摘要:
The invention relates to the manufacture of manganese dioxide by a chemical process. The resulting manganese dioxide product takes the form of particles characterized by filament-like protrusions jutting out from its surface. The manganese dioxide particles having such surface features can be manufactured by reacting manganese sulfate with sodium peroxodisulfate in an aqueous solution. The process can be controlled to yield manganese dioxide of varying density and surface area. The manganese dioxide formed in the process can be deposited directly onto the surface of electrolytic manganese dioxide (EMD) or onto the surface of other particles. The manganese dioxide product is particularly suitable for use as a cathode active material in electrochemical cells.
摘要:
Heavy metal polysulfides which are insoluble in non-aqueous electrolytes and having the formula M.sub.x.sup.m (S.sub.y) .sub.z.sup.-2 (wherein M is a heavy metal such as iron, cobalt, copper or nickel; S is sulfer; mx=2z; and y is greater than two) are utilized as very high energy density cathodes in non-aqueous electrochemical cells.
摘要:
Novel electrolyte salts having high current carrying capability for non-aqueous electrochemical cells particularly those containing fluid depolarizer/electrolyte solvents. The salts have the general formula M(ZX.sub.4).sub.n with "M" being an alkali or alkaline earth metal, "Z" being gallium, .[.indium or thallium,.]. "X" being a halogen and "n" being either 1 or 2.
摘要:
A fluid cathode depolarized cell having a catalytic cathode comprised of a graphite intercalated metal halide such as CuCl.sub.2, CoCl.sub.2, FeCl.sub.3 and SbF.sub.5.
摘要:
A non-aqueous cell containing a corrosive fluid cathode depolarizer such as thionyl chloride (SOCl.sub.2) and a metal cathode such as of cold rolled steel which is substantially corroded by said fluid depolarizer with the cell having improved high rate discharge characteristics.
摘要:
Batteries are disclosed. In some embodiments, a battery includes a cathode having a composition that includes a manganese oxide. The composition has an X-ray diffraction pattern with a first peak at about 18 degrees, a second peak at about 22 degrees, and a third peak at about 32 degrees.
摘要:
A method of making a lithium electrochemical cell includes treating the cathode active material with an agent that includes lithium but not sodium. A cathode including the cathode active material, an anode, a separator, and an electrolyte are assembled in a housing to provide a cell containing less than 1500 ppm by weight of sodium.
摘要:
A lithium electrochemical cell includes an electrolyte having a mixture of solvents including propylene carbonate (PC) and dimethoxyethane (DME), and a salt mixture. The salt mixture includes lithium trifluoromethanesulfonate (LiTFS), and lithium trifluoromethanesulfonimide (LiTFSI), and the cell contains less than 1500 ppm by weight of sodium. The mixture of solvents can further include ethylene carbonate (EC).
摘要:
Disclosed is a process for treating manganese dioxide containing ion-exchangeable cations by replacing the ion-exchangeable cations present in the manganese dioxide with lithium by a process comprising first replacing ion-exchangeable cations present in the manganese dioxide with hydrogen. This readily is accomplished by slurrying the manganese dioxide in an aqueous acid solution. The resulting acidic manganese dioxide then is neutralized with a basic solution of a lithium containing compound, such as lithium hydroxide. This neutralization step serves to accomplish replacement of the previously introduced hydrogen, by ion-exchange, with lithium. The manganese dioxide then is washed with water, dried, and heat-treated at an elevated temperature, in conventional manner, to convert the gamma manganese dioxide to a mixture of the gamma and beta forms, which then is used as the active cathodic component in an electrochemical cell.
摘要:
The invention relates to the manufacture of manganese dioxide by a chemical process. The resulting manganese dioxide product takes the form of particles characterized by filament-like protrusions jutting out from its surface. The manganese dioxide particles having such surface features can be manufactured by reacting manganese sulfate with sodium peroxodisulfate in an aqueous solution. The process can be controlled to yield high density manganese dioxide. The manganese dioxide formed in the process can be deposited directly onto the surface of electrolytic manganese dioxide (EMD). The manganese dioxide product the is particularly suitable for use as a cathode active material in electrochemical cells.