要翻译： 含有磺酸基和通式I的化合物其中D1是重氮组分的基团，X1和X2彼此独立地是羟基或未取代的或取代的氨基，Y是氢，氯，甲基，羟基磺酰基 或式D3-N = N-和D2的基团是下式的基团，其中R3是苯胺或氨基萘系列的重氮组分的基团，K是偶联基团 苯和萘系的组分，并且偶联组分D2中的环可以进一步被氯，甲基，甲氧基，羟基磺酰基，氨基磺酰基，羟基或酰氨基取代，并且这些化合物的金属络合物，给出非常快的棕色染色，特别是 在皮革上。
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公开(公告)号：US4486198A
公开(公告)日：1984-12-04
申请号：US570455
申请日：1984-01-13
申请人： Ernst Becker , Udo Bergmann , Helmut Degen , Guenter Hansen , Reinhold Krallmann
发明人： Ernst Becker , Udo Bergmann , Helmut Degen , Guenter Hansen , Reinhold Krallmann
CPC分类号： C09B67/0051 , C09B29/0813 , C09B29/0816 , C09B29/0825 , Y10S534/02 , Y10S8/922
摘要： Navy dye mixtures essentially contain dyes of the formula I ##STR1## where X is hydrogen, chlorine or bromine, the radicals R.sup.1 independently of one another are each methyl or ethyl and R is a radical of the formula ##STR2## where A is ##STR3## B is unsubstituted or substituted C.sub.1 -C.sub.4 -alkyl, phenyl-C.sub.1 -C.sub.4 -alkyl, phenoxy-C.sub.2 - or -C.sub.3 -alkyl or cyclohexyl and R.sup.2 is C.sub.1 -C.sub.4 -alkyl, the mixtures containing from 20 to 80 parts of dyes in which R is NH-A-COOB and from 80 to 20 parts of dyes in which R is ##STR4## The novel mixtures are very useful for dyeing synthetic polyesters, and give dyeings which have, in particular, very good heatfastness.
摘要翻译： 海军染料混合物基本上含有式I的染料，其中X为氢，氯或溴，基团R 1彼此独立地为甲基或乙基，R为下式基团，其中A为< B是未取代的或取代的C 1 -C 4 - 烷基，苯基-C 1 -C 4 - 烷基，苯氧基-C 2 - 或-C 3-烷基或环己基，R 2是C 1 -C 4 - 烷基，所述混合物含有20至80份 其中R是NH-A-COOB的染料和其中R为80至20份的染料。新颖的混合物对于染色合成聚酯是非常有用的，并且给出特别是非常好的耐热性的染色。
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公开(公告)号：US4389216A
公开(公告)日：1983-06-21
申请号：US355309
申请日：1982-03-05
CPC分类号： C09B67/0051 , C09B29/081 , C09B29/0813 , C09B29/0825 , Y10S534/01 , Y10S8/922
摘要： Navy dye mixtures which contain, as essential components, compounds of the general formula I ##STR1## in the following amounts, based on the total weight of the mixture:______________________________________ X = Br R.sup.1 = C.sub.2 H.sub.4 CN R.sup.2 = CH.sub.2 CHCH.sub.2 39-49%, X = Br R.sup.1 = C.sub.2 H.sub.4 CN R.sup.2 = H 1-10%, X = Br R.sup.1 = H R.sup.2 = CH.sub.2 CHCH.sub.2 4-16%, X = Cl R.sup.1 = C.sub.2 H.sub.4 CN R.sup.2 = H 15-25%, X = Cl R.sup.1 = C.sub.2 H.sub.4 CN R.sup.2 = CH.sub.2 CHCH.sub.2 4-9%, and X = Cl ##STR2## R.sup.2 = H 4-10%. ______________________________________ The novel mixtures are very useful for dyeing synthetic polyesters.
摘要翻译： 基于混合物的总重量含有以下量的通式I的化合物作为必要成分的海军染料混合物：-X = Br R1 = C2H4CN R2 = CH2CHCH2 39-49％， - X = Br R1 = C2H4CN R2 = H 1-10％，-X = Br R1 = H R2 = CH2CHCH2 4-16％，-X = C1 R1 = C2H4CN R2 = H 15-25％，-X = Cl R1 = C 2 H 4 CN R 2 = CH 2 CHCH 2 4-9％， - 和 - -X = Cl
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公开(公告)号：US4386934A
公开(公告)日：1983-06-07
申请号：US370904
申请日：1982-04-22
CPC分类号： C09B67/0051 , C09B29/0813 , C09B29/0825 , D06P1/18 , Y10S534/01 , Y10S8/922
摘要： Navy dye mixtures which contain, as essential components, compounds of the general formula I ##STR1## where X is chlorine or bromine, Y is methoxy or ethoxy, and R is ##STR2## NHC.sub.2 H.sub.4 CN, NHCH.sub.2 CH.dbd.CH.sub.2 or N(C.sub.2 H.sub.4 OCOCH.sub.3).sub.2, and wherein the dye of the above formula where X is Br, Y is OCH.sub.3 or OC.sub.2 H.sub.5 and R is N(C.sub.2 H.sub.4 OCOCH.sub.3).sub.2 is present in an amount of 25-45%, based on the total weight of the mixture, are very useful for dyeing synthetic polyesters.
摘要翻译： 含有作为必要组分的通式I的化合物的海军染料混合物，其中X是氯或溴，Y是甲氧基或乙氧基，R是NHC2H4CN，NHCH2CH = CH2或N（C2H4OCOCH3）2 并且其中X为Br，Y为OCH 3或OC 2 H 5且R为N（C 2 H 4 OCOCH 3）2的上式的染料的含量相对于混合物的总重量为25-45％，非常有用 用于染色合成聚酯。
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