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    31.
    发明申请
    4"-Deoxy-4"-(s)-amido avermectin derivatives 有权
    4“ - 脱氧-4” - (s) - 氨基阿维菌素衍生物

    公开(公告)号:US20050176656A1

    公开(公告)日:2005-08-11

    申请号:US10513247

    申请日:2003-05-06

    IPC分类号: C07H17/08 C07H19/01 A01N43/04

    CPC分类号: C07H19/01

    摘要: A compound of formula (I); that has the S-configuration at the 4″-position and wherein the bond between carbon atoms 22 and 23 is a single or a double bond; R1 is C1-C12alkyl, C3-C8cycloalkyl; or C2-C12alkenyl; R2 is H, or, for example, unsubstituted or mono- to penta-substituted C1-C12alkyl, C2-C12alkenyl, C2-C12alkynyl or C1-C6alkoxy-C1-C6alkyl; R3 is H or, for example, C1-C12alkyl; X is a bond, O, NR4 or S; and Z is C═O, C═S or S02; and, where applicable, E/Z isomers, mixtures of E/Z isomers and/or tautomers, in each case in free form or in salt form; a process for the preparation of and the use of those compounds and their isomers and tautomers; starting materials for the preparation of the compounds of formula (I); pesticidal compositions in which the active ingredient has been selected from those compounds and their tautomers; and a method of controlling pests using those compositions are described.

    摘要翻译: 式(I)化合物; 其在4“位具有S-构型,并且其中碳原子22和23之间的键是单键或双键; R 1是C 1 -C 12烷基,C 3 -C 8烷基,C 1 -C 12烷基,C 3 -C 12烷基, 环烷基 或C 2 -C 12 - 烯基; R 2是H,或者例如未取代的或一至五取代的C 1 -C 12烷基,C 1 -C 12烷基, C 1 -C 12烷基,C 2 -C 12炔基或C 1 -C 1烷基, C 1 -C 6烷氧基-C 1 -C 6烷基; R 3是H或例如C 1 -C 12烷基; X是键,O,NR 4或S; Z是C-O,C-S或S 0 <2个; 并且在适用的情况下,E / Z异构体,E / Z异构体和/或互变异构体的混合物,在每种情况下为游离形式或盐形式; 一种制备和使用这些化合物及其异构体和互变异构体的方法; 用于制备式(I)化合物的起始原料; 其中活性成分选自那些化合物及其互变异构体的杀虫组合物; 并描述了使用这些组合物来控制害虫的方法。

    4″-deoxy-4″-(S)-amido avermectin derivatives
    32.
    发明授权
    4″-deoxy-4″-(S)-amido avermectin derivatives 有权
    4“ - 脱氧-4” - (S) - 氨基阿维菌素衍生物

    公开(公告)号:US07608595B2

    公开(公告)日:2009-10-27

    申请号:US10513247

    申请日:2003-05-06

    IPC分类号: A01N43/04 A61K31/70 C07H17/08

    CPC分类号: C07H19/01

    摘要: A compound of formula (I); that has the S-configuration at the 4″-position and wherein the bond between carbon atoms 22 and 23 is a single or a double bond; R1 is C1-C12alkyl, C3-C8cycloalkyl; or C2-C12alkenyl; R2 is H, or, for example, unsubstituted or mono- to penta-substituted C1-C12alkyl, C2-C12alkenyl, C2-C12alkynyl or C1-C6alkoxy-C1-C6alkyl; R3 is H or, for example, C1-C12alkyl; X is a bond, O, NR4 or S; and Z is C═O, C═S or S02; and, where applicable, E/Z isomers, mixtures of E/Z isomers and/or tautomers, in each case in free form or in salt form; a process for the preparation of and the use of those compounds and their isomers and tautomers; starting materials for the preparation of the compounds of formula (I); pesticidal compositions in which the active ingredient has been selected from those compounds and their tautomers; and a method of controlling pests using those compositions are described.

    摘要翻译: 式(I)化合物; 其在4“位具有S-构型,并且其中碳原子22和23之间的键是单键或双键; R1是C1-C12烷基,C3-C8环烷基; 或C 2 -C 12烯基; R 2是H,或者例如未取代的或一至五取代的C 1 -C 12烷基,C 2 -C 12链烯基,C 2 -C 12炔基或C 1 -C 6烷氧基-C 1 -C 6烷基; R3是H或例如C1-C12烷基; X是O,NR4或S键; Z为C-O,C-S或SO 2; 并且在适用的情况下,E / Z异构体,E / Z异构体和/或互变异构体的混合物,在每种情况下为游离形式或盐形式; 一种制备和使用这些化合物及其异构体和互变异构体的方法; 用于制备式(I)化合物的起始原料; 其中活性成分选自那些化合物及其互变异构体的杀虫组合物; 并描述了使用这些组合物来控制害虫的方法。