公开(公告)号：US4111787A

公开(公告)日：1978-09-05

申请号：US858546

申请日：1977-12-08

Applicant: Clyde L. Aldridge ,  Roby Bearden, Jr.

Inventor： Clyde L. Aldridge ,  Roby Bearden, Jr.

IPC: C10G1/06 ,  C10G1/00 ,  C10G1/08 ,  C10G45/16

CPC classification number: C10G45/16 ,  C10G1/006 ,  C10G1/083 ,  C10G1/086 ,  C10G2300/107

Abstract: A catalytic slurry hydroconversion process for producing normally liquid hydrocarbons from a heavy hydrocarbonaceous oil and from coal is performed in at least two stages in series. The heavy oil is introduced into the first hydroconversion stage and the coal is introduced into any of the hydroconversion stages other than the first stage.

公开(公告)号：US4077867A

公开(公告)日：1978-03-07

申请号：US702272

申请日：1976-07-02

Applicant: Clyde L. Aldridge ,  Roby Bearden, Jr.

Inventor： Clyde L. Aldridge ,  Roby Bearden, Jr.

IPC: C10G1/06 ,  B01J23/00 ,  B01J31/00 ,  C10G1/08

CPC classification number: C10G1/086 ,  C10G1/083 ,  Y10S208/951

Abstract: A process for catalytically hydroconverting coal to produce coal liquids is effected by forming a mixture of an oil soluble metal compound, a hydrogen donor solvent and coal, converting the compound to a catalyst within said mixture and reacting the mixture with hydrogen. The recovered hydrogen donor solvent may be recycled to the hydroconversion zone without intervening hydrogenation. Preferred compounds are molybdenum compounds.

Abstract translation: 通过形成油溶性金属化合物，氢供体溶剂和煤的混合物，将化合物转化为所述混合物内的催化剂并使混合物与氢反应，来实现催化加氢转化煤以产生煤液体的方法。 回收的氢供体溶剂可以循环到加氢转化区而无需中间氢化。 优选的化合物是钼化合物。

公开(公告)号：US5108581A

公开(公告)日：1992-04-28

申请号：US607928

申请日：1990-11-01

Applicant: Clyde L. Aldridge ,  Roby Bearden, Jr. ,  William E. Lewis

Inventor： Clyde L. Aldridge ,  Roby Bearden, Jr. ,  William E. Lewis

IPC: C10G1/08

CPC classification number: C10G1/086

Abstract: Disclosed is a catalytic process for hydroconverting heavy hydrocarbonaceous feedstocks to lower boiling products wherein a catalyst precursor concentrate or catalyst concentrate is first prepared in a heavy oil medium then fed to a hydroconversion zone which may also contain a supported hydrotreating catalyst. The hydroconversion zone may be operated in either slurry or ebullating bed mode.

Abstract translation: 公开了一种用于将重质烃原料加氢转化成低沸点产物的催化方法，其中首先在重油介质中制备催化剂前体浓缩物或催化剂浓缩物，然后将其加入到还可以含有负载型加氢处理催化剂的加氢转化区。 加氢转化区可以以浆料或沸腾床模式操作。

公开(公告)号：US4988434A

公开(公告)日：1991-01-29

申请号：US449177

申请日：1989-12-13

Applicant: Clyde L. Aldridge ,  Roby Bearden, Jr. ,  Kenneth L. Riley

Inventor： Clyde L. Aldridge ,  Roby Bearden, Jr. ,  Kenneth L. Riley

IPC: B01J23/22 ,  C10G45/04 ,  C10G67/02

CPC classification number: C10G45/04 ,  C10G2300/107

Abstract: A method of reducing the concentration of metal contaminants, such as vanadium and nickel, in a petroleum distillate or other hydrocarbonaceous liquid is disclosed. The method comprises demetallizing the distillate over an activated-carbon supported vanadium catalyst.

公开(公告)号：US4604190A

公开(公告)日：1986-08-05

申请号：US762764

申请日：1985-08-05

Applicant: Roby Bearden, Jr. ,  Clyde L. Aldridge

Inventor： Roby Bearden, Jr. ,  Clyde L. Aldridge

IPC: B01J23/26 ,  C10G1/08 ,  C10G47/06 ,  C10G47/12

CPC classification number: B01J23/26 ,  C10G1/086 ,  C10G47/06

Abstract: A catalyst is prepared by adding a water soluble aliphatic polyhydroxy compound such as a polyhydroxy alcohol or a carbohydrate (e.g., sucrose) to an aqueous solution of chromic acid and subsequently introducing the resulting mixture into a hydrocarbon material. The hydrocarbon-containing mixture is heated in the presence of hydrogen sulfide to convert the chromium catalyst precursor to a solid chromium-containing catalyst. Hydroconversion processes utilizing the catalyst to convert oil, coal, and mixtures thereof are also provided.

Abstract translation: 通过将水溶性脂族多羟基化合物如多羟基醇或碳水化合物（例如蔗糖）加入到铬酸水溶液中并随后将所得混合物引入烃材料中来制备催化剂。 将含烃混合物在硫化氢存在下加热以将铬催化剂前体转化成固体含铬催化剂。 还提供了利用催化剂转化油，煤及其混合物的加氢转化方法。

公开(公告)号：US4579838A

公开(公告)日：1986-04-01

申请号：US728082

申请日：1985-04-29

Applicant: Roby Bearden, Jr. ,  Clyde L. Aldridge

Inventor： Roby Bearden, Jr. ,  Clyde L. Aldridge

IPC: B01J23/26 ,  C10G1/08 ,  C10G47/06 ,  C10G47/26 ,  B01J27/047

CPC classification number: B01J23/26 ,  C10G1/086 ,  C10G47/06 ,  C10G47/26

Abstract: A catalyst is prepared by heating the reaction product of CrO.sub.3 and tert-butyl alcohol as catalyst precursor in a hydrocarbon medium in the presence of hydrogen sulfide to convert the catalyst precursor to a solid chromium-containing catalyst. Hydroconversion processes utilizing the catalyst to convert oil, coal, and mixtures thereof are also provided.

Abstract translation: 通过在硫化氢存在下，在烃介质中加热作为催化剂前体的CrO 3和叔丁醇的反应产物以将催化剂前体转化为固体含铬催化剂来制备催化剂。 还提供了利用催化剂转化油，煤及其混合物的加氢转化方法。

公开(公告)号：US4569751A

公开(公告)日：1986-02-11

申请号：US676863

申请日：1984-11-30

Applicant: Clarence M. Eidt, Jr. ,  Clyde L. Aldridge ,  Roby Bearden, Jr.

Inventor： Clarence M. Eidt, Jr. ,  Clyde L. Aldridge ,  Roby Bearden, Jr.

IPC: C10G69/06 ,  C10G69/00 ,  C10G69/10

CPC classification number: C10G69/06

Abstract: A carbonaceous feed, such as a heavy hydrocarbonaceous oil or coal and mixtures thereof, is upgraded by a combination coking and catalytic slurry hydroconversion process.

Abstract translation: 通过组合焦化和催化浆料加氢转化方法提高碳质进料，例如重质含烃油或煤及其混合物。

公开(公告)号：US4567156A

公开(公告)日：1986-01-28

申请号：US728485

申请日：1985-04-29

Applicant: Roby Bearden, Jr. ,  Clyde L. Aldridge

Inventor： Roby Bearden, Jr. ,  Clyde L. Aldridge

IPC: B01J23/26 ,  C10G1/08 ,  C10G47/06 ,  B01J31/12

CPC classification number: C10G1/086 ,  B01J23/26 ,  C10G47/06

Abstract: A catalyst is prepared by adding a water soluble aliphatic polyhydroxy compound such as a polyhydroxy alcohol or a carbohydrate (e.g., sucrose) to an aqueous solution of chromic acid and subsequently introducing the resulting mixture into a hydrocarbon material. The hydrocarbon-containing mixture is heated in the presence of hydrogen sulfide to convert the chromium catalyst precursor to a solid chromimum-containing catalyst. Hydroconversion processes utilizing the catalyst to convert oil, coal, and mixtures thereof are also provided.

Abstract translation: 通过将水溶性脂族多羟基化合物如多羟基醇或碳水化合物（例如蔗糖）加入到铬酸水溶液中并随后将所得混合物引入烃材料中来制备催化剂。 将含烃混合物在硫化氢存在下加热以将铬催化剂前体转化为含固体含铬的催化剂。 还提供了利用催化剂转化油，煤及其混合物的加氢转化方法。

公开(公告)号：US4557822A

公开(公告)日：1985-12-10

申请号：US453529

申请日：1982-12-27

Applicant: Roby Bearden, Jr. ,  Clyde L. Aldridge

Inventor： Roby Bearden, Jr. ,  Clyde L. Aldridge

IPC: B01J37/20 ,  C10G29/02 ,  C10G47/26 ,  C10G67/02 ,  C10G1/06 ,  C10G47/10

CPC classification number: C10G67/02 ,  B01J37/20 ,  C10G29/02 ,  C10G47/26

Abstract: A process for the conversion of a hydrocarbonaceous oil in the presence of hydrogen and an iron-coal catalyst is provided in which a slurry of catalyst in the oil is treated with a hydrogen sulfide-containing gas at specified conditions prior to subjecting the slurry to hydroconversion conditions.

Abstract translation: 提供了一种在氢气和铁 - 煤催化剂存在下转化烃油的方法，其中在经过浆液加氢转化之前，在特定条件下用含硫化氢的气体处理油中的催化剂浆液 条件。

公开(公告)号：US4330392A

公开(公告)日：1982-05-18

申请号：US182508

申请日：1980-08-29

Applicant: Roby Bearden, Jr. ,  Clyde L. Aldridge ,  William C. Baird, Jr.

Inventor： Roby Bearden, Jr. ,  Clyde L. Aldridge ,  William C. Baird, Jr.

IPC: C10G1/08 ,  C10G47/02 ,  C10G47/12 ,  C10G47/26 ,  C10G1/06 ,  C10G47/04

CPC classification number: C10G1/086 ,  C10G47/02 ,  C10G47/12 ,  C10G47/26

Abstract: Nitrogen-containing carbonaceous feeds such as hydrocarbonaceous oils and coal are hydroconverted in the presence of a solid vanadium-containing catalyst and a hydrogen halide.

Abstract translation: 在固体含钒催化剂和卤化氢的存在下，将含氮碳质进料如烃油和煤加氢转化。