公开(公告)号：US4968588A

公开(公告)日：1990-11-06

申请号：US404480

申请日：1989-09-08

申请人： Takatoshi Ishikawa ,  Morio Yagihara

发明人： Takatoshi Ishikawa ,  Morio Yagihara

IPC分类号： G03C7/413

CPC分类号： G03C7/413

摘要： A method for processing a silver halide color photographic material is described, which comprises processing a silver halide color photographic material comprising a reflective support having thereon at least one silver halide emulsion layer for a period of 2 minutes and 30 seconds or less with a color devleoping solution which does not substantially contain benzyl alcohol and which contains at least one of compounds selected from the group consisting of a compound represented by formula (I), a compound represented by formula (II), hydantoic acid, allylamine, aminoguanidine, o-aminobenzoic acid, L-(+)-cysteine, benzylamine, DL-serine, morpholine, N-hydroxyethyl morpholine, o-aminobenzyl alcohol, quinuclidine, or salts thereof, tetramethylammonium acetate, choline, or choline chloride, ##STR1## wherein R.sup.1 represents a hydroxyalkyl group having from 2 to 10 carbon atoms; and R.sup.2 and R.sup.3 each represents a hydrogen atom, an alkyl group having from 1 to 10 carbon atoms, a hydroxyalkyl group having from 2 to 20 carbon atoms or a group represented by the formula ##STR2## wherein n represents an integer from 1 to 10; and X and Y each represents a hydrogen atom, an alkyl group having from 1 to 10 carbon atoms, or a hydroxyalkyl group having from 2 to 10 carbon atoms. ##STR3## wherein R.sup.4 represents an alkyl group having from 1 to 10 carbon atoms; R.sup.5 and R.sup.6 each represents a hydrogen atom or an alkyl group having from 1 to 10 carbon atoms.In accordance with this method for processing a silver halide color photographic material, color images having high coloring property can be obtained within a short period of a color developing time without substantially using benzyl alcohol, which is disadvantageous in view of environmental pollution, in the color developing solution.The effect of the present invention is particularly remarkable in the case wherein the silver halide color photographic material contains a pyrazoloazole type magenta coupler represented by formula (III) as described in the specification.

公开(公告)号：USH809H

公开(公告)日：1990-08-07

申请号：US299487

申请日：1989-01-23

申请人： Kazuto Andoh ,  Takatoshi Ishikawa ,  Hiroshi Fujimoto ,  Morio Yagihara

发明人： Kazuto Andoh ,  Takatoshi Ishikawa ,  Hiroshi Fujimoto ,  Morio Yagihara

IPC分类号： G03C7/30 ,  G03C7/305 ,  G03C7/38 ,  G03C7/407 ,  G03C7/413

CPC分类号： G03C7/413 ,  G03C7/30529 ,  G03C7/3825

摘要： A method for processing a silver halide color photographic material containing at least one pyrazoloazole magenta coupler represented by general formula (I), which comprises processing the light-sensitive material, after imagewise exposure, with a color developer containing an aromatic primary amine color developing agent and at least one member selected from among hydrazines and hydrazides represented by general formula (II): ##STR1## wherein R.sub.11 represents a hydrogen atom or a substituent, X represents a hydrogen atom or a group capable of being eliminated by a coupling reaction with an oxidation product of an aromatic primary amine developing agent, Za, Zb and Zc each represents a methine group, a substituted methine group, .dbd.N-- or --NH--, provided that one of the Za-Zb bond and the Zb-Zc bond is a double bond and the other is a single bond and, when Zb-Zc is a carbon-to-carbon double bond, it may be a part of an aromatic ring, and a dimer or higher polymer may be formed at R.sub.11 or X, or, when Za, Zb or Zc represents a substituted methine group, a dimer or higher polymer may be formed at the substituted methine group; ##STR2## wherein R.sup.1, R.sup.2 and R.sup.3 each independently represents a hydrogen atom, an alkyl group, an aryl group or a meterocyclic group, R.sup.4 represents a hydrogen atom, a hydroxy group, a hydrazino group, an alkyl group, an aryl group, a heterocyclic group, an alkoxy group, an aryloxy group, a carbamoyl group or an amino group, X.sup.1 represents a divalent group, and n represents 0 to 1, provided that, when n is 0, R.sup.4 represents an alkyl group, an aryl group or a heterocyclic group, and that R.sup.3 and R.sup.4 may together form a heterocyclic ring.

公开(公告)号：US4920029A

公开(公告)日：1990-04-24

申请号：US235805

申请日：1988-08-23

申请人： Nobuaki Inoue ,  Senzo Sasaoka ,  Yoshio Inagaki ,  Tetsuro Kojima ,  Morio Yagihara

发明人： Nobuaki Inoue ,  Senzo Sasaoka ,  Yoshio Inagaki ,  Tetsuro Kojima ,  Morio Yagihara

IPC分类号： G03C5/29 ,  G03C1/06

CPC分类号： G03C1/061 ,  Y10S430/15

摘要： A negative type silver halide photographic material and a process for forming a super high contrast negative image using said material are described. This photographic material comprises a support having provided thereon at least one silver halide emulsion layer which has a substantial influence upon image density and at least one light-insensitive hydrophilic colloid layer, wherein a hydrophilic colloid layer other than said silver halide emulsion layer contains a hydrazine derivative in a non-diffusing condition. With this photographic material, a super high contrast negative image can be obtained without decreasing sensitivity and gamma by the use of a developer containing not less than 0.15 mol/liter of sulfite ions and having a pH of from 10.5 to 12.3.

摘要翻译： 描述负型卤化银照相材料和使用所述材料形成超高对比度负像的方法。 该照相材料包括其上设置有至少一个卤化银乳剂层的载体，其对图像密度具有实质影响，并且至少一个不透光的亲水胶体层，其中除了所述卤化银乳剂层之外的亲水胶体层含有肼 衍生物在非扩散条件下。 利用该照相材料，可以通过使用含有不低于0.15mol / l亚硫酸根离子并且pH为10.5〜12.3的显影剂，而不降低灵敏度和γ而获得超高对比度负像。

公开(公告)号：US4914003A

公开(公告)日：1990-04-03

申请号：US291391

申请日：1988-12-27

申请人： Morio Yagihara ,  Nobuaki Inoue

发明人： Morio Yagihara ,  Nobuaki Inoue

IPC分类号： G03C1/06 ,  G03C5/30

CPC分类号： G03C1/061 ,  Y10S430/15

摘要： A novel silver halide photographic material is provided comprising at least one light-sensitive silver halide emulsion layer provided on a support and containing at least one hydrazine compound and at least one amine compound of the general formula (I) in said emulsion layer or at least one of other constituting layers, provided that said hydrazine compound and said amine compound can be present in the same or different layers: ##STR1## wherein R.sup.2 and R.sup.3, which can be the same or different, each represents a substituted or unsubstituted alkyl group or R.sup.2 and R.sup.3 may be linked to each other to form a ring; R.sup.4 represents a substituted or unsubstituted alkyl, aryl or heterocyclic group; A represents a divalent linkage group; X represents --CONR.sup.5 --, --OCONR.sup.5 --, --NR.sup.5 CONR.sup.5 --, --NR.sup.5 COO--, --COO--, --OCO--, --CO--, --NR.sup.5 CO--, --SO.sub.2 NR.sup.5 --, --NR.sup.5 SO.sub.2 --, --SO.sub.2 --, --S-- or --O-- group (in which R.sup.5 represents a hydrogen atom or a lower alkyl group having 1 to 5 carbon atoms); and n represents an integer of 0 or 1, with the proviso that the total number of carbon atoms contained in R.sup.2, R.sup.3, R.sup.4 and A is 20 or more. Furthermore, a novel method for forming a superhigh contrast negative image is provided which comprises imagewise exposing a silver halide photographic material comprising at least one silver halide emulsion layer provided on a support and containing at least one hydrazine compound and at least one amine compound of the general formula (I) in said emulsion layer of at least one of other constituting layers to light provided that said hydrazine compound and said amine compound can be present in the same or different layers, and then developing the silver halide photographic material thus exposed with a developing solution having a pH value of 10.5 to 12.0 and containing 0.15 mol/liter or more of sulfite ions.

摘要翻译： 提供了一种新颖的卤化银照相材料，其包括至少一种感光卤化银乳剂层，其设置在载体上并且在所述乳剂层中至少包含至少一种肼化合物和至少一种通式（I）的胺化合物 所述肼化合物和所述胺化合物可以以相同或不同的层存在：其中R 2和R 3可以相同或不同，各自表示取代或未取代的 烷基或R 2和R 3可以彼此连接形成环; R 4表示取代或未取代的烷基，芳基或杂环基; A表示二价连接基团; X代表-CON​​R5-，-OCONR5-，-NR5CONR5-，-NR5COO-，-COO-，-OCO-，-CO-，-NR5CO-，-SO2NR5-，-NR5SO2-，-SO2 - ， - S-或 -O-基（其中，R5表示氢原子或碳原子数1〜5的低级烷基）。 并且n表示0或1的整数，条件是R2，R3，R4和A中所含的碳原子总数为20以上。 此外，提供了一种用于形成超高对比度负像的新方法，其包括成像曝光卤化银照相材料，所述卤化银照相材料包含至少一个提供在载体上的卤化银乳剂层，并含有至少一种肼化合物和至少一种 所述乳液层中的至少一种其它构成层的通式（I）为光，条件是所述肼化合物和所述胺化合物可以以相同或不同的层存在，然后将由此暴露于其中的卤化银照相材料显影 显影液的pH值为10.5〜12.0，含有0.15mol / l以上的亚硫酸根离子。

公开(公告)号：US4876174A

公开(公告)日：1989-10-24

申请号：US63469

申请日：1987-06-18

申请人： Takatoshi Ishikawa ,  Morio Yagihara

发明人： Takatoshi Ishikawa ,  Morio Yagihara

IPC分类号： G03C1/035 ,  G03C7/30 ,  G03C7/407 ,  G03C7/413

CPC分类号： G03C7/413

摘要： The present invention relates to a method of processing a silver halide color photosensitive material. In particular, to a rapid processing method capable of reducing the development time. In the processing method, an exposed silver halide color photosensitive material having at least one emulsion layer containing a silver halide having a chlorine content of at least 80 molar % based on the total halogens is processed with a color developer containing an aromatic primary amine color developing agent and a dialkylhydroxylamine of the following general formula (I) but substantially free of benzyl alcohol: ##STR1## wherein R.sup.1 and R.sup.2 each represent an unsubstituted or substituted alkyl group or an unsubstituted or substituted alkenyl group or R.sup.1 and R.sup.2 may form a hetero ring together with nitrogen atom.

摘要翻译： 本发明涉及一种处理卤化银色感光材料的方法。 特别涉及一种能够缩短开发时间的快速处理方法。 在该处理方法中，将曝光的卤化银色感光材料用含有芳香族伯胺显色剂的彩色显影剂加工，所述卤化银色感光材料具有至少一种含有基于总卤素的氯含量至少为80摩尔％的卤化银的乳剂层 （I）但基本上不含苄醇的二烷基羟胺：其中R 1和R 2各自表示未取代或取代的烷基或未取代或取代的烯基，或者R 1和R 2可以形成 杂环与氮原子一起。

公开(公告)号：US4863836A

公开(公告)日：1989-09-05

申请号：US158470

申请日：1988-02-22

申请人： Takatoshi Ishikawa ,  Nobutaka Ohki ,  Morio Yagihara

发明人： Takatoshi Ishikawa ,  Nobutaka Ohki ,  Morio Yagihara

IPC分类号： G03C7/30 ,  G03C7/413

CPC分类号： G03C7/413

摘要： There is provided a method for processing a silver halide color photographic material which comprises processing the silver halide color photographic material with a color developer containing an aromatic primary amine color developing agent and a specific amino compound. According to this method the stability and color forming property of a color developer are improved so that the increased fogging problem in continuous processing is lessened and the processing time is shortened. There is also provided a color developer composition which can be used as the developer, as it is or after adjusting its composition.

摘要翻译： 提供了一种处理卤化银彩色照相材料的方法，其包括用含有芳族伯胺显色剂和特定氨基化合物的显色剂处理卤化银彩色照相材料。 根据该方法，改善了彩色显影剂的稳定性和着色性能，从而减少了连续加工中增加的雾化问题，缩短了处理时间。 还提供了一种彩色显影剂组合物，可以将其作为显影剂或调整其组成后使用。

公开(公告)号：US4767692A

公开(公告)日：1988-08-30

申请号：US484

申请日：1987-01-05

申请人： Yoshio Inagaki ,  Morio Yagihara ,  Shigeo Hirano

发明人： Yoshio Inagaki ,  Morio Yagihara ,  Shigeo Hirano

IPC分类号： C07D295/215 ,  G03C1/06 ,  G03C1/485 ,  G03C1/42

CPC分类号： C07D295/215 ,  G03C1/061 ,  G03C1/48561

摘要： A novel silver halide photographic material is provided comprising a support and at least one silver halide photographic emulsion layer formed thereon and containing in said photographic emulsion layer or at least one hydrophilic colloid layer a compound represented by formula (I): ##STR1## wherein R.sup.1 and R.sup.2 may be the same or different and each represents a hydrogen atom, an aliphatic residual group, an aromatic residual group, or a heterocyclic residual group; R.sup.3 represents a hydrogen atom or an aliphatic residual group; L.sub.1 represents a divalent aliphatic group, a divalent aromatic group, or a divalent heterocyclic group; L.sub.2 represents --O--, --CONR--, --NRCO--, --SO.sub.2 NR--, --NRSO.sub.2 --, --OCO--, --COO--, --S--, --NR--, --CO--, --SO--, --SO.sub.2 --, --OCOO--, --NRCONR'--, --NRCOO--, --OCONR--, or --NRSO.sub.2 NR'-- (in which R and R' each represents a hydrogen atom, an alkyl group or an aryl group); l and m each represents an integer of 1 or 2; n represents an integer of 0 or 1; and A represents a residual group which is obtained by removing hydrogen atoms from Ar or B in a compound represented by formula (II), provided that when m=1, one hydrogen atom is removed; when m=2, two hydrogen atoms are removed: ##STR2## wherein Ar represents an aryl group; B represents a formyl group, an acyl group, an alkyl or arylsulfonyl group, an alkyl or arylsulfinyl group, a carbamoyl group, a sulfamoyl group, an alkoxy or aryloxycarbonyl group, a sulfinamoyl group, an alkoxysulfonyl group, a thioacyl group, a thiocarbamoyl group, or a heterocyclic group; and R.sub.0 and R.sub.00 each represents a hydrogen atom or one of R.sub.0 and R.sub.00 represents a hydrogen atom and the other represents a substituted or unsubstituted alkylsulfonyl group, a substituted or unsubstituted arylsulfonyl group or a substituted or unsubstituted acyl group, with the proviso that B, R.sub.00 and the nitrogen atom to which B and R.sub.00 are bonded may together form a partial structure of hydrazone (--N.dbd.C

公开(公告)号：US4659651A

公开(公告)日：1987-04-21

申请号：US753847

申请日：1985-07-11

申请人： Morio Yagihara ,  Akihiko Ikegawa

发明人： Morio Yagihara ,  Akihiko Ikegawa

IPC分类号： C07D409/04 ,  C07D239/52 ,  C07D239/56 ,  C07D249/18 ,  C07D257/04 ,  C07D335/00 ,  C07D335/02 ,  C07D409/12 ,  G03C1/06 ,  G03C1/34 ,  G03C7/26 ,  G03C7/305 ,  G03C1/46 ,  G03C1/02

CPC分类号： G03C7/30511 ,  G03C1/34 ,  Y10S430/156 ,  Y10S430/158 ,  Y10S430/16 ,  Y10S430/161

摘要： A silver halide photographic material comprising a support having thereon at least one light-sensitive silver halide emulsion layer having associated therewith at least one blocked photographic reagent represented by formula (I) or (II); ##STR1## wherein, A represents a moiety of a photographic reagent or a moiety of a precursor of a photographic reagent bonded to the ring containing Z through a hetero atom; Y.sup.1, and Y.sup.2 and Y.sup.3 each represents a hydrogen atom or a substituent, or Y.sup.1 and Y.sup.3 in formula (I) together form a ring; Z represents an atomic group necessary for forming a carbon ring or a heterocyclic ring; and n represents 1 or 2.The silver halide photographic material is stable under storage conditions.

摘要翻译： 一种卤化银照相材料，其包含其上具有至少一种感光卤化银乳剂层的载体，所述感光卤化银乳剂层具有至少一种由式（I）或（II）表示的封闭照相试剂。 （II）其中，A表示通过杂原子键合到含有Z的环的照相试剂或照相试剂的前体的部分的部分; Y1，Y2和Y3各自表示氢原子或取代基，或式（I）中的Y1和Y3一起形成环; Z表示形成碳环或杂环所必需的原子团; 并且n表示1或2.卤化银照相材料在储存条件下是稳定的。

公开(公告)号：US4624911A

公开(公告)日：1986-11-25

申请号：US706532

申请日：1985-02-27

申请人： Yoshio Idota ,  Morio Yagihara

发明人： Yoshio Idota ,  Morio Yagihara

IPC分类号： G03C8/32 ,  G03C8/36 ,  G03C5/54 ,  G03C5/38

CPC分类号： G03C8/365

摘要： A method for image formation by a diffusion transfer process including developing an imagewise light-exposed light-sensitive silver halide emulsion layer in the presence of a developing agent, a silver halide solvent and an alkali, wherein at least two cyclic imide compounds represented by the formula: ##STR1## wherein Z represents an atomic group necessary to form a 5- or 6-membered imido ring containing from 1 to 3 nitrogen atoms, are used as the silver halide solvent is disclosed. Images obtained by the method are stable during storage over a long period of time.

摘要翻译： 一种通过扩散转移法形成图像的方法，包括在显影剂，卤化银溶剂和碱的存在下显影成像曝光的感光卤化银乳剂层，其中至少两种由 公开：其中Z表示形成含有1至3个氮原子的5-或6-元亚胺基所必需的原子团的式（I）化合物用作卤化银溶剂。 通过该方法获得的图像在长时间的储存期间是稳定的。

公开(公告)号：US4500634A

公开(公告)日：1985-02-19

申请号：US526171

申请日：1983-08-24

申请人： Kei Sakanoue ,  Morio Yagihara ,  Seigi Ichijima ,  Kimitoshi Nagao

发明人： Kei Sakanoue ,  Morio Yagihara ,  Seigi Ichijima ,  Kimitoshi Nagao

IPC分类号： G03C7/32 ,  G03C7/26

CPC分类号： G03C7/3225 ,  Y10S430/158

摘要： A silver halide color photographic material in which both a coupler capable of releasing a diffusible development restrainer by coupling and a polymer coupler latex are present to increase visual sharpness.

摘要翻译： 存在卤化银彩色照相材料，其中存在能够通过偶联释放扩散显影抑制剂的成色剂和聚合物成色剂胶乳，以增加视觉清晰度。