Abstract:
A process for the manufacture of 3-phytyl-2,5,6-trimethylhydroquinone-1-acetate, and optionally therefrom tocopheryl acetate, comprises either C-alkylating 2,3,6-trimethylhydroquinone-1-acetate with isophytol or phytol in the presence of a sulphur(VI) containing catalyst of the formula R1SO2OH, wherein R1 signifies hydroxy, halogen, lower alkyl, halogenated lower alkyl or aryl, in an aprotic organic solvent, or O-alkylating 2,3,6-trimethylhydroquinone-1-acetate with a phytyl halide in a polar aprotic organic solvent in the presence of a base, and subjecting the so-obtained 4-O-phytyl-2,3,6-trimethylhydroquinone-1-acetate to a rearrangement reaction, and in each case optionally submitting the so-obtained 3-phytyl-2,5,6-trimethylhydroquinone-1-acetate to a ring closure reaction to produce tocopheryl acetate. The invention also includes the novel compound 3-phytyl-2,5,6-trimethylhydroquinone-1-acetate and certain stereoisomers thereof, and also the further novel compound 4-hydroxy-2,3,6-trimethyl-5-[3-(4,8,12-trimethyltridecyl)-but-3enyl]phenyl acetate which itself is one of several isomers of 3-phytyl-2,5,6-trimethylhydroquinone-1-acetate formed by isomerization under the influence of heating, e.g. during its distillation as part of the isolation and purification procedure following its manufacture as indicated above. (All-rac)-α-tocopherol, which may be derived from its acetate, is known to be the most active industrially important member of the vitamin E group.
Abstract:
An electrical connector assembly including a plug assembly and a socket assembly. The plug assembly includes a first flex cable and a first housing, and a biasing member. The socket assembly includes a second flex cable and a second housing. The plug assembly is adapted to be inserted into the socket assembly to electrically connect the first flex cable to the second flex cable. The biasing member is adapted to be contacted by a portion of the second housing to move the first flex cable out of an aperture of the first housing.
Abstract:
The invention relates to a connector for joining two conductors, including a first semi-housing and a second semi-housing that can be moved from a position in which said second semi-housing is in a pre-locked state with the first semi-housing into a final locked position. The inventive connector also comprises an electrically conducting clamp which contacts and interconnects the two conductors in the final locked position.
Abstract:
A process for the manufacture of 3-phytyl-2,5,6-trimethylhydroquinone-1-acetate, and optionally therefrom tocopheryl acetate, comprises either C-alkylating 2,3,6-trimethylhydroquinone-1-acetate with isophytol or phytol in the presence of a sulphur(VI) containing catalyst of the formula R1SO2OH, wherein R1 signifies hydroxy, halogen, lower alkyl, halogenated lower alkyl or aryl, in an aprotic organic solvent, or O-alkylating 2,3,6-trimethylhydroquinone-1-acetate with a phytyl halide in a polar aprotic organic solvent in the presence of a base, and subjecting the so-obtained 4-O-phytyl-2,3,6-trimethylhydroquinone-1-acetate to a rearrangement reaction, and in each case optionally submitting the so-obtained 3-phytyl-2,5,6-trimethylhydroquinone-1-acetate to a ring closure reaction to produce tocopheryl acetate. The invention also includes the novel compound 3-phytyl-2,5,6-trimethylhydroquinone-1-acetate and certain stereoisomers thereof, and also the further novel compound 4-hydroxy-2,3,6-trimethyl-5-[3-(4,8,12-trimethyltridecyl)-but-3enyl]phenyl acetate which itself is one of several isomers of 3-phytyl-2,5,6-trimethylhydroquinone-1-acetate formed by isomerization under the influence of heating, e.g. during its distillation as part of the isolation and purification procedure following its manufacture as indicated above. (All-rac)-α-tocopherol, which may be derived from its acetate, is known to be the most active industrially important member of the vitamin E group.
Abstract:
The invention relates to a method for electrically connecting a conductor to a contact, according to which the electrical conductor that is coated with an insulation is first inserted between two legs of the contact, whereupon a welding device is placed against both legs and the welding process is carried out by turning on the welding current. The insulation of the electrical conductor is destroyed due to the heat delivered during the welding process, resulting in a permanent mechanical and electrical connection between the conductor and the contact.
Abstract:
The invention relates to a clamping connector for at least two aligned flexible ribbon cables, said connector including a base body, spring elements for pressing together the surfaces to be brought into contact, and a counter body. The base body and the counter body can be fixed to each other in a pre-locking position and a final locking position. The respective skinned partial regions of at least two flexible ribbon cables are pressed against each other in order to bring the same into contact. The sides of the base body and the counter body facing the flexible ribbon cables, are provided with complementary recesses or projections by which means the flexible ribbon cables can be guided to form a cable grip.