摘要:
A light-emitting device comprising: a pair of electrodes formed on a substrate; and organic compound layers provided in between the electrodes, wherein the organic compound layers comprises a light-emitting layer comprising a hole-transporting material and a phosphorescent compound and an electron-transporting layer comprising an electron-transporting material, and an ionization potential of the electron-transporting material is 5.9 eV or more or wherein the organic compound layers comprises a hole-transporting layer comprising a hole-transporting material, a light-emitting layer comprising a phosphorescent compound and an electron-transporting layer comprising an electron-transporting material, and an ionization potential of the electron-transporting material is 5.9 eV or more.
摘要:
Photographic processing using an additive represented by formula (I): ##STR1## wherein R.sub.1 is an aliphatic hydrocarbon group, an aryl group, or a heterocyclic ring group; R.sub.2 is hydrogen, an aliphatic hydrocarbon group, an aryl group, or a heterocyclic ring group; L.sub.1, L.sub.2, L.sub.3, L.sub.4 and L.sub.5 are independently an alkylene group; m and n are independently 0 or 1; W.sup.1 and W.sup.2 are independently an alkylene group, an arylene group, aralkylene group or a divalent nitrogen-containing heterocyclic ring group; D is a single bond, --O--, --S-- or --N(R.sub.w), where R.sub.2 is hydrogen, an aliphatic hydrocarbon group or an aryl group; v is 0 or an integer or from 1 to 3; w is an integer of from 1 to 3; and M.sub.1, M.sub.2, M.sub.3 and M.sub.4 are independently hydrogen or a cation.
摘要:
A method of processing a silver halide color photographic material using a carbamoyl or imidazole type organic metal complex bleaching agent of any of compounds of formulae (I), (II), (III), (IV), and (V) and a mercapto, mesoionic or thioether fixing agent of compounds of formulae (A), (B) and (C). A bleach-fixing composition containing the bleaching agent and fixing agent is also disclosed. The processing method provides good desilvering with little bleach fogging of the processed photographic material, and the processing composition has good stability. W in formula (III) below represents a divalent linking group. ##STR1##
摘要:
A composition for the processing of a silver halide color photographic material, which comprises at least one metal chelate compound formed of a salt of metal selected from the group consisting of Fe(III), Mn(III), Co(III), Rh(II), Rh(III), Au(III), Au(II) and Ce(IV) and a compound represented by the general formula (I): ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.a, R.sub.b, and R.sub.c each represent a hydrogen atom, an aliphatic group or an aromatic group; R.sub.5 and R.sub.6 each represents a hydrogen atom, an aliphatic group, an aromatic group, a halogen atom, a cyano group, a nitro group, an acyl group a sulfamoyl group, a carbamoyl group, an alkoxycarbonyl group, an aryloxycarbonyl group, a sulfonyl group or a sulfinyl group, or R.sub.5 and R.sub.6 together may form a 5- or 6-membered ring; L.sub.1 represents a divalent aliphatic or aromatic group or a divalent linking group containing at least one of them; A.sub.1 represents a carboxyl group, a phosphono group, a sulfo group, a hydroxyl group, or a substituted group thereof (acidic group only) with an alkali metal atom; and t and u each represents an integer 0 or 1; provided that when R.sub.5 and R.sub.6 together form a 5- or 6-membered ring, R.sub.1, R.sub.2, R.sub.3 and R.sub.4 each does not present an aromatic ring, and when R.sub.5 and R.sub.6 together form a benzene ring, at least one of t and u represents 1, and a process for the processing of a silver halide color photographic material with the processing composition.
摘要:
A silver halide photographic material is disclosed, which has at least one compound represented general formula (1): ##STR1## wherein R represents an aliphatic group, an aromatic group, or a heterocyclic group; both L and Time represent a divalent organic group; t represents 0 or 1; PUG represents a photographically useful group; Y represents --SO.sub.2 --, --Y'--SO.sub.2 --, or ##STR2## and Y' represents --O--, --NH--, or ##STR3## The material has a broad exposure latitude in line image-taking work and has a high resolving power in the work. It can form an ultrahard image having a high gamma value of 10 or more. The material may excellently reproduce a line original to form an ultrahard image having a high background density. It also has a broad exposure latitude in halftone dot image-taking work and can form a halftone dot image having ultrahigh contrast with high image quality.
摘要:
A silver halide photographic material comprising one or more silver halide emulsion layers and hydrophilic colloid layers, wherein at least one of the layers contains an acylhydrazine compound as described below. The instant photographic materials have high contrast negative-gradation or positive-gradation characteristics, high maximum image density, excellent reversal characteristics and long-term storage stability.
摘要:
A silver halide photographic material comprising at least one compound represented by formula (I): ##STR1## wherein X represents a hydrogen atom or a group which can become a hydrogen atom by hydrolytic action, Time represents a divalent connecting group, t represents 0 or 1, PUG represents a development inhibitor, V represents a carbonyl group, ##STR2## a sulfonyl group, a sulfoxy group, ##STR3## (R.sub.0 represents an alkoxy group or an aryloxy group), an iminomethylene group, a thiocarbonyl group or ##STR4## (W represents an electron attractive group), R represents a hydrogen atom, a substituted or unsubstituted aliphatic group, a substituted or unsubstituted aromatic group, or ##STR5## (PUG, Time, t and W are as defined above); and at least one compound represented by formula (II): ##STR6## wherein R.sub.1 represents a substituted or unsubstituted aliphatic group or a substituted or unsubstituted aromatic group, R.sub.2 represents a hydrogen atom, an alkyl group, an aryl group, an alkoxy group, an aryloxy group, an amino group, a hydrazino group, a carbamoyl group or an oxycarbonyl group, each of which may be substituted, G.sub.1 represents a carbonyl group, a sulfonyl group, a sulfoxy group, ##STR7## a thiocarbonyl group, or an iminomethylene group, A.sub.1 and A.sub.2 each represents a hydrogen atom, or one of A.sub.1 and A.sub.2 represents a hydrogen atom while the other represents a substituted or unsubstituted alkylsulfonyl group, a substituted or unsubstituted arylsulfonyl group, or a substituted or unsubstituted acyl group.
摘要:
A silver halide photographic material is disclosed, comprising a support having thereon at least one of silver halide photographic emulsion layers and other hydrophilic colloidal layers, wherein said photographic emulsion layers or other hydrophilic colloidal layers contain a hydrazine compound represented by formula (I): ##STR1## wherein at least one of A.sub.1 and A.sub.2 represents a hydrogen atom and the other represents a hydrogen atom, a sulfonyl group or an acyl group; R.sub.1 represents an aliphatic, group, an aromatic group, or a heterocyclic group; Y.sub.1 represents a divalent organic group; G.sub.1 represents a carbonyl group, a sulfonyl group, a sulfoxy group, ##STR2## wherein R.sub.2 represents an alkoxy group or an aryloxy group, ##STR3## or an iminomethylene group; Z.sub.1 represents a group suitable for making a nucleophilic attack on G.sub.1 to separate the G.sub.1 --L.sub.1 --Z.sub.1 from the rest of the molecule; and L.sub.1 represents a divalent organic group suitable for producing a cyclic structure with G.sub.1 and Z.sub.1 upon nucleophilic attack by Z.sub.1 on G.sub.1.
摘要翻译:公开了一种卤化银照相材料,其包括其上具有卤化银照相乳剂层和其它亲水性胶体层中的至少一种的载体,其中所述照相乳剂层或其它亲水性胶体层含有式(I)表示的肼化合物: (I)其中A1和A2中的至少一个表示氢原子,另一个表示氢原子,磺酰基或酰基; R1表示脂肪族,基团,芳香族基团或杂环基团; Y1表示二价有机基团; G 1表示羰基,磺酰基,磺酰氧基,其中R 2表示烷氧基或芳氧基,或者亚氨基亚甲基。 Z1表示适合于对G1进行亲核攻击以将G1-L1-Z1与其余分子分离的基团; L1表示适合于通过在G1上的Z1亲核攻击时产生具有G1和Z1的环状结构的二价有机基团。
摘要:
A silver halide photographic material capable of providing very high contrast image and having improved safelight safety is described, which comprises a support having thereon at least one silver halide emulsion layer, and containing in the silver halide emulsion layer or another hydrophilic colloid layer (i) a compound represented by formula (I) ##STR1## wherein PWR represents a group capable of releasing ##STR2## upon being reduced; Time represents a group capable of releasing LA after being released from PWR, t is 0 or 1; and LA represents a group having an absorption maximum in the wavelength region longer than 310 nm, (ii) a hydrazine derivative, and (iii) at least one compound represented by formulae (IX) and (X) ##STR3## wherein R.sup.91, R.sup.92, R.sup.93, and R.sup.94, which may be the same or different, each represents hydrogen, an alkyl group, an aryl group, an amino group, a hydroxyl group, an alkoxy group, an alkylthio group, a carbamoyl group, a halogen atom, a cyano group, a carboxyl group, an alkoxycarbonyl group or a heterocyclic group and R.sup.91 and R.sup.92 or R.sup.92 and R.sup.93 may be linked to form a 5- or 6-membered ring; provided that at least one of R.sup.91 and R.sup.93 represents a hydroxyl group.
摘要:
The present invention relates to a direct positive silver halide photosensitive material and a method for forming a direct positive image. By the use of a novel nucleating agent having a specific structural formula, the present invention provides a direct positive silver halide photosensitive material with an increased Dmax value and a decreased Dmin value, as compared with the use of the conventional nucleating agents, even if a small amount of the novel nucleating agent is used, and does not substantially reduce the Dmax value, even if the photosensitive material is kept in a high-humidity state for a long time before exposure.