Electrochemical cell having a controlled electrode surface and associated fabrication and chemical process
    31.
    发明授权
    Electrochemical cell having a controlled electrode surface and associated fabrication and chemical process 有权
    具有受控电极表面和相关制造和化学过程的电化学电池

    公开(公告)号:US06168878A

    公开(公告)日:2001-01-02

    申请号:US09208895

    申请日:1998-12-10

    IPC分类号: H01M1034

    摘要: An electrochemical cell, and an associated process, wherein the cell includes a controlled electrode surface comprising an electrode with a metallic current collector having a surface, an electrolyte and a reduced additive. The invention further includes a passivating layer at the interface between the metallic current collector and the electrolyte. The passivating layer includes the reduced additive. This passivating layer substantially precludes contact between electrolyte solvent and surface of the metallic current collector to, in turn, substantially prevent gas formation within the cell, which would otherwise result from decomposition of the solvent upon contact with the surface of the metallic current collector. Also, the reduced additive will likewise be substantially precluded from generating a gas upon its decomposition.

    摘要翻译: 电化学电池和相关联的方法,其中所述电池包括受控电极表面,其包括具有带有表面的金属集流体的电极,电解质和还原性添加剂。 本发明还包括在金属集流体和电解质之间的界面处的钝化层。 钝化层包括还原添加剂。 该钝化层基本上排除了电解质溶剂和金属集流体表面之间的接触,从而基本上防止了电池内的气体形成,否则这些气体在与金属集流体的表面接触时分解溶剂会导致。 此外,还原添加剂同样基本上不会在其分解时产生气体。