公开(公告)号：US4001203A

公开(公告)日：1977-01-04

申请号：US459516

申请日：1974-04-10

Applicant: Gerhard Back ,  Alfred Fasciati

Inventor： Gerhard Back ,  Alfred Fasciati

IPC: C09B45/02 ,  C09B62/006 ,  C09B62/012 ,  C09B45/00

CPC classification number: C09B62/0067 ,  C09B45/025 ,  C09B62/012

Abstract: Heavy metal complexes can be prepared from azo compounds that contain a heterocyclic diazo component containing a complex-forming group such as hydroxyl, carboxyl, alkoxy or amino, or containing a hetero nitrogen atom able to form a coordinate bond, exemplified by quinolinyl and benzthiazolyl. The coupling component is 5-halogeno-2,3-dihydroxypyridyl where halogen is preferably chloro or bromo. The dyestuffs are useful, inter alia, for dyeing natural and synthetic polyamides such as wool and nylon. The dyeings obtained are uniform, are resistant to acid and alkali, are fast to light and to rubbing and barely change their appearance in artificial light.

Abstract translation: 重金属络合物可以由含有含有络合物形成基团如羟基，羧基，烷氧基或氨基的杂环重氮成分或含有能够形成配位键的杂氮原子的偶氮化合物制备，例如喹啉基和苯并噻唑基。 偶合组分是5-卤代-2,3-二羟基吡啶基，其中卤素优选为氯或溴。 该染料尤其用于染色天然和合成聚酰胺如羊毛和尼龙。 得到的染色均匀，耐酸碱，耐光，耐摩擦，在人造光线下几乎不改变其外观。

公开(公告)号：US3933785A

公开(公告)日：1976-01-20

申请号：US410748

申请日：1973-10-29

Applicant: Gerhard Back ,  Alfred Fasciati

Inventor： Gerhard Back ,  Alfred Fasciati

IPC: C09B45/00 ,  C09B62/012 ,  C09B45/18 ,  C09B45/48 ,  D06P1/10 ,  D06P3/02

CPC classification number: C09B45/00 ,  C09B62/012

Abstract: A mixed metal complex compound that contains for every atom of a trivalent metal one molecule of an azo or azomethine compound which contains a complex-forming group in the ortho, ortho'-positions to the azo or azomethine bridge, and one molecule of an azo or azomethine compound acting as trifunctional ligand which contains a complex-forming group in the ortho-position to the azo or azomethine bridge and contains two non-ionisable co-ordination positions. These mixed metal complexes dye nitrogenous fibers such as wool in level shades which are stable to acids and alkalis and have good fastness to light, rubbing, perspiration and water.

Abstract translation: 对于偶氮或偶氮甲碱化合物的三价金属一分子的每个原子，在偶氮或偶氮甲碱桥的邻位，邻位上含有络合物形成基团和一个偶氮分子的混合金属络合物 或作为三官能配体的偶氮甲碱化合物，其在偶氮或偶氮甲碱桥的邻位含有络合物形成基团，并含有两个不可离子化的配位位置。 这些混合金属配合物在酸性和碱性稳定的水平色调中染色诸如羊毛的含氮纤维，并具有良好的耐光牢度，耐擦拭性，出汗性和耐水性。