公开(公告)号：US20180334390A1

公开(公告)日：2018-11-22

申请号：US15821001

申请日：2017-11-22

Applicant: Saudi Arabian Oil Company

Inventor： Lianhui Ding ,  Essam Al-Sayed ,  Kareemuddin Shaik ,  Abdennour Bourane

IPC: C01B39/02 ,  B01J29/04 ,  B01J29/08 ,  B01J23/28 ,  B01J23/30 ,  B01J23/75 ,  B01J23/755 ,  B01J35/00 ,  B01J35/10 ,  B01J37/00 ,  B01J37/08

CPC classification number: C01B39/026 ,  B01J23/28 ,  B01J23/30 ,  B01J23/75 ,  B01J23/755 ,  B01J29/041 ,  B01J29/042 ,  B01J29/044 ,  B01J29/045 ,  B01J29/084 ,  B01J29/166 ,  B01J35/0066 ,  B01J35/10 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1042 ,  B01J35/1047 ,  B01J35/1057 ,  B01J35/1061 ,  B01J35/1066 ,  B01J35/108 ,  B01J35/1085 ,  B01J35/109 ,  B01J37/0018 ,  B01J37/08 ,  B01J37/20 ,  B01J2029/081 ,  B01J2229/14 ,  B01J2229/16 ,  B01J2229/183 ,  B01J2229/186 ,  B01J2229/20 ,  B01J2229/32 ,  B01J2229/38 ,  B01J2229/40 ,  B01J2229/42 ,  B01J2229/62 ,  C01B39/04 ,  C01B39/205 ,  C01B39/24 ,  C10G45/04 ,  C10G47/20

Abstract: According to one or more embodiments disclosed herein, a mesoporous zeolite may be made by a method comprising contacting an initial zeolite material with ammonium hexafluorosilicate to modify the framework of the initial zeolite material, and forming mesopores in the framework-modified zeolite material. The contacting may form a framework-modified zeolite material. The mesoporous zeolites may be incorporated into catalysts.

公开(公告)号：US09776180B2

公开(公告)日：2017-10-03

申请号：US13581997

申请日：2011-03-22

Applicant: Shinichi Inoue ,  Yukitaka Wada ,  Akihiro Mutou ,  Takeo Ono

Inventor： Shinichi Inoue ,  Yukitaka Wada ,  Akihiro Mutou ,  Takeo Ono

IPC: B01J23/85 ,  B01J31/38 ,  B01J21/04 ,  B01J21/06 ,  B01J23/883 ,  B01J35/00 ,  B01J35/10 ,  B01J37/02 ,  C10G45/08 ,  B01J37/06 ,  B01J23/88 ,  B01J27/19 ,  B01J23/882

CPC classification number: B01J31/38 ,  B01J21/04 ,  B01J21/063 ,  B01J23/88 ,  B01J23/882 ,  B01J23/883 ,  B01J27/19 ,  B01J35/002 ,  B01J35/0026 ,  B01J35/0033 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1047 ,  B01J35/1061 ,  B01J35/1085 ,  B01J37/0207 ,  B01J37/0219 ,  B01J37/0221 ,  B01J37/06 ,  C10G45/08

Abstract: Provided are: a hydrotreating catalyst for hydrocarbon oil having a hydrodesulfurization activity additionally improved by: simultaneously and continuously adding an aqueous solution of an acidic compound containing titanium and an aqueous solution containing an alkaline compound to a hydrosol containing an alumina hydrate particle at a temperature of 10 to 100° C. and a pH of 4.5 to 6.5; washing the resultant to remove a contaminating ion; forming the washed product after dehydration so as to have a moisture content at which it is formable; drying the resultant; impregnating the dried product with a catalytic component aqueous solution containing at least one kind of periodic table group 6 metal compound, at least one kind of periodic table group 8-10 metal compound, at least one kind of phosphorus compound, and at least one kind of saccharide; and drying the resultant; a manufacturing method for the catalyst; and a hydrodesulfurization treatment method for hydrocarbon oil using the catalyst.

公开(公告)号：US09737883B2

公开(公告)日：2017-08-22

申请号：US14349105

申请日：2012-10-22

Applicant: JGC CATALYSTS AND CHEMICALS LTD.

Inventor： Kenji Yamane ,  Kouichi Ohama ,  Shogo Tagawa

IPC: B01J27/16 ,  B01J27/19 ,  B01J31/12 ,  B01J35/10 ,  C10G45/04 ,  B01J37/02 ,  B01J37/03 ,  B01J37/28

CPC classification number: B01J27/19 ,  B01J27/16 ,  B01J31/121 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1047 ,  B01J35/1061 ,  B01J35/1085 ,  B01J35/109 ,  B01J37/0203 ,  B01J37/024 ,  B01J37/033 ,  B01J37/28 ,  C10G45/04 ,  C10G2300/201

Abstract: A hydrotreating catalyst includes a hydrogenation active metal supported on a alumina-phosphorus support and satisfies: a specific surface area being 100 m2/g or more; a total pore volume measured by mercury intrusion being in a range 0.80-1.50 ml/g; a maximum value of pore distribution being present in a pore diameter range 10-30 nm; a ratio of a pore volume of pores with a pore diameter within a range of ±2 nm of a pore diameter at the maximum value to a pore volume of pores with a pore diameter in a range 5-100 nm being 0.40 or less; a pressure capacity being 10 N/mm or more; 0.4-10.0 mass % of phosphorus being contained in the catalyst in terms of P2O5 concentration based on a total amount of the catalyst; and a hydrogenation active metal being at least one metal selected from metals of VIA and VIII groups of the periodic table.

公开(公告)号：US20170165641A1

公开(公告)日：2017-06-15

申请号：US15441732

申请日：2017-02-24

Applicant: Rennovia Inc.

Inventor： Eric L. Dias ,  Alfred Hagemeyer ,  Hong X. Jiang ,  James Longmire ,  James A.W. Shoemaker ,  Valery Sokolovskii ,  Guang Zhu ,  Vincent J. Murphy ,  Gary M. Diamond

IPC: B01J21/18 ,  C09C1/56 ,  C09C1/48

CPC classification number: B01J21/18 ,  B01J23/06 ,  B01J23/18 ,  B01J23/22 ,  B01J23/28 ,  B01J23/34 ,  B01J23/40 ,  B01J23/42 ,  B01J23/52 ,  B01J23/6567 ,  B01J23/70 ,  B01J23/755 ,  B01J23/892 ,  B01J35/002 ,  B01J35/008 ,  B01J35/0086 ,  B01J35/023 ,  B01J35/04 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1061 ,  B01J35/1066 ,  B01J35/1085 ,  B01J37/0009 ,  B01J37/0018 ,  B01J37/0201 ,  B01J37/0215 ,  B01J37/084 ,  B01J37/10 ,  C04B35/532 ,  C04B35/636 ,  C04B35/6365 ,  C04B35/638 ,  C04B38/0615 ,  C04B2111/0081 ,  C04B2235/424 ,  C04B2235/5409 ,  C04B2235/6586 ,  C04B2235/96 ,  C07C29/149 ,  C07C29/60 ,  C07C51/235 ,  C07C51/377 ,  C07C209/16 ,  C09C1/48 ,  C09C1/56 ,  C07C211/12 ,  C07C55/14 ,  C07C59/285 ,  C07C31/20 ,  C04B38/0054

Abstract: Shaped porous carbon products and processes for preparing these products are provided. The shaped porous carbon products can be used, for example, as catalyst supports and adsorbents. Catalyst compositions including these shaped porous carbon products, processes of preparing the catalyst compositions, and various processes of using the shaped porous carbon products and catalyst compositions are also provided.

公开(公告)号：US20170073592A1

公开(公告)日：2017-03-16

申请号：US15124756

申请日：2015-02-27

Applicant: Nippon Ketjen Co., Ltd

Inventor： Kenji NONAKA ,  Yuuki KANAI ,  Yasuo TOYOSHI ,  Youhei NISHIMORI ,  Toyokazu KOBAYASHI

IPC: C10G45/08 ,  B01J37/02 ,  B01J35/10 ,  B01J23/882 ,  B01J27/19

CPC classification number: C10G45/08 ,  B01J21/12 ,  B01J21/14 ,  B01J23/002 ,  B01J23/882 ,  B01J23/883 ,  B01J27/19 ,  B01J31/0202 ,  B01J31/0204 ,  B01J31/0209 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1061 ,  B01J35/1085 ,  B01J37/0009 ,  B01J37/0018 ,  B01J37/0203 ,  B01J37/0207 ,  B01J37/0213 ,  B01J37/0236 ,  B01J37/036 ,  B01J2231/64 ,  B01J2523/00 ,  B01J2531/64 ,  B01J2531/66 ,  B01J2531/845 ,  B01J2531/847 ,  C10G45/06 ,  C10G2300/1037 ,  C10G2300/1044 ,  C10G2300/1051 ,  C10G2300/1074 ,  C10G2300/202 ,  C10G2300/301 ,  C10G2400/04 ,  C10G2400/06 ,  B01J2523/22 ,  B01J2523/31 ,  B01J2523/41

Abstract: To provide a catalyst having hydrotreatment (hydrogenation, desulfurization and denitrification) performance that is equal to or superior to the prior art, as a hydrotreating catalyst for hydrocarbon oils, and a hydrotreating process for hydrocarbon oils using the catalyst. The catalyst comprises 10 to 40 mass % of at least one element of Group 6 of the Periodic Table, 0.5 to 15 mass % of at least one element of Groups 8 to 10 of the Periodic Table based on the oxide catalysts, and a 0.05- to 3-fold amount of an organic additive with respect to the total number of moles of the elements of Group 6 and Groups 8 to 10 of the Periodic Table, added to an inorganic porous support composed mainly of silica-alumina that comprises an oxide of a metal of Group 2 of the Periodic Table.

Abstract translation: 提供具有与现有技术相同或优于现有技术的加氢处理（氢化，脱硫和脱氮）性能的催化剂，作为烃油的加氢处理催化剂，以及使用该催化剂的烃油的加氢处理方法。 催化剂含有10〜40质量％的元素周期表第6族元素中的至少一种元素，0.5〜15质量％的元素周期表第8〜10元中的至少一种元素，基于氧化物催化剂， 至3倍量的有机添加剂，相对于周期表中第6族和第8至10族的元素的总摩尔数，加入到主要由二氧化硅 - 氧化铝组成的无机多孔载体中，其包含氧化物 周期表第2组的金属。

公开(公告)号：US20170021341A1

公开(公告)日：2017-01-26

申请号：US15135054

申请日：2016-04-21

Applicant: RELIANCE INDUSTRIES LIMITED

Inventor： Chidambaram MANDAN ,  Kshudiram MANTRI ,  Ramesh BHUJADE ,  Nagesh SHARMA ,  Raksh Vir JASRA

IPC: B01J27/19 ,  B01J23/882 ,  B01J37/20 ,  B01J37/02 ,  B01J37/16 ,  C10G3/00 ,  B01J37/08

CPC classification number: B01J27/19 ,  B01J23/002 ,  B01J23/882 ,  B01J23/8877 ,  B01J27/0515 ,  B01J35/002 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1061 ,  B01J35/1085 ,  B01J37/0203 ,  B01J37/0205 ,  B01J37/0236 ,  B01J37/024 ,  B01J37/08 ,  B01J37/16 ,  B01J37/18 ,  B01J37/20 ,  B01J37/28 ,  B01J2523/00 ,  C10G3/44 ,  C10G3/46 ,  C10G3/48 ,  C10G3/50 ,  C10G2300/1011 ,  C10G2300/1014 ,  C10G2300/202 ,  Y02P30/20 ,  B01J2523/25 ,  B01J2523/31 ,  B01J2523/3712 ,  B01J2523/48 ,  B01J2523/51 ,  B01J2523/68 ,  B01J2523/821 ,  B01J2523/845 ,  B01J2523/56

Abstract: The present disclosure provides a multi-metallic catalyst system comprising at least one support, and at least one promoter component and an active component comprising at least two metals uniformly dispersed on the support. The present disclosure also provides a process for preparing the multi-metallic catalyst system. Further, the present disclosure provides a process for preparing upgraded fuel from biomass. The process is carried out in two steps. In the first step, a biomass slurry is prepared and is heated in the presence of hydrogen and a multi-metallic catalyst that comprises at least one support, at least one promoter component, and an active component comprising at least two metals to obtain crude biofuel as an intermediate product. The intermediate product obtained in the first step is then cooled and filtered to obtain a filtered intermediate product. In the second step, the filtered intermediate product is hydrogenated in the presence of the multi-metallic catalyst to obtain the upgraded fuel. The fuel obtained from the process of the present disclosure is devoid of heteroatoms such as oxygen, nitrogen and sulfur.

Abstract translation: 本公开内容提供了包含至少一种载体和至少一种促进剂组分和包含均匀分散在载体上的至少两种金属的活性组分的多金属催化剂体系。 本公开还提供了制备多金属催化剂体系的方法。 此外，本公开提供了一种从生物质制备升级燃料的方法。 该过程分两步进行。 在第一步骤中，制备生物质浆料并在氢气和多金属催化剂的存在下加热，所述多金属催化剂包含至少一种载体，至少一种助催化剂组分和包含至少两种金属的活性组分以获得粗生物燃料 作为中间产品。 然后将在第一步骤中获得的中间产物冷却并过滤以获得过滤的中间产物。 在第二步中，过滤的中间产物在多金属催化剂的存在下氢化以获得升级的燃料。 从本公开的方法获得的燃料没有杂原子，例如氧，氮和硫。

公开(公告)号：US09339798B2

公开(公告)日：2016-05-17

申请号：US14788861

申请日：2015-07-01

Applicant: Saint-Gobain Ceramics & Plastics, Inc.

Inventor： Michael A. Richard ,  John R. Lockemeyer

IPC: B01J27/047 ,  B01J27/02 ,  C07D301/04 ,  C07D301/10 ,  B01J21/04 ,  B01J23/50 ,  B01J27/055 ,  B01J35/10 ,  B01J23/66

CPC classification number: B01J27/047 ,  B01J21/04 ,  B01J23/50 ,  B01J23/66 ,  B01J27/02 ,  B01J27/055 ,  B01J35/1085 ,  B01J35/109 ,  B01J35/1095 ,  C07D301/04 ,  C07D301/10 ,  Y02P20/52

Abstract: The carrier of the present invention includes at least 85 wt percent alpha alumina, at least 0.06 wt percent SiO2 and no more than 0.04 wt percent Na2O. The carrier has a water absorption no greater than 0.35 g/g and a ratio of water absorption (g/g) to surface area (m2/g) no greater than 0.50 g/m2. Another aspect of the invention is a catalyst for the epoxidation of olefins which comprises the above described carrier and silver dispersed thereon, where the carrier has a monomodal, bimodal or multimodal pore distribution and where the quantity of silver is between 5 and 50 wt/%, relative to the weight of the catalyst. A reactor system for the epoxidation of olefins is also disclosed.

Abstract translation: 本发明的载体包括至少85wt％的α氧化铝，至少0.06wt％的SiO 2和不超过0.04wt％的Na 2 O. 载体的吸水率不大于0.35g / g，吸水率（g / g）与表面积（m2 / g）不大于0.50g / m 2。 本发明的另一方面是用于环氧化烯烃的催化剂，其包含分散在其上的上述载体和银，其中载体具有单峰，双峰或多峰孔分布，并且其中银的量为5至50重量％ ，相对于催化剂的重量。 还公开了用于烯烃环氧化的反应器系统。

公开(公告)号：US09227180B2

公开(公告)日：2016-01-05

申请号：US13465704

申请日：2012-05-07

Applicant: Chiranjeevi Thota ,  Dattatraya Tammannashastri Gokak ,  Poyyamani Swaminathan Viswanathan

Inventor： Chiranjeevi Thota ,  Dattatraya Tammannashastri Gokak ,  Poyyamani Swaminathan Viswanathan

IPC: B01J29/06 ,  B01J29/076 ,  B01J35/10 ,  B01J23/648 ,  B01J29/12 ,  B01J38/12 ,  C10G11/18 ,  C10G11/05 ,  B01J23/44 ,  B01J29/068 ,  B01J29/90 ,  B01J37/02 ,  B01J37/08 ,  B01J38/48 ,  B01J23/58 ,  B01J23/89 ,  B01J23/96 ,  B01J29/072 ,  B01J29/14 ,  B01J29/16 ,  B01J35/00 ,  B01J35/02

CPC classification number: B01J29/076 ,  B01J23/44 ,  B01J23/58 ,  B01J23/648 ,  B01J23/6482 ,  B01J23/8906 ,  B01J23/892 ,  B01J23/96 ,  B01J29/068 ,  B01J29/072 ,  B01J29/123 ,  B01J29/126 ,  B01J29/143 ,  B01J29/146 ,  B01J29/163 ,  B01J29/166 ,  B01J29/90 ,  B01J35/002 ,  B01J35/0026 ,  B01J35/023 ,  B01J35/1019 ,  B01J35/1061 ,  B01J35/1085 ,  B01J35/109 ,  B01J37/0201 ,  B01J37/0207 ,  B01J37/0244 ,  B01J37/08 ,  B01J38/12 ,  B01J38/485 ,  C10G11/05 ,  C10G11/18 ,  C10G11/182 ,  C10G2300/405 ,  C10G2300/70

Abstract: The present invention relates to a multifunctional catalyst additive composition for reduction of carbon monoxide and nitrogen oxides in a fluid catalytic cracking process comprising an inorganic oxide; alumino silicate or a zeolite; a noble metal; a metal of Group I A; a metal of Group II A; a metal of Group III A; a metal of Group IV A; a metal of Group V A; a rare earth oxide; at least a metal of Group VIII. The composition is attrition resistant and is incorporated on a support. The present invention also discloses a process for preparing the multifunctional catalyst additive composition. The present invention also discloses a fluid cracking catalyst comprising the multifunctional catalyst additive composition.

Abstract translation: 本发明涉及用于在包含无机氧化物的流化催化裂化方法中还原一氧化碳和氮氧化物的多官能催化剂添加剂组合物; 铝硅酸盐或沸石; 贵金属; 第一组A的金属; IIA族金属; IIIA族金属; IVA族金属; V A族金属; 稀土氧化物; 至少是第VIII组的金属。 该组合物是耐磨损的并且被结合在载体上。 本发明还公开了一种制备多官能催化剂添加剂组合物的方法。 本发明还公开了一种包含多官能催化剂添加剂组合物的流体裂解催化剂。

公开(公告)号：US20150267124A1

公开(公告)日：2015-09-24

申请号：US14662795

申请日：2015-03-19

Applicant: IFP ENERGIES NOUVELLES ,  ENI S.P.A.

Inventor： Dominique DECOTTIGNIES ,  Fabrice DIEHL ,  Vincent LECOCQ ,  Marie VELLY

IPC: C10G2/00

CPC classification number: C10G2/33 ,  B01J23/002 ,  B01J27/1853 ,  B01J27/1856 ,  B01J35/002 ,  B01J35/023 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1047 ,  B01J35/1085 ,  B01J37/0205 ,  B01J37/18 ,  B01J37/341 ,  B01J2523/00 ,  C10G2/332 ,  C10G2/333 ,  C10G2300/70 ,  B01J2523/31 ,  B01J2523/41 ,  B01J2523/51 ,  B01J2523/845

Abstract: The present invention describes a Fischer-Tropsch process for synthesis of hydrocarbons comprising contacting a charge comprising synthesis gas under Fischer-Tropsch synthesis operating conditions with at least one catalyst containing an active phase comprising at least one metal of group VIIIB selected from cobalt, nickel, ruthenium and iron deposited on an oxides support comprising alumina, silica and phosphorus, said oxides support not containing any spinel phase. The catalyst has an improved hydrothermal and mechanical resistance in a Fischer-Tropsch process while improving its catalytic performances.

Abstract translation: 本发明描述了用于合成烃的费 - 托方法，包括在费 - 托合成操作条件下使含有合成气的电荷与至少一种含有活性相的催化剂接触，所述催化剂含有至少一种选自钴，镍， 钌和铁沉积在包含氧化铝，二氧化硅和磷的氧化物载体上，所述氧化物不含任何尖晶石相。 催化剂在费 - 托方法中具有改进的水热和机械阻力，同时改善其催化性能。

公开(公告)号：US09011674B2

公开(公告)日：2015-04-21

申请号：US13314683

申请日：2011-12-08

Applicant: Stanley Nemec Milam ,  Michael Anthony Reynolds ,  Scott Lee Wellington ,  Frederik Arnold Buhrman

Inventor： Stanley Nemec Milam ,  Michael Anthony Reynolds ,  Scott Lee Wellington ,  Frederik Arnold Buhrman

IPC: C10G65/12 ,  C10G45/04 ,  C10G47/06 ,  B01J23/652 ,  B01J23/85 ,  B01J27/051 ,  B01J35/00 ,  B01J35/10 ,  B01J37/02

CPC classification number: C10G65/12 ,  B01J23/652 ,  B01J23/85 ,  B01J27/051 ,  B01J27/0515 ,  B01J35/002 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1061 ,  B01J35/1085 ,  B01J37/0201 ,  C10G45/04 ,  C10G47/06 ,  C10G2300/202 ,  C10G2300/301 ,  C10G2300/4006 ,  C10G2300/4012

Abstract: A process is provided in which a first hydrocarbon-containing composition is provided where the first hydrocarbon-containing composition comprises hydrocarbons having a boiling range from 25° C. to 538° C. and from 0.1 wt. % to 5 wt. % sulfur, where at least 40 wt. % of the sulfur is contained in hydrocarbons having a boiling point of less than 343° C. where at least 40 wt. % of the sulfur contained in hydrocarbons having a boiling point less than 343° C. is contained in benzothiophenic compounds, and the first hydrocarbon-containing compound is hydrotreated to produce a second hydrocarbon-containing compound.

Abstract translation: 提供了一种方法，其中提供第一含烃组合物，其中第一含烃组合物包含沸点范围为25℃至538℃的烃和0.1重量％ ％至5wt。 ％硫，其中至少40wt。 硫含量在沸点低于343℃的烃中，其中至少40wt。 在苯并噻吩类化合物中含有沸点低于343℃的烃中所含的硫的％，第一含烃化合物被加氢处理以产生第二含烃化合物。