公开(公告)号：US4181602A

公开(公告)日：1980-01-01

申请号：US967413

申请日：1978-12-07

Applicant: Leonard M. Quick ,  Albert L. Hensley, Jr.

Inventor： Leonard M. Quick ,  Albert L. Hensley, Jr.

IPC: B01J23/28 ,  B01J23/88 ,  B01J23/887 ,  B01J35/10 ,  C10G45/04 ,  C10G23/02

CPC classification number: B01J23/8878 ,  B01J23/28 ,  B01J35/10 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1061 ,  B01J35/1085 ,  C10G2300/107

Abstract: The process comprises contacting a heavy hydrocarbon stream under suitable conditions and in the presence of hydrogen with a catalyst comprising a hydrogenating component selected from the group consisting of (1) molybdenum, chromium, and a small amount of cobalt, (2) their oxides, (3) their sulfides, and (4) mixtures thereof deposed on a large-pore, catalytically active alumina. The molybdenum is present in an amount within the range of about 5 wt.% to about 15 wt.%, calculated as MoO.sub.3 and based upon total catalyst weight, the chromium is present in an amount within the range of about 5 wt.% to about 20 wt.%, calculated as Cr.sub.2 O.sub.3 and based upon the total catalyst weight, and the cobalt is present in an amount within the range of about 0.1 wt.% to about 5 wt.%, calculated as CoO and based upon the total catalyst weight. The catalyst possesses a pore volume within the range of about 0.4 cc/gm to about 0.8 cc/gm, a surface area within the range of about 150 m.sup.2 /gm to about 300 m.sup.2 /gm, and an average pore diameter within the range of about 100 A to about 200 A.

Abstract translation: 该方法包括在合适的条件下和氢存在下使重质烃流与包含选自（1）钼，铬和少量钴的氢化组分的催化剂接触，（2）其氧化物， （3）它们的硫化物，和（4）其沉积在大孔催化活性氧化铝上的混合物。 钼的存在量为约5重量％至约15重量％，以MoO 3计，基于总催化剂重量，铬的存在量为约5重量％至 约20重量％，以Cr 2 O 3计，基于总催化剂重量，钴的存在量为约0.1重量％至约5重量％，以COO计，基于总催化剂 重量。 催化剂的孔体积在约0.4cc / g至约0.8cc / gm范围内，表面积在约150m 2 / gm至约300m 2 / gm范围内，平均孔径在 约100 A至约200 A.