公开(公告)号：US07732124B2

公开(公告)日：2010-06-08

申请号：US12292528

申请日：2008-11-20

申请人： Yasuaki Deguchi ,  Shin Soejima ,  Naoto Ohshima ,  Tatsuya Ishizaka ,  Katsuyuki Takada ,  Futoshi Yoshida ,  Atsushi Maruhashi ,  Yoshinori Morimoto ,  Takehisa Ohno

发明人： Yasuaki Deguchi ,  Shin Soejima ,  Naoto Ohshima ,  Tatsuya Ishizaka ,  Katsuyuki Takada ,  Futoshi Yoshida ,  Atsushi Maruhashi ,  Yoshinori Morimoto ,  Takehisa Ohno

IPC分类号： G03C7/26 ,  G03C7/36 ,  G03C7/42 ,  G03C1/08 ,  G03C1/06

CPC分类号： G03C5/04 ,  G03C1/09 ,  G03C1/16 ,  G03C1/30 ,  G03C7/3022 ,  G03C7/3225 ,  G03C7/346 ,  G03C7/3825 ,  G03C7/3926 ,  G03C7/407 ,  G03C2001/03517 ,  G03C2001/03535 ,  G03C2001/093 ,  G03C2001/096 ,  G03C2007/3025 ,  G03C2200/52 ,  G03C2200/60

摘要： A color-image forming method in a silver halide color photographic light-sensitive material, having the steps of: performing exposure of the light-sensitive material cut into sheets; and subjecting the exposed light-sensitive material sheets to photographic processing, while conveying them with conveying rollers, with the sheet conveying speed being 40.0 to 100 mm/sec; wherein the light-sensitive material to be exposed contains any of: 1) a dye-forming coupler of formula (IA), 2) a compound of formula (I), and 3) 1.4 mg/m2 or more of a compound of formula (II); wherein R′ and R″ are a substituent; Z is a hydrogen atom, or a coupling split-off group; A is an alkyl group, M is a cation, and R is an atom or group having 100 or lower total molecular weight.

摘要翻译： 一种卤化银彩色摄影感光材料中的彩色图像形成方法，具有以下步骤：对切割成片材的感光材料进行曝光; 并在曝光的感光材料片材进行照相处理，同时用输送辊输送它们，片材输送速度为40.0至100mm /秒; 其中要曝光的感光材料包含以下任何一种：1）式（IA）的染料形成成色剂，2）式（I）化合物和3）1.4mg / m 2或更多的式 （二）; 其中R'和R“是取代基; Z是氢原子或偶联分离基; A是烷基，M是阳离子，R是具有100个或更低总分子量的原子或基团。

公开(公告)号：US07135275B2

公开(公告)日：2006-11-14

申请号：US10920275

申请日：2004-08-18

申请人： Kazuaki Yoshida

发明人： Kazuaki Yoshida

IPC分类号： G03C7/42

CPC分类号： G03C7/44 ,  G03C5/265 ,  G03C7/42 ,  G03C2200/40

摘要： A solid bleach-fixing composition for a silver halide color photographic light-sensitive material, comprising at least one specific 5-membered heterocyclic azoliumthiolate compound, particularly, a solid bleach-fixing composition wherein the specific thiolate compound is a diazolium-thiolate compound substituted by a water-soluble group. A method for processing a silver halide color photographic light-sensitive material, comprising using a bleach-fixing solution containing a specific 5-membered heterocyclic azoliumthiolate compound, and regenerating at least 50 mass % of the used bleach-fixing solution as a bleach-fixing processing agent for replenishment; and a method for processing a silver halide color photographic light-sensitive material, comprising regenerating at least 30 mass % of the used processing solution further containing used rinsing solution as a bleach-fixing processing agent for replenishment.

摘要翻译： 一种用于卤化银彩色照相感光材料的固体漂白剂定影组合物，其包含至少一种特定的5元杂环唑硫醇盐化合物，特别是固体漂白剂固定组合物，其中特定硫醇化合物是被噻唑鎓硫醇化合物取代的固体漂白剂 水溶性基团。 一种用于处理卤化银彩色照相感光材料的方法，包括使用含有特定5元杂环硫代硫醇化合物的漂白剂固定溶液，再生至少50质量％的使用的漂白剂定影液作为漂白剂固定 加料处理剂; 以及用于处理卤化银彩色照相感光材料的方法，包括再生至少30质量％的使用的处理溶液，其进一步含有用作补充剂的漂白剂固定处理剂的用过的漂洗溶液。

公开(公告)号：US07108962B2

公开(公告)日：2006-09-19

申请号：US10349918

申请日：2003-01-24

申请人： Makoto Suzuki ,  Yasufimi Nakai

发明人： Makoto Suzuki ,  Yasufimi Nakai

IPC分类号： G03C7/413 ,  G03C7/42

CPC分类号： G03C7/3046 ,  G03C5/268 ,  G03C5/30 ,  G03C5/31 ,  G03C5/38 ,  G03C5/395 ,  G03C7/413 ,  G03C7/42 ,  G03C7/44 ,  Y10S430/134

摘要： A photographic processing composition, containing at least one compound of formula (I) or (II): A1-X-L-Y-A2  (I) wherein A1 and A2 each are a specific aryl or aromatic heterocyclic group; L is a specific arylene or divalent aromatic heterocyclic group; X and Y each are a specific divalent group; the compound of (I) contains at least two of —SO3M or —CO2M, but not contains —N═N— or —SH; M is a hydrogen, alkali or alkali earth metal, ammonium, or pyridinium; wherein A11 is a specific tri- or tetra-valent aromatic hydrocarbon or aromatic heterocyclic group; A12 is an aryl or aromatic heterocyclic group; X1 is a divalent group; M1 is a hydrogen, alkali or alkali earth metal, ammonium, or pyridinium; the molecule of (II) does not contain —N═N— or —SH; n is 3 or 4; r and s each are 0 to 10, (r+s) is 2 or more.

摘要翻译： 含有至少一种式（I）或（II）化合物的照相处理组合物：<？in-line-formula description =“In-line Formulas”end =“lead”？> A <1 > -XLYA <2>（I）<？in-line-formula description =“In-line Formulas”end =“tail”？>其中A <1>＆lt; SUB > 2 各自是特定的芳基或芳族杂环基; L是特定的亚芳基或二价芳族杂环基; X和Y各自是特定的二价基团; （I）的化合物包含至少两个-SO 3 M或-CO 2 M，但不包含-N-N-或-SH; M是氢，碱金属或碱土金属，铵或吡啶; 其中A 11是特定的三价或四价芳族烃或芳族杂环基; A 12是芳基或芳族杂环基; X 1是二价基团; M 1是氢，碱金属或碱土金属，铵或吡啶; （II）的分子不含有-N-N-或-SH; n为3或4; r和s分别为0〜10，（r + s）为2以上。

公开(公告)号：US06890706B2

公开(公告)日：2005-05-10

申请号：US10301226

申请日：2002-11-20

申请人： Christophe Bulliard ,  Georges Metzger ,  Sonia Megert

发明人： Christophe Bulliard ,  Georges Metzger ,  Sonia Megert

IPC分类号： G03C7/00 ,  C07D251/68 ,  G03C1/775 ,  G03C1/79 ,  G03C1/815 ,  G03C5/305 ,  G03C7/30 ,  G03C7/407 ,  G03C7/413 ,  G03C7/42 ,  G03C11/00

CPC分类号： G03C7/413 ,  G03C1/775 ,  G03C1/815 ,  G03C1/8155 ,  G03C5/305 ,  G03C7/421 ,  Y10S430/134

摘要： A process for removing stain in a photographic material is described which process comprises incorporation of at least one compound of the formula (I) wherein X is O or NH; n is 1 or 2, p is 0, 1 or 2, M is hydrogen, an alkali metal atom, ammonium or a cation formed from an amine; each R1, independently, is an aminoacid residue from which a hydrogen atom on the amino group has been removed; each R2, independently, is hydrogen, C1-C8alkyl, C1-C8alkoxy, halogen, cyano, COOR, wherein R is hydrogen or C1-C3alkyl, CONH—R in which R has its previous significance, SO2NH—R in which R has its previous significance, NH—COR in which R has its previous significance, or SO3M, wherein M has its previous significance, or, if n is 1, R2 can also be CO—R3 in which R3 is C1-C3alkyl or phenyl, in that photographic material.

摘要翻译： 描述了去除照相材料中污点的方法，该方法包括加入至少一种其中X为O或NH的式（I）化合物; n为1或2，p为0,1或2，M为氢，由胺形成的碱金属原子，铵或阳离子; 每个R 1独立地是氨基上的氢原子被除去的氨基酸残基; 每个R 2独立地是氢，C 1 -C 8烷基，C 1 -C 3 烷氧基，卤素，氰基，COOR，其中R是氢或C 1 -C 3烷基，其中R具有其先前含义的CONH-R ，其中R具有其先前含义的SO 2 NH-R，其中R具有其先前含义的NH-COR，或其中M具有其先前的含义 ，或者如果n是1，R 2也可以是其中R 3是C 1 H 2的CO-R 3， 在这种照相材料中，C 1 -C 3烷基或苯基。

公开(公告)号：US6136516A

公开(公告)日：2000-10-24

申请号：US320038

申请日：1999-05-26

申请人： Thomas Fogel ,  Jurgen Gohmann ,  Norman Klaunzer

发明人： Thomas Fogel ,  Jurgen Gohmann ,  Norman Klaunzer

IPC分类号： G03C7/30 ,  G03C7/42

CPC分类号： G03C7/3046 ,  G03C7/42 ,  Y10S430/144

摘要： A process for processing exposed photographic silver halide materials at least comprising the stages color development, stopping, bleaching and fixing using a bleaching bath with hydrogen peroxide as the active substance, characterized in that the stop bath contains as a buffer agent at least one carboxylic acid of the formulae I to VIII ##STR1## in which R.sub.1 to R.sub.5 mutually independently mean hydrogen, --OH, --COOM, --SO.sub.3 M, --PO(OM).sub.2, an optionally substituted alkyl residue, an optionally substituted aryl residue, an optionally substituted amino residue or a heterocyclic residue andM means hydrogen or an alkali metal atom and wherein at least one further acid group is present in the molecule, ##STR2## and at least one agent which stops development, is distinguished by improved bleaching action and the use of an environmentally friendly bleaching bath.

摘要翻译： 一种处理暴露的照相卤化银材料的方法，其至少包括使用过氧化氢作为活性物质的漂白浴来进行彩色显影，停止，漂白和定影，其特征在于，停止浴含有缓冲剂至少一种羧酸 其中R 1至R 5相互独立地表示氢，-OH，-COOM，-SO3M，-PO（OM）2，任选取代的烷基残基，任选取代的芳基，任选取代的氨基残基或 杂环残基，M表示氢或碱金属原子，其中至少一个其它酸基存在于分子中，并且至少一种停止显影的试剂通过改善漂白作用和使用环境友好的漂白浴来区分 。

公开(公告)号：US6063553A

公开(公告)日：2000-05-16

申请号：US994770

申请日：1997-12-19

申请人： Adrian J. Codling ,  John R. Fyson

发明人： Adrian J. Codling ,  John R. Fyson

IPC分类号： G03C7/32 ,  G03C7/30 ,  G03C7/407 ,  G03C7/42 ,  G03C7/14

CPC分类号： G03C7/3003 ,  G03C7/3017 ,  G03C7/42 ,  G03C7/3022 ,  G03C7/32 ,  G03C7/3225 ,  Y10S430/144

摘要： A photographic recording material for use in redox amplification comprises a support having thereon a plurality of emulsion layers, each emulsion layer containing a color-forming coupler, and wherein the activity of the couplers is from 45 to 70% as measured by the citrazinic acid method. These materials may be developed by a redox development step which may be followed by a bleach-fix step without any intervening step. Staining is eliminated with the use of these photographic materials.

公开(公告)号：US6022673A

公开(公告)日：2000-02-08

申请号：US99674

申请日：1998-06-18

申请人： Shun-ichi Ishikawa

发明人： Shun-ichi Ishikawa

IPC分类号： G03C7/00 ,  G03C1/42 ,  G03C1/498 ,  G03C5/26 ,  G03C7/392 ,  G03C7/407 ,  G03C7/42

CPC分类号： G03C7/407 ,  G03C1/42 ,  G03C1/49845 ,  G03C2200/21 ,  G03C5/261 ,  G03C8/4086

摘要： An image formation method in which a photosensitive element is exposed in image-wise fashion, then, a first treating element comprising a treating layer comprising a base and/or base precursor is prepared, this first treating element is laminated on the photosensitive element so that the treating layer of the first treating element faces the photosensitive layer of the photosensitive element and the resultant laminate is heated for 5 to 60 seconds at a temperature of 60 to 100.degree. C. in the presence of water in an amount of 1 cc/m.sup.2 to 50 cc/m.sup.2 between the photosensitive layer of the photosensitive element and the treating layer of the first treating element. Then the photosensitive element is separated from the first treating member. Then a second treating element comprising a support carrying thereon a treating layer comprising at least an acidic polymer is prepared. This second treating element is laminated on the photosensitive element so that the treating layer of the second treating element faces the photosensitive layer of the photosensitive element and the resultant laminate is heated for 2 to 60 seconds at a temperature of 40 to 100.degree. C. in the presence of water in an amount of 1 cc/m.sup.2 to 50 cc/m.sup.2 between the photosensitive layer of the photosensitive element and the treating layer of the second treating element. Then the photosensitive material is separated from the second treating element, to form an image on the photosensitive element.

摘要翻译： 一种图像形成方法，其中感光元件以成像方式曝光，然后制备包括基底和/或基底前体的处理层的第一处理元件，该第一处理元件层压在感光元件上，使得 第一处理元件的处理层面向感光元件的感光层，并且所得到的层压体在60-100℃的温度下在水的存在下以1cc / m 2的量加热5至60秒 在感光元件的感光层和第一处理元件的处理层之间为50cc / m 2。 然后感光元件与第一处理构件分离。 然后制备第二处理元件，其包括承载有至少包含酸性聚合物的处理层的载体。 将第二处理元件层压在感光元件上，使得第二处理元件的处理层面对感光元件的感光层，并将所得层压体在40至100℃的温度下加热2至60秒钟 在感光元件的感光层和第二处理元件的处理层之间存在1cc / m 2至50cc / m 2的量的水。 然后感光材料与第二处理元件分离，以在感光元件上形成图像。

公开(公告)号：US06007972A

公开(公告)日：1999-12-28

申请号：US250943

申请日：1999-02-16

申请人： Eric R. Schmittou ,  David G. Foster

发明人： Eric R. Schmittou ,  David G. Foster

IPC分类号： G03C5/38 ,  G03C7/42

CPC分类号： G03C7/421

摘要： Color photographic silver halide elements, such as color films, can be rapidly fixed using a fixing composition containing a thiosulfate fixing agent, and certain sulfur-substituted oxadiazoles (that is oxadiazolethiones). Each of the components is present in specific amounts to effect rapid and efficient desilvering. The composition also includes predominantly ammonium cations (at least 50 mol %). Besides effective and rapid silver removal (less than 60 seconds), the fixing composition also minimizes residual dye stain from sensitizing dye aggregates within the photographic elements.

摘要翻译： 可以使用含有硫代硫酸盐固定剂和某些硫取代的恶二唑（即恶二唑硫杂）的固定组合物快速固定彩色照相卤化银元素，如彩色胶片。 每个组分以特定的量存在以实现快速和有效的脱银。 该组合物还主要包括铵阳离子（至少50mol％）。 除了有效和快速的银清除（少于60秒）之外，定影组合物还使得在感光元件内致敏染料聚集体的残留染料染色最小化。

公开(公告)号：US6004731A

公开(公告)日：1999-12-21

申请号：US643607

申请日：1996-05-06

申请人： Hiroshi Hayashi ,  Tetsuro Kojima ,  Shinichi Ichikawa

发明人： Hiroshi Hayashi ,  Tetsuro Kojima ,  Shinichi Ichikawa

IPC分类号： G03C7/30 ,  G03C7/407 ,  G03C7/42

CPC分类号： G03C7/421 ,  G03C7/3022 ,  G03C7/407

摘要： A method for processing a silver halide color photographic light-sensitive material comprising a support having thereon at least one light-sensitive silver halide emulsion layer, the method comprising the steps of: exposing the light-sensitive material; color developing the light-sensitive material; and desilvering the light-sensitive material, the desilvering step comprising processing the light-sensitive material with a desilvering processing solution containing at least one compound represented by formula (I) or a salt thereof: ##STR1## wherein Z represents --NR.sub.5 (R.sub.6) or --OR.sub.7, R represents an alkylene group, n represents 0 or 1, R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5 and R.sub.6 each independently represents a hydrogen atom, an aliphatic group or an aromatic group, and R.sub.7 represents an aliphatic group or an aromatic group, provided that any two of R.sub.1, R.sub.2, R.sub.3 and R.sub.4 may be combined with each other to form a ring, that the total carbon number of R.sub.5 and R.sub.6 is from 4 to 20 and that R.sub.5 and R.sub.6 may form a ring.

摘要翻译： 一种用于处理卤化银彩色照相感光材料的方法，其包括其上具有至少一个感光卤化银乳剂层的载体，所述方法包括以下步骤：使感光材料曝光; 彩色显影感光材料; 脱银步骤包括用含有至少一种由式（I）表示的化合物或其盐的脱溶剂处理溶液处理感光材料：其中Z表示-NR5（R6）或-OR7 ，R表示亚烷基，n表示0或1，R1，R2，R3，R4，R5和R6各自独立地表示氢原子，脂族基团或芳香族基团，R7表示脂肪族基团或芳香族基团， 条件是R 1，R 2，R 3和R 4中的任何两个可以彼此结合形成环，R 5和R 6的总碳数为4至20，并且R 5和R 6可以形成环。

公开(公告)号：US5972579A

公开(公告)日：1999-10-26

申请号：US206585

申请日：1998-12-07

申请人： Sidney J. Bertucci ,  Eric R. Schmittou

发明人： Sidney J. Bertucci ,  Eric R. Schmittou

IPC分类号： G03C1/005 ,  G03C5/44 ,  G03C7/30 ,  G03C7/42

CPC分类号： G03C7/3046 ,  G03C7/42 ,  G03C1/0053 ,  G03C5/44 ,  G03C7/421

摘要： Color photographic elements are processed with an acidic periodate bleaching composition that may also include chloride ions as a rehalogenating agent. Bleaching is carried out after color development is stopped with an acidic stop bath. The processing method provides relatively rapid bleaching without physical defects such as blistering or vesiculation.

摘要翻译： 用酸性高碘酸盐漂白组合物处理彩色照相元件，其也可以包括作为再卤化剂的氯离子。 漂白是在酸性停止浴停止显色后进行的。 处理方法提供相对快速的漂白而没有诸如起泡或泡沫的物理缺陷。