摘要:
The invention provides a photographic element comprising at least one light-sensitive silver halide emulsion layer having associated therewith: (A) a phenolic cyan dye-forming narrow bandwidth “NB coupler”; (B) a phenolic cyan dye-forming coupler of formula (II): wherein: R3 is an unsubstituted or substituted alkyl or aryl group or a 5-10 membered heterocyclic ring which contains one or more heteroatoms selected from nitrogen, oxygen and sulfur, which ring is unsubstituted or substituted; R4 is an unsubstituted or substituted alkyl group; R5 is hydrogen, halogen or an unsubstituted or substituted alkyl or aryl group or a 5-10 membered heterocyclic ring which contains one or more heteroatoms selected from nitrogen, oxygen and sulfur, which ring is unsubstituted or substituted; and Z is a hydrogen atom or a group which can be split off by the reaction of the coupler with an oxidized color-developing agent; and (C) a stabilizer of formula (III) wherein: each Y is an independently selected substituent and m is 0 to 4; and each T is an independently selected substituent and p is 0 to 4. Preferably the element has associated therewith one or more high-boiling solvents of formula (IV) wherein: R1 is an unsubstituted or substituted alkyl or aryl group; and G is an unsubstituted or substituted alkyl group.
摘要:
Disclosed is a photographic element comprising at least one light sensitive silver halide emulsion layer having associated therewith: (A) a phenolic cyan dye-forming "NB coupler";(B) a high boiling solvent having Formula (II):R.sup.3 OO--C--(--G--)--C--OO--R.sup.4 (II) wherein:R.sup.3 and R.sup.4 represent independently selected alkyl or aryl groups; andG represents an alkyl (including cycloalkyl and aralkyl) containing linking group; and(C) a stabilizer having Formula (III): ##STR1## wherein each Y is an independently selected substituent and m is 0 to 4; andeach T is an independently selected substituent and p is 0 to 4.
摘要:
Disclosed is a photographic element having a reduced rate of crystal formation comprising a silver halide emulsion layer having associated therewith:(a) a phenolic cyan dye-forming "NB coupler";(b) a first high boiling solvent having Formula (IV):G--C--OO--R.sup.1 (IV) wherein:R.sup.1 is an alkyl or aryl groups; andG is an alkyl (including cycloalkyl and aralkyl) containing linking group; and(c) one or more second high boiling solvents selected from phosphates, phosphonates, phosphine oxides, sulfoxides, and carbonamides, said second high boiling solvent being present in amounts (by weight) sufficient to reduce crystal formation in a dispersion of the coupler compared to a dispersion of the same coupler in a dispersion where the second solvent is replaced with a like amount of the first solvent.
摘要:
Loaded latex dispersions of hydrophobic photographically useful compounds with a wide variety of polymer latices are prepared by preparing an oil phase solution of the hydrophobic compound or compounds, preferably essentially free of water-miscible or volatile solvent, combining the oil solution with one or more aqueous solutions, at least one of which contains a polymer latex, and mixing the combination of oil solution, aqueous solution and latex under high shear or turbulence sufficient to cause loading of the photographically useful compound into the dispersed polymer latex wherein the pH of the mixture does not need to be significantly changed.
摘要:
Photographic elements comprising loaded latex compositions are prepared by (a) combining under conditions of low or moderate shear, in the presence of surfactant, and in the substantial absence of water-miscible or volatile organic solvents, a liquid organic composition comprising at least one photographically useful compound with an aqueous polymer latex, (b) holding the combination resulting from (a) in a liquid state for sufficient time for substantial loading of the organic coposition into the polymer latex to occur, and (c) coating the loaded latex resulting from (b) on a support.
摘要:
Silver halide light sensitive photographic elements are disclosed comprising a support bearing at least one yellow image forming hydrophilic colloid layer comprising a yellow dye-forming coupler and a trialkyl citrate coupler solvent of the formula C3H4(OH)(CO2R)3, where each R independently represents an alkyl group and the total number of carbon atoms for the three R groups combined is greater than 6. The combination of such citrate ester solvents with yellow dye forming couplers in photographic elements leads to both good reactivity and good image-dye light stability. The advantages of the invention are particularly useful for photographic color paper elements on reflective supports.
摘要翻译:公开了卤化银光敏感照相材料,其包括载体,该载体承载至少一个黄色图像形成亲水胶体层,其包含黄色染料形成成色剂和式C 3 H 4(OH)(CO 2 R)3的三烷基柠檬酸酯偶联剂溶剂,其中每个R独立地 代表烷基,并且三个R基团的总碳原子数大于6.这些柠檬酸酯溶剂与形成成色剂的黄色染料在照相元件中的组合导致良好的反应性和良好的图像染料光稳定性。 本发明的优点对于反射支撑件上的照相彩色纸元件特别有用。
摘要:
The present invention relates to a method of ordering images at an imaging device which permits a user to print images immediately, and simultaneously with the printing of the images, access further images for editing. The method of the present invention also provides a running account to the user as the user decides to print an image that details the cost of the jobs as they are being performed. Further, the system provides an ability to check the transaction cost versus the deposit for a fulfillment session and update the cost as the jobs are fulfilled.
摘要:
The present invention relates to a method of aligning comprising providing a support, applying a transparent layer, patterning at least the transparent layer to produce a pattern and an alignment feature capable of scattering light, illuminating the support and the transparent layer with oblique lighting, providing an analysis system capable of sensing scattered light from the alignment feature and referencing, sensing the scattered light from the alignment feature; referencing the scattered light from the alignment feature to a position on said support; and aligning a second operation to the position.
摘要:
The present invention relates to an imaging member comprising poultry gelatin. In one embodiment, the poultry gelatin is located preferably in at least one layer in the upper half of said imaging member comprising poultry gelatin. Another embodiment provides an aqueous coating composition comprising poultry gelatin.
摘要:
A process for making a direct dispersion of a photographically useful material is discloses comprising: mixing (i) an aqueous phase comprising a gelatin solution and (ii) a liquid organic phase comprising a photographically useful material under conditions of high shear or turbulence to form a fine dispersion of the organic phase having an average particle size of less than 0.5 micron dispersed in the aqueous phase; wherein the gelatin solution comprises a mixture of a first gelatin having an isoelectric point pH of less than or equal to 5.2 and a second gelatin having an isoelectric point pH of greater than or equal to 6.0. In accordance with the invention, the use of blends of a first gelatin having an pI of less than or equal to 5.2, such as a conventional lime processed gelatin, and a second gelatin having an pI of greater than or equal to 6.0, such as an acid processed gelatin, in a direct photographic dispersion yields a substantial reduction in viscosity in comparison to the use of the first gelatin alone, which reduction is greater than would be expected by just using blends of the first gelatin with another relatively low pI gelatin having an equivalent inherent viscosity as the second gelatin. In accordance with preferred embodiments of the invention, relatively low levels of APO gelatin may be used partially replacing LPO gelatin in a dispersion formulation to obtain significant viscosity reduction while minimizing adverse effects which may be associated with the use of higher levels of acid processed gelatin.