Organic element for electroluminescent devices
    31.
    发明授权
    Organic element for electroluminescent devices 有权
    电致发光器件的有机元件

    公开(公告)号:US07052785B2

    公开(公告)日:2006-05-30

    申请号:US10700916

    申请日:2003-11-04

    IPC分类号: H05B33/14

    摘要: Disclosed is an OLED device comprising a light-emitting layer (LEL) containing a host and a dopant located between a cathode and an anode wherein the emitter is an orange-red light emitting rubrene derivative represented by formula (II): wherein: a) there are identical branched alkyl or non-aromatic carbocyclic groups at the 2- and 8-positions; b) the phenyl rings in the 5- and 11-positions contain only para-substituents identical to the branched alkyl or non-aromatic carbocyclic groups in paragraph a); and c) the phenyl rings in the 6- and 12-positions are substituted.

    摘要翻译: 公开了一种OLED器件,其包括含有主体和位于阴极和阳极之间的掺杂剂的发光层(LEL),其中发射体是由式(II)表示的橙红色发光红荧烯衍生物:其中:a) 在2-和8-位有相同的支链烷基或非芳族碳环基; b)5-和11位中的苯环仅含有与段落a)中的支链烷基或非芳族碳环基团相同的对位取代基; 和c)6位和12位的苯环被取代。

    OLED DEVICE WITH FLUORANTHENE ELECTRON TRANSPORT MATERIALS
    33.
    发明申请
    OLED DEVICE WITH FLUORANTHENE ELECTRON TRANSPORT MATERIALS 有权
    具有氟代电子传输材料的OLED器件

    公开(公告)号:US20090108735A1

    公开(公告)日:2009-04-30

    申请号:US11924631

    申请日:2007-10-26

    IPC分类号: H01L27/28

    摘要: The invention provides an OLED device comprising a cathode, an anode, and having there between a light-emitting layer, further comprising, between the cathode and the light emitting layer, a non-luminescent electron transporting layer containing a compound with a 7,10-diaryl substituted fluoranthene nucleus having no aromatic rings annulated to the fluoranthene nucleus and desirably comprises still further an additional layer containing an organic alkali metal compound, located between the cathode and the electron transporting layer.Devices of the invention provide improvement in features such as efficiency, drive voltage, and operational stability.

    摘要翻译: 本发明提供了一种OLED器件,其包括阴极,阳极,并且在发光层之间具有发光层,该发光层还包括在阴极和发光层之间的非发光电子传输层,其含有具有7,10 没有芳族环的二芳基取代的荧蒽核连接到荧蒽核上,并且期望还包含位于阴极和电子传输层之间的含有有机碱金属化合物的另外的层。 本发明的装置提供诸如效率,驱动电压和操作稳定性等特征的改进。

    Photographic element, compound, and process
    35.
    发明授权
    Photographic element, compound, and process 失效
    摄影元素,复合和过程

    公开(公告)号:US06689551B1

    公开(公告)日:2004-02-10

    申请号:US10325367

    申请日:2002-12-18

    IPC分类号: G03C146

    CPC分类号: G03C7/346 G03C7/38 G03C7/4136

    摘要: Disclosed is a photographic element comprising a light-sensitive silver halide emulsion layer having associated therewith a phenolic “NB magenta coupler” having the formula: wherein: the term “NB magenta coupler” represents a coupler of formula (I) that forms a magenta dye with the developer 4-amino-3-methyl-N-ethyl-N-(2-methanesulfonamidoethyl) aniline sesquisulfate hydrate for which the maximum absorption of the dye upon spin coating is in the range of from 520 to 590 nm and the left bandwidth (LBW) or the right bandwidth (RBW) using spin-coating, is at least 5 nm less than that of the same dye in solution form; R1 is a heterocyclic, carbocyclic, or alkenyl group with substituents of sufficient electron withdrawing capacity to obtain a spin-coated dye as described in the preceding subparagraph that exhibits a maximum absorption in the range of 520-590 nm; Y is H or a coupling-off group; each Z* is an independently selected substituent group where p is independently 0 to 2; R2 is a heterocyclic or carbocyclic ring group, or an alkyl group; provided that when R2 is an alkyl group with an &agr;-alkyl substituent, said &agr;-alkyl substituent is unbranched; and provided further that the combined sum of the aliphatic carbon atoms in R1, R2 and all Z* is at least 8.

    摘要翻译: 公开了一种包含感光卤化银乳剂层的照相元件,其具有下式的酚醛“NB品红色成色剂”:其中:术语“NB品红色成色剂”表示形成品红染料的式(I)的成色剂 与显影剂4-氨基-3-甲基-N-乙基-N-(2-甲磺酰氨基乙基)苯胺倍半硫酸盐水合物,旋涂时染料的最大吸收范围为520至590nm,左带宽 (LBW)或使用旋涂的正确带宽(RBW)比溶液形式的相同染料小至少5nm; R1是具有足够吸电能力的取代基的杂环,碳环或烯基,以获得 上述分段中所示的旋涂染料在520-590nm范围内具有最大吸收; Y为H或偶合离去基团;每个Z *为独立选择的取代基,其中p独立地为0至 2; R2是杂种 烷基或碳环基团或烷基;条件是当R 2为具有α-烷基取代基的烷基时,所述α-烷基取代基是未分支的; 并进一步提供R1,R2和全部Z *中的脂族碳原子的总和至少为8。

    Photographic element, compound, and process
    36.
    发明授权
    Photographic element, compound, and process 失效
    摄影元素,复合和过程

    公开(公告)号:US06562558B1

    公开(公告)日:2003-05-13

    申请号:US10021149

    申请日:2001-12-06

    IPC分类号: G03C108

    CPC分类号: G03C7/346

    摘要: Disclosed is a photographic element comprising a light-sensitive silver halide emulsion layer having associated therewith a cyan “NB coupler” having the formula (I): wherein: the term “NB coupler” represents a coupler of formula (I) that forms a dye for which the left bandwidth (LBW) using spin-coating is at least 5 nm less than that of the same dye in solution form; X is selected from O, NR* or S and R* is an alkyl, carbocyclic or heterocyclic group; L is a linking group and a is 0 or 1; Y is H or a coupling-off group; Z* is a substituent group and p is 0 to 2; and R1 and R2 are independently selected H or substituents; provided that the combined sum of the aliphatic carbon atoms in R1, R2, R*, L and all Z* is at least 8.

    摘要翻译: 公开了一种照相元件,其包含具有式(I)的青色“NB成色剂”的感光卤化银乳剂层:其中:术语“NB成色剂”表示形成染料的式(I)的成色剂 使用旋涂的左带宽(LBW)比溶液形式的相同染料少至少5nm; X选自O,NR *或S,R *是烷基,碳环或杂环基; L是连接基团,a是0或1; Y是H或偶合离去基团; Z *是取代基,p是0-2; 并且R 1和R 2独立地选自H或取代基;条件是R 1,R 2,R *,L和全部Z *中的脂族碳原子的总和为至少8。

    Photographic element, compound, and process
    37.
    发明授权
    Photographic element, compound, and process 失效
    摄影元素,复合和过程

    公开(公告)号:US06197490B1

    公开(公告)日:2001-03-06

    申请号:US09473335

    申请日:1999-12-28

    IPC分类号: G03C108

    CPC分类号: G03C7/346

    摘要: Disclosed is a photographic element comprising a light-sensitive silver halide emulsion layer having associated therewith a “NB coupler” having the formula (I): wherein the term “NB coupler” represents a coupler of formula (I) that forms a dye for which the left bandwidth (LBW) using spin-coating is at least 5 nm less than that of the same dye in solution form; Y is H or a coupling-off group; each Z″ and Z* is an independently selected substituent group where n is 0 to 5 and p is 0 to 2; W2 represents the atoms necessary to complete a carbocyclic or heterocyclic ring group; and V is a substituent group containing a sulfonamido group; provided that the combined sum of the aliphatic carbon atoms in V, all Z″ and all Z* is at least 8. The element provides a dye of improved hue.

    摘要翻译: 公开了一种照相元件,其包含感光卤化银乳剂层,其具有与其相关联的具有式(I)的“NB成色剂”:其中术语“NB成色剂”表示式(I)的成色剂,其形成染料, 使用旋涂的左带宽(LBW)比溶液形式的相同染料小至少5nm; Y是H或偶合离去基团;每个Z'和Z *是独立选择的取代基,其中n 为0〜5,p为0〜2; W2表示完成碳环或杂环基所必需的原子; 并且V是含有亚磺酰氨基的取代基;条件是V,所有Z“和全Z *中的脂族碳原子的总和为至少8.该元素提供改进的色调的染料。

    Cyan coupler, and stabilizer-containing photographic element and process
    38.
    发明授权
    Cyan coupler, and stabilizer-containing photographic element and process 有权
    青色耦合器和含稳定剂的照相元件和工艺

    公开(公告)号:US6132947A

    公开(公告)日:2000-10-17

    申请号:US266233

    申请日:1999-03-10

    摘要: Disclosed is a photographic element comprising at least one light sensitive silver halide emulsion layer having associated therewith: (A) a phenolic cyan dye-forming "NB coupler";(B) a high boiling solvent having Formula (II):R.sup.3 OO--C--(--G--)--C--OO--R.sup.4 (II) wherein:R.sup.3 and R.sup.4 represent independently selected alkyl or aryl groups; andG represents an alkyl (including cycloalkyl and aralkyl) containing linking group; and(C) a stabilizer having Formula (III): ##STR1## wherein each Y is an independently selected substituent and m is 0 to 4; andeach T is an independently selected substituent and p is 0 to 4.

    摘要翻译: 公开了一种照相元件,其包含至少一种与之相关的感光卤化银乳剂层:(A)形成苯酚青色染料的“NB偶联剂”; (B)具有式(II)的高沸点溶剂:R3OO-C - ( - G - ) - C-OO-R4(Ⅱ)其中:R3和R4代表独立选择的烷基或芳基; 和G表示含有连接基团的烷基(包括环烷基和芳烷基) 和(C)具有式(III)的稳定剂:其中每个Y是独立选择的取代基,m是0-4; 并且每个T是独立选择的取代基,p是0至4。

    Color photographic element containing oxidized developer-scavenging
naphtholic coupler forming wash-out dye
    40.
    发明授权
    Color photographic element containing oxidized developer-scavenging naphtholic coupler forming wash-out dye 失效
    含有氧化的显影剂清除的萘环成色剂形成洗出染料的彩色照相元件

    公开(公告)号:US5932407A

    公开(公告)日:1999-08-03

    申请号:US846910

    申请日:1997-04-30

    IPC分类号: G03C7/305 G03C7/392 G03C7/32

    摘要: A color photographic element comprising a film support and a first radiation-sensitive layer further includes an oxidized developer-scavenging naphtholic coupler that is substantially immobilized in the element but forms a dye that can be removed from the material during photographic processing. The naphtholic coupler, which comprises a dye-forming moiety and a ballasted, substantially photographically inert coupling-off moiety, has the structure ##STR1## where R.sup.1 and R.sup.2 each independently represents hydrogen, an alkyl group, an alkoxyalkyl group, or a hydroxyalkyl group, R.sup.1 and R.sup.2 together containing a total of up to 4 carbon atoms; R.sup.3 represents hydrogen, halo, or an alkoxy, an alkylcarbonamido, an alkylsulfonamido, a carbamoyl, or a sulfamoyl group containing up to 4 carbon atoms; R.sup.1, R.sup.2, and R.sup.3 of the dye-forming moiety are each devoid of alkali-solubilizing groups and together allow substantially complete removal during photographic processing of the dye formed by the naphtholic coupler; R.sup.4, R.sup.5 and R.sup.6 represent substituent groups that together comprise ballast sufficient to substantially immobilize the coupler in the color photographic element and together render the coupling-off moiety substantially photographically inert, at least one of R.sup.4, R.sup.5 and R.sup.6 comprises at least 8 carbon atoms; and R.sup.5 is selected from a group of substituent groups effective to substantially prevent formation of dye and/or stain by reaction of the coupling-off moiety with oxidized developer.

    摘要翻译: 包含薄膜载体和第一辐射敏感层的彩色照相元件还包括基本上固定在元件中的氧化的显影剂清除的萘酚成色剂,但形成可在照相处理过程中从材料中除去的染料。 包含染料形成部分和压实的基本上为摄影惰性的偶合离去部分的萘酚成色剂具有其中R 1和R 2各自独立地表示氢,烷基,烷氧基烷基或羟烷基的结构,R 1和 R2总共含有最多4个碳原子; R3表示氢,卤素或烷氧基,烷基碳酰氨基,烷基亚磺酰氨基,氨基甲酰基或含有至多4个碳原子的氨磺酰基; 染料形成部分的R 1,R 2和R 3各自没有碱增溶基团,并且在由萘鎓偶联剂形成的染料的照相处理期间一起允许基本上完全去除; R 4,R 5和R 6表示一起包含足以使成色剂基本上固定在彩色照相元件中并且一起使耦合部分基本上呈摄影惰性的压载物的取代基,R4,R5和R6中的至少一个包含至少8个碳原子 ; 并且R 5选自有效基本上防止偶联离子部分与氧化显影剂反应形成染料和/或着色的取代基组。