公开(公告)号：US5229249A

公开(公告)日：1993-07-20

申请号：US755426

申请日：1991-09-04

申请人： Kazunobu Katoh ,  Tetsuro Kojima

发明人： Kazunobu Katoh ,  Tetsuro Kojima

IPC分类号： G03C5/29 ,  G03C1/06 ,  G03C1/295 ,  G03C1/42 ,  G03C5/30 ,  G03C5/305

CPC分类号： G03C1/061

摘要： A silver halide photographic material comprising a support, having thereon one or more hydrophilic colloid layers, wherein at least one of the hydrophilic colloid layers is a silver halide emulsion layer, and wherein the silver halide emulsion layer or another hydrophilic colloid layer contains a compound represented by general formula (I):Y--[(X).sub.n --A.sub.0 --B.sub.0 ].sub.m (I)wherein Y represents a group which is adsorbed on silver halide, X represents a divalent group comprising an atom or group of atoms selected from among a hydrogen atom, a carbon atom, a nitrogen atom, an oxygen atom and a sulfur atom, A.sub.0 represents a divalent linking group which has at least two alkyleneoxy units, B.sub.0 represents an amino group, an ammonium group or a nitrogen containing heterocyclic group, m represents 1, 2 or 3, and n represents 0 or 1, as well as a method for processing a silver halide photographic material in the presence of a compound according to general formula (I).

摘要翻译： 一种卤化银照相材料，其包括其上具有一个或多个亲水胶体层的载体，其中所述亲水胶体层中的至少一个为卤化银乳剂层，并且其中所述卤化银乳剂层或另一亲水胶体层含有表示的化合物 通式（I）：Y - [（X）n-A0-B0] m（I）其中Y表示吸附在卤化银上的基团，X表示包含选自以下的原子或原子团的二价基团： 氢原子，碳原子，氮原子，氧原子和硫原子，A0表示具有至少两个亚烷基氧基的二价连接基，B 0表示氨基，铵基或含氮杂环基， m表示1,2或3，n表示0或1，以及在通式（I）的化合物存在下处理卤化银照相材料的方法。

公开(公告)号：US5196293A

公开(公告)日：1993-03-23

申请号：US821217

申请日：1992-01-15

申请人： Hisashi Okamura ,  Kazunobu Katoh ,  Shoji Yasuda ,  Takashi Hoshimiya

发明人： Hisashi Okamura ,  Kazunobu Katoh ,  Shoji Yasuda ,  Takashi Hoshimiya

IPC分类号： G03C1/06 ,  G03C1/43 ,  G03C7/305

CPC分类号： G03C1/061 ,  G03C7/30558 ,  Y10S430/158

摘要： A silver halide photographic material comprising a support having thereon at least one silver halide emulsion layer, wherein the silver halide photographic material contains at least one compound represented by formula (I): ##STR1## wherein ED represents a group capable of releasing (Time).sub.t -Ind upon a reaction with an oxidation product of a developing agent; Time represents a divalent linking group; t represents 0 to 1; and Ind represents a group represented by formula (II): ##STR2## wherein X represents a monovalent group; and s represents an integer of from 0 to 4.The compound represented by formula (I) is excellent in preservability and rapidly releases a development inhibitor.The silver halide photographic material provides an ultrahigh contrast image using a highly stable developing solution and is particularly suitable for use in photomechanical processes.

公开(公告)号：US5190850A

公开(公告)日：1993-03-02

申请号：US699835

申请日：1991-05-14

申请人： Minoru Sakai ,  Kazunobu Katoh

发明人： Minoru Sakai ,  Kazunobu Katoh

IPC分类号： G03C1/06 ,  G03C1/43 ,  G03C1/46 ,  G03C7/305

CPC分类号： G03C7/30511 ,  G03C1/061 ,  G03C1/46 ,  Y10S430/158

摘要： A silver halide photographic material having on a support a first light-sensitive layer containing a light-sensitive silver halide emulsion and a second light-sensitive layer containing a light-sensitive silver halide emulsion, wherein the first light-sensitive layer and/or a hydrophilic colloid layer contains a hydrazine compound, the second light-sensitive layer contains a redox compound capable of releasing a development inhibitor by oxidation, and the sensitivity of the first light-sensitive layer is higher by 0.2 to 1.0 than that of the second light-sensitive layer.

摘要翻译： 一种卤化银照相材料，其在载体上具有含有感光卤化银乳剂的第一感光层和含有感光卤化银乳剂的第二感光层，其中第一感光层和/或 亲水胶体层含有肼化合物，第二感光层含有通过氧化释放显影抑制剂的氧化还原化合物，第一感光层的灵敏度比第二感光层的灵敏度高0.2〜 敏感层。

公开(公告)号：US5187042A

公开(公告)日：1993-02-16

申请号：US515882

申请日：1990-04-27

申请人： Kazunobu Katoh ,  Hisashi Okamura ,  Hisashi Okada ,  Nobuaki Inoue ,  Toshiro Takahashi ,  Morio Yagihara ,  Tetsuo Yamaguchi

发明人： Kazunobu Katoh ,  Hisashi Okamura ,  Hisashi Okada ,  Nobuaki Inoue ,  Toshiro Takahashi ,  Morio Yagihara ,  Tetsuo Yamaguchi

IPC分类号： G03C1/06 ,  G03C1/09 ,  G03C7/305

CPC分类号： G03C7/30511 ,  G03C1/061 ,  G03C1/09 ,  Y10S430/158

摘要： A silver halide photographic material comprising a support having thereon at least one sensitive silver halide emulsion layer, wherein said emulsion layer comprises a monodisperse emulsion and said emulsion layer or other hydrophilic colloid layer contains at least one hydrazine derivative and at least one redox compound capable of releasing a development inhibitor when oxidized.

摘要翻译： 一种卤化银照相材料，包括其上具有至少一个敏感卤化银乳剂层的载体，其中所述乳剂层包含单分散乳液，所述乳剂层或其它亲水胶体层含有至少一种肼衍生物和至少一种能够 当氧化时释放显影抑制剂。

公开(公告)号：US5175074A

公开(公告)日：1992-12-29

申请号：US784737

申请日：1991-10-29

申请人： Morio Yagihara ,  Kazunobu Katoh

发明人： Morio Yagihara ,  Kazunobu Katoh

IPC分类号： G03C1/06 ,  G03C7/305

CPC分类号： G03C1/061 ,  G03C7/30511 ,  Y10S430/158

摘要： A silver halide photographic material suitable for photomechanical process is disclosed, which has at least one silver halide photographic emulsion hydrophilic colloid layer and contains at least one redox compound capable of releasing a development inhibitor by oxidation and at least one compound of general formula (I') in the photographic emulsion layer or in at least one other hydrophilic colloid layer: ##STR1## wherein the variable terms are as defined in the specification.

摘要翻译： 公开了一种适用于光机械方法的卤化银照相材料，其具有至少一种卤化银照相乳剂亲水胶体层，并含有至少一种能通过氧化释放显影抑制剂的氧化还原化合物和至少一种通式（I' ）在照相乳剂层或至少一个其它亲水胶体层中：其中可变项如说明书中所定义。

公开(公告)号：US5147755A

公开(公告)日：1992-09-15

申请号：US745956

申请日：1991-08-09

申请人： Kazunobu Katoh ,  Hisashi Okada

发明人： Kazunobu Katoh ,  Hisashi Okada

IPC分类号： G03C1/06

CPC分类号： G03C1/06 ,  G03C1/061 ,  G03C2001/108 ,  Y10S430/15

摘要： An ultra-high contrast negative type silver halide photographic material is disclosed, wherein at least one hydrazine derivative of formula (I) and at least one compound of formula (IV) are contained in a silver halide emulsion layer or another hydrophilic collide layer of the photographic material: ##STR1## wherein A.sub.1 and A.sub.2 both represent hydrogen atoms, or one represents a hydrogen atom and the other represents a sulfinic acid residual group or an acyl group, R represents an aliphatic group, an aromatic group or a heterocyclic group, and X represents a group as indicated by formulae (II) and (III) ##STR2## wherein X.sub.1 and X.sub.2 each represent a hydrogen atom, an alkyl group, an alkenyl group, an aryl group, and X.sub.1 and X.sub.2 may be joined together to form a ring;--O--X.sub.3 (III)wherein X.sub.3 represents a hydrogen atom, an alkyl group, an alkenyl group, an aryl group or a heterocyclic group; andY.sub.0 [(A.sub.0).sub.n B].sub.m (IV)wherein Y.sub.0 represents a group which promotes adsorption on silver halide, A.sub.0 represents a divalent linking group, B represents an amino group, an ammonium group, or a nitrogen containing heterocyclic group, m represents 1, 2 or 3, and n represents 0, or 1.

摘要翻译： 公开了一种超高对比度负型卤化银照相材料，其中式（I）的至少一种肼衍生物和至少一种式（IV）的化合物包含在卤化银乳剂层或其中的另一种亲水性碰撞层 照片材料：其中A1和A2均表示氢原子，或一个表示氢原子，另一个表示亚磺酸残基或酰基，R表示脂族基团，芳族基团或杂环基 基团，X表示由式（II）和（III）表示的基团，其中X1和X2各自表示氢原子，烷基，烯基，芳基和X1和X2 可以结合在一起形成环; -O-X3（III）其中X3表示氢原子，烷基，烯基，芳基或杂环基; Y0 [（A0）nB] m（IV）其中Y0表示促进卤化银吸附的基团，A0表示二价连接基团，B表示氨基，铵基或含氮杂环基，m表示 1,2或3，n表示0或1。

公开(公告)号：US5124231A

公开(公告)日：1992-06-23

申请号：US588123

申请日：1990-09-25

申请人： Minoru Sakai ,  Kazunobu Katoh

发明人： Minoru Sakai ,  Kazunobu Katoh

IPC分类号： G03C1/06

CPC分类号： G03C1/061 ,  Y10S430/158

摘要： A silver halide photographic material which has at least one photosensitive silver halide emulsion layer containing a hydrazine derivative, and in which said emulsion layer and/or a hydrophilic colloid layer which is different from said emulsion layer contains a redox compound which release a development inhibitor when it is oxidized and an organic compound which is a melting-pointlowering agent which is essentially insoluble in water and which has the effect of lowering the melting point of said redox compound when the former has been mixed with the latter.

摘要翻译： 一种卤化银照相材料，其具有含有肼衍生物的至少一种光敏卤化银乳剂层，并且其中与所述乳剂层不同的所述乳剂层和/或亲水胶体层含有释放显影抑制剂的氧化还原化合物， 它被氧化，并且是一种有机化合物，其是基本上不溶于水的熔点降低剂，并且当前者与后者混合时具有降低所述氧化还原化合物的熔点的作用。

公开(公告)号：US5061594A

公开(公告)日：1991-10-29

申请号：US470496

申请日：1990-01-26

申请人： Hisashi Okamura ,  Kazunobu Katoh

发明人： Hisashi Okamura ,  Kazunobu Katoh

IPC分类号： C07D401/12 ,  G03C1/06 ,  G03C1/485

CPC分类号： C07D401/12 ,  G03C1/061

摘要： A silver halide photographic material which comprises a support having thereon at least one hydrophilic colloid layer being a silver halide photographic emulsion layer, and at least one hydrophilic colloid layer containing a compound represented by the following general formula (I): ##STR1## wherein A.sub.1 and A.sub.2 both represent a hydrogen atom, or one of A.sub.1 and A.sub.2 is a hydrogen atom and the other is a sulfonyl group or an acyl group; R.sub.1 represents an aliphatic group or an aromatic group; G.sub.1 represents a carbonyl group, a sulfonyl group, a sulfinyl group, a sulfoxy group, a group of ##STR2## wherein R.sub.2 is an alkoxy group or an aryloxy group, a group of ##STR3## or an iminomethylene group; X.sub.1 represents a residue of a nitrogen-containing heterocyclic ring; and at least one of R.sub.1 and X.sub.1 having an adsorption-accelerating group on silver halide.

摘要翻译： 一种卤化银照相材料，其包括其上具有至少一个亲水胶体层的卤化银照相乳剂层的支持体和至少一种含有由以下通式（I）表示的化合物的亲水胶体层： ）其中A1和A2均表示氢原子，或A1和A2之一为氢原子，另一个为磺酰基或酰基; R1表示脂肪族基团或芳香族基团; G1表示羰基，磺酰基，亚磺酰基，亚砜基，其中R2是烷氧基或芳氧基，一个“IMAGE”或“亚氨基亚甲基”的基团; X1表示含氮杂环的残基; 并且在卤化银上具有吸附促进基团的R1和X1中的至少一个。

公开(公告)号：US5006445A

公开(公告)日：1991-04-09

申请号：US343441

申请日：1989-04-26

申请人： Morio Yagihara ,  Hisashi Okada ,  Kazunobu Katoh

发明人： Morio Yagihara ,  Hisashi Okada ,  Kazunobu Katoh

IPC分类号： G03C1/06 ,  G03C1/485

CPC分类号： G03C1/061

摘要： A silver halide photographic material comprising a support having thereon at least one hydrophilic colloid layer, at least one of which is a silver halide photographic emulsion layer, is disclosed. At least one of the silver halide emulsion layers or other hydrophilic colloid layers of the photographic material contains a compound represented by formula (I): ##STR1## wherein, A.sub.1 and A.sub.2 both represent hydrogen atoms or one represents a hydrogen atom and the other a sulfonyl group or an acyl group, R.sub.1 represents an aliphatic group, an aromatic group or a heterocyclic group, G.sub.1 represents a carbonyl group, a sulfonyl group, a sulfoxy group, a ##STR2## group wherein R.sub.2 represents an alkoxy group or an aryloxy group, a ##STR3## group or an iminomethylene group, X.sub.1 is a moiety which instigates a ring-forming reaction by cleaving the --G.sub.1 --X.sub.1 moiety from the residual molecule and forms a cyclic structure containing the atoms of the --G.sub.1 --X.sub.1 moiety, and at least one of R.sub.1 and X.sub.1 has a silver halide adsorption accelerating group.

摘要翻译： 公开了一种卤化银照相材料，其包含其上具有至少一个亲水胶体层的载体，其中至少一个是卤化银照相乳剂层。 照相材料的卤化银乳剂层或其他亲水胶体层中的至少一种含有由式（I）表示的化合物：其中，A1和A2均代表氢原子或一个表示氢原子， 另一个是磺酰基或酰基，R 1表示脂族基团，芳族基团或杂环基团，G 1表示羰基，磺酰基，磺基氧基，其中R 2表示烷氧基或 一个芳氧基，一个“IMAGE”基团或一亚氨基亚甲基，X 1是通过从残留分子中切割-G1-X1部分并形成含有-G1-的原子的环状结构来引发成环反应的部分， X1部分，并且R1和X1中的至少一个具有卤化银吸附促进基团。

公开(公告)号：US4987052A

公开(公告)日：1991-01-22

申请号：US139230

申请日：1987-12-29

申请人： Shigeo Hirano ,  Kazunobu Katoh ,  Yoshio Inagaki ,  Nobuaki Inoue

发明人： Shigeo Hirano ,  Kazunobu Katoh ,  Yoshio Inagaki ,  Nobuaki Inoue

IPC分类号： G03C1/06 ,  G03C1/12

CPC分类号： G03C1/12 ,  G03C1/061

摘要： A silver halide photographic material is disclosed, which comprises at least one silver halide emulsion layer on a support, at least one of the emulson layer and other layers contains at least one hydrazine derivative and at least one of these layers contains at least one compound having both a silver halide adsorbing group and an acid group represented by the general formula (I):C-L-D (I)wherein C represents a group that enhances adsorption to silver halide, D represents an acid group, and L represents a divalent linking group,and possessing substantially no absorption maximum in the visible region. A method for forming superhigh contrast negative images is also disclosed, comprising imagewise exposing this silver halide photographic material, followed by developing with a developing solution containing sulfite ions in an amount of about 0.15 mol or more per liter and having a pH of about 10.5 to about 12.3.

摘要翻译： 公开了一种卤化银照相材料，其包含至少一个卤化银乳剂层，其中至少一个乳化剂层和其它层含有至少一个肼衍生物，并且这些层中的至少一个含有至少一种具有 卤化银吸附基团和由通式（I）表示的酸基团：CLD（I）其中C表示增强对卤化银的吸附的基团，D表示酸基，L表示二价连接基团， 在可见区域基本上没有吸收最大值。 还公开了一种用于形成超高对比度负像的方法，包括成像曝光该卤化银照相材料，然后用含有约0.15摩尔或更高/升每升的量的亚硫酸根离子的显影溶液显影，并具有约10.5的pH至 约12.3。