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31.发明授权Method of preparation of direct dispersions of photographically useful chemicals 失效制备摄影有用化学品的直接分散体的方法公开(公告)号：US07338756B2
公开(公告)日：2008-03-04
申请号：US10692535
申请日：2003-10-24
申请人： Paul L. Zengerle , Richard K. Rothrock , Jerrold N. Poslusny , Stephen P. Singer , Peter P. Garrisi , Paul B. Merkel
发明人： Paul L. Zengerle , Richard K. Rothrock , Jerrold N. Poslusny , Stephen P. Singer , Peter P. Garrisi , Paul B. Merkel
CPC分类号： G03C7/3885 , G03C1/005 , G03C2001/0854
摘要： A process for making a direct dispersion of a photographically useful material comprising: mixing (i) an aqueous phase and (ii) a liquid organic phase under conditions of shear or turbulence to form a dispersion of the organic phase dispersed in the aqueous phase; wherein the liquid organic phase comprises one or more photographically useful materials and one or more organic solvents having a boiling point of at least 150° C., a molecular weight less than or equal to 300, and a solvatochromic parameter β value greater than or equal to 0.50, wherein the weight ratio of the sum of the solvents having a boiling point of at least 150° C., a molecular weight less than or equal to 300, and a solvatochromic parameter β value greater than or equal to 0.50 to the photographically useful materials does not exceed 0.25. The use of relatively low levels of specified high-boiling organic solvents enables the direct dispersion of hydrophobic photographically useful materials with low solubility in conventional primary photographic useful solvents without crystallization problems or excessive decomposition.
摘要翻译： 一种用于直接分散照相的有用材料的方法，包括：（i）水相和（ii）液态有机相在剪切或湍流条件下混合以形成分散在水相中的有机相的分散体; 其中液体有机相包含一种或多种照相用的材料和一种或多种沸点为至少150℃，分子量小于或等于300的有机溶剂，溶剂化变色参数β值大于或等于 至0.50，其中沸点为至少150℃，分子量小于或等于300的溶剂的总和与溶剂化变色参数β值大于或等于0.50的相对于照相的重量比 有用的材料不超过0.25。 使用相对低含量的特定高沸点有机溶剂使得能够在常规的主要照相有用溶剂中直接分散具有低溶解度的疏水照相用材料，而没有结晶问题或过度分解。
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公开(公告)号：US07105215B2
公开(公告)日：2006-09-12
申请号：US10180638
申请日：2002-06-26
申请人： Krishamohan Sharma , Joseph F. Bringley , Paul B. Merkel , Deepak Shukla , Christine Landry-Coltrain
发明人： Krishamohan Sharma , Joseph F. Bringley , Paul B. Merkel , Deepak Shukla , Christine Landry-Coltrain
IPC分类号： B41M5/00
CPC分类号： B41M5/5218 , Y10T428/24802 , Y10T428/25 , Y10T428/2991
摘要： An ink jet recording element comprising a support having thereon an image-receiving layer, the ink jet recording element containing a metal(oxy)hydroxide complex, Mn+(O)a(OH)b(Ap−)c•xH2O, wherein M is at least one metal ion; n is 3 or 4; A is an organic or inorganic ion; p is 1, 2 or 3; and x is equal to or greater than 0; with the proviso that when n is 3, then a, b and c each comprise a rational number as follows: 0≦a
摘要翻译： 一种喷墨记录元件，包括其上具有图像接收层的支撑体，所述喷墨记录元件含有金属（氧）氢氧化物复合物，M + N + （OH）b（A） - （CH 2）n C x H 2 O，其中M是至少一种金属 离子; n为3或4; A是有机或无机离子; p为1,2或3; x等于或大于0; 条件是当n为3时，则a，b和c各自包含如下有理数：0 <= a <1.5; 0
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公开(公告)号：US06659604B2
公开(公告)日：2003-12-09
申请号：US10008777
申请日：2001-12-04
申请人： Paul B. Merkel , Gregory E. Missell
发明人： Paul B. Merkel , Gregory E. Missell
IPC分类号： B41J3407
CPC分类号： B41M5/5254 , B41M5/508
摘要： An ink jet printing method having the steps of: A) providing an ink jet printer that is responsive to digital data signals; B) loading the printer with an ink jet recording element having a support having thereon an image-receiving layer of porous polymeric particles in a polymeric binder, the polymeric binder being poly(vinyl alcohol) having a degree of hydrolysis of at least about 95% and having a number average molecular weight of at least about 45,000; C) loading the printer with an ink jet ink composition; and D) printing on the ink jet recording element using the inkjet ink composition in response to the digital data signals.
摘要翻译： 一种喷墨打印方法，具有以下步骤：A）提供响应于数字数据信号的喷墨打印机; B）使用具有支撑体的喷墨记录元件装载打印机，所述支撑体具有聚合物粘合剂中的多孔聚合物颗粒的图像接收层，所述聚合物粘合剂是具有至少约95％水解度的聚（乙烯醇） 并且具有至少约45,000的数均分子量; C）用喷墨油墨组合物装载打印机; 和D）响应于数字数据信号，使用喷墨油墨组合物在喷墨记录元件上进行印刷。
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公开(公告)号：US06629759B2
公开(公告)日：2003-10-07
申请号：US09999405
申请日：2001-10-31
IPC分类号： B41J201
CPC分类号： B41M5/52 , B41M5/506 , B41M5/5254
摘要： An ink jet printing method having the steps of: A) providing an ink jet printer that is responsive to digital data signals; B) loading the printer with an ink jet recording element having a support having thereon the following layers in order: i) a base layer having a polymeric binder and a polymeric mordant; and ii) an overcoat layer having a polymeric UV-absorbing material; C) loading the printer with an ink jet ink composition of water, a humectant, and a water-soluble dye; and D) printing on the overcoat layer using the ink jet ink in response to the digital data signals.
摘要翻译： 一种喷墨打印方法，具有以下步骤：A）提供响应于数字数据信号的喷墨打印机; B）用具有支撑物的喷墨记录元件装载打印机，所述支撑体依次具有以下层：i）具有聚合物粘合剂和聚合物媒染剂的基层; 和ii）具有聚合物UV吸收材料的外涂层; C）使用水，湿润剂和水溶性染料的喷墨油墨组合物装载打印机; 和D）响应于数字数据信号，使用喷墨油墨在外涂层上进行印刷。
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公开(公告)号：US06605325B2
公开(公告)日：2003-08-12
申请号：US09998736
申请日：2001-10-31
IPC分类号： B32B300
CPC分类号： B41M5/5227 , B41M5/506 , Y10T428/24802
摘要： An ink jet recording element having a support having thereon the following layers in order: i) a base layer of a polymeric binder, a polymeric mordant and a stabilizer having the following formula: and ii) an overcoat layer of a trisaryl-1,3,5-triazine ultraviolet light absorbing material.
摘要翻译： 一种喷墨记录元件，其具有依次具有以下层的支撑体：i）聚合物粘合剂的基层，聚合物媒染剂和具有下式的稳定剂：和ii）三芳基-1,3 ，5-三嗪紫外光吸收材料。
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公开(公告)号：US06422697B1
公开(公告)日：2002-07-23
申请号：US09610735
申请日：2000-07-06
申请人： Paul B. Merkel , Patricia A. Wyble
发明人： Paul B. Merkel , Patricia A. Wyble
IPC分类号： B41J201
CPC分类号： B41M5/52 , B41M5/5218 , Y10T428/31855
摘要： An ink jet printing method, comprising the steps of: A) providing an ink jet printer that is responsive to digital data signals; B) loading the printer with an ink jet recording element comprising a substrate having thereon an image-receiving layer comprising a heterocyclic amine polymer, the image-receiving layer having associated therewith a water-soluble first-row transition metal ion salt; C) loading the printer with an ink jet ink composition; and D) printing on the ink jet recording element using the ink jet ink in response to the digital data signals.
摘要翻译： 一种喷墨打印方法，包括以下步骤：A）提供响应于数字数据信号的喷墨打印机; B）用喷墨记录元件装载打印机，该喷墨记录元件包括其上具有包含杂环的图像接收层的基板 胺聚合物，图像接收层与其相关联具有水溶性第一列过渡金属离子盐; C）用喷墨油墨组合物装载打印机; 和D）响应于数字数据信号，使用喷墨油墨在喷墨记录元件上进行打印。
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37.发明授权Combinations of purine-releasing pyrazolone DIR couplers and pyrazolone or pyrazolotriazole imaging couplers 失效嘌呤释放吡唑啉酮DIR成色剂和吡唑啉酮或吡唑并三唑成像剂的组合
公开(公告)号：US5989798A
公开(公告)日：1999-11-23
申请号：US994663
申请日：1997-12-19
CPC分类号： G03C7/30558 , G03C7/3225 , G03C7/24 , G03C7/3835 , G03C7/384 , Y10S430/158
摘要： A photographic element comprises: (a) a support; and (b) at least one silver halide emulsion layer; wherein said emulsion layer contains (c) at least one magenta dye-forming pyrazolone DIR coupler of structure I; and (d) at least one magenta dye-forming imaging coupler of structure II, structure IIIa or structure IIIb, below: ##STR1## wherein the substituents are as defined in the specification.
摘要翻译： 照相元件包括：（a）支撑体; 和（b）至少一个卤化银乳剂层; 其中所述乳剂层含有（c）结构I的至少一种品红色染料形成吡唑啉酮DIR成色剂; 和（d）结构II，结构IIIa或结构IIIb的至少一种品红染料形成成像成色剂，其中取代基如说明书中所定义。
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公开(公告)号：US5532117A
公开(公告)日：1996-07-02
申请号：US431234
申请日：1995-04-28
CPC分类号： G03C1/831
摘要： The invention provides a multicolor negative photographic element which contains a layer containing a yellow or orange-yellow azoaniline dye of structure I ##STR1## wherein: R.sub.1 is an alkyl group or a phenyl group;R.sub.2 is hydrogen or an alkyl group;R.sub.3 is an alkoxy, aryloxy or alkyl group when R.sub.2 is hydrogen, or is hydrogen when R.sub.2 is an alkyl group;R.sub.1 and R.sub.2 or R.sub.1 and R.sub.3 may join to form a ring;R.sub.4, which may be in the para or meta position relative to the azo group, is an electron-withdrawing group selected from the group consisting of trifluoromethyl, cyano, halogen, and from alkoxycarbonyl, aryloxycarbonyl, acyloxy, carbonamido, sulfonamido, carbamoyl, sulfamoyl, alkylsulfonyl, arylsulfonyl, sulfonyloxy (--OSO.sub.3 R), alkoxysulfonyl, aryloxysulfonyl, and sulfoxide groups;R.sub.5 is hydrogen or, can be a chlorine in the meta position when R.sub.4 is a chlorine in the para position; andthe total number of carbon atoms in R.sub.1, R.sub.2, R.sub.3, and R.sub.4 taken together is at least 9;wherein neither a layer sensitive to blue light nor a layer sensitive to green light is located between the support and the layer in which the azoaniline dye is located. The invention also provides a method of forming an image in an element of the invention.
摘要翻译： 本发明提供一种多色负片照相元件，其含有含有结构I的黄色或橙色 - 黄色偶氮苯胺染料的层，其中：R1是烷基或苯基; R2是氢或烷基; 当R 2为氢时，R 3为烷氧基，芳氧基或烷基，或当R 2为烷基时为R 3; R1和R2或R1和R3可以连接形成环; R4可以相对于偶氮基在对位或间位，是从三氟甲基，氰基，卤素和烷氧基羰基，芳氧基羰基，酰氧基，碳酰氨基，亚磺酰氨基，氨基甲酰基，氨磺酰基中的吸电子基团 ，烷基磺酰基，芳基磺酰基，磺酰氧基（-OSO 3 R），烷氧基磺酰基，芳氧基磺酰基和亚砜基团; 当R4是对位的氯时，R5是氢或可以是间位的氯; R 1，R 2，R 3和R 4中的碳原子总数合计为9以上。 其中对蓝色光敏感的层和对绿色光敏感的层都不位于载体和偶氮苯胺染料所在的层之间。 本发明还提供了一种在本发明的元件中形成图像的方法。
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39.发明授权Photographic elements comprising 2-phenylcarbamoyl-1-naphthol image-modifying couplers yeilding dyes resistant to crystallization and reduction 失效包含2-苯基氨基甲酰基-1-萘酚图像改性成色剂的摄影元件对结晶和还原具有抗性
公开(公告)号：US5521057A
公开(公告)日：1996-05-28
申请号：US99039
申请日：1993-07-28
CPC分类号： G03C11/00 , G03C7/30523 , Y10S430/156
摘要： Photographic elements comprising certain 2-phenylcarbamoyl-1-naphthol image-modifying couplers exhibit proper hue, a resistance to dye crystallization, and a resistance to leuco cyan dye formation. Such couplers can be utilized for their image-modifying effect and can contribute substantially to the overall dye density of an image.
摘要翻译： 包含某些2-苯基氨基甲酰基-1-萘酚图像改性成色剂的照相元件表现出适当的色调，抗染料结晶性和对无色青色染料形成的抗性。 这样的成色剂可以用于其影像修饰效果，并且可以显着地有助于图像的整体染料密度。
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40.发明授权Photographic elements comprising 2-phenylcarbamoyl-1-naphthol image-modifying couplers yielding dyes resistant to crystallization and reduction 失效包含2-苯基氨基甲酰基-1-萘酚图像改性成色剂的摄影元件产生耐结晶和还原的染料
公开(公告)号：US5506094A
公开(公告)日：1996-04-09
申请号：US098552
申请日：1993-07-28
CPC分类号： G03C7/30523 , Y10S430/158
摘要： Photographic elements comprising certain 2-phenylcarbamoyl-1-naphthol image-modifying couplers exhibit proper hue, a resistance to dye crystallization, and a resistance to leuco cyan dye formation. Such couplers can be utilized for their image-modifying effect and can contribute substantially to the overall dye density of an image.
摘要翻译： 包含某些2-苯基氨基甲酰基-1-萘酚图像改性成色剂的照相元件表现出适当的色调，抗染料结晶性和对无色青色染料形成的抗性。 这样的成色剂可以用于其影像修饰效果，并且可以显着地有助于图像的整体染料密度。
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